The influence of surface adsorption on microbubble dynamics

Author(s):  
E Stride

In a pure liquid, the behaviour of a gas or vapour microbubble is determined primarily by its size, the ambient pressure and the properties of the surrounding liquid. In practice, however, adsorption of a dissolved substance from the surrounding liquid onto the microbubble surface will often take place, producing a thin coating which can significantly affect both the microbubble's stability and its dynamic response. This can have important implications in a wide range of applications, including underwater acoustics, cavitation detection, medical imaging and drug delivery. The aim of this paper is to review the existing theoretical treatments of coated microbubbles and to present and discuss some recent developments. It will be shown that the presence of the coating can substantially modify the amplitude of microbubble volumetric oscillation, resonance characteristics and relative amplitude in tension and compression. Finally, the need for improved understanding of the dynamic behaviour of surface coatings at high frequencies will be discussed.

The recycling and reuse of materials and objects were extensive in the past, but have rarely been embedded into models of the economy; even more rarely has any attempt been made to assess the scale of these practices. Recent developments, including the use of large datasets, computational modelling, and high-resolution analytical chemistry, are increasingly offering the means to reconstruct recycling and reuse, and even to approach the thorny matter of quantification. Growing scholarly interest in the topic has also led to an increasing recognition of these practices from those employing more traditional methodological approaches, which are sometimes coupled with innovative archaeological theory. Thanks to these efforts, it has been possible for the first time in this volume to draw together archaeological case studies on the recycling and reuse of a wide range of materials, from papyri and textiles, to amphorae, metals and glass, building materials and statuary. Recycling and reuse occur at a range of site types, and often in contexts which cross-cut material categories, or move from one object category to another. The volume focuses principally on the Roman Imperial and late antique world, over a broad geographical span ranging from Britain to North Africa and the East Mediterranean. Last, but not least, the volume is unique in focusing upon these activities as a part of the status quo, and not just as a response to crisis.


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.


Author(s):  
Hernâni Marques ◽  
Pedro Cruz-Vicente ◽  
Tiago Rosado ◽  
Mário Barroso ◽  
Luís A. Passarinha ◽  
...  

Environmental tobacco smoke exposure (ETS) and smoking have been described as the most prevalent factors in the development of certain diseases worldwide. According to the World Health Organization, more than 8 million people die every year due to exposure to tobacco, around 7 million due to direct ETS and the remaining due to exposure to second-hand smoke. Both active and second-hand exposure can be measured and controlled using specific biomarkers of tobacco and its derivatives, allowing the development of more efficient public health policies. Exposure to these compounds can be measured using different methods (involving for instance liquid- or gas-chromatographic procedures) in a wide range of biological specimens to estimate the type and degree of tobacco exposure. In recent years, a lot of research has been carried out using different extraction methods and different analytical equipment; this way, liquid–liquid extraction, solid-phase extraction or even miniaturized procedures have been used, followed by chromatographic analysis coupled mainly to mass spectrometric detection. Through this type of methodologies, second-hand smokers can be distinguished from active smokers, and this is also valid for e-cigarettes and vapers, among others, using their specific biomarkers. This review will focus on recent developments in the determination of tobacco smoke biomarkers, including nicotine and other tobacco alkaloids, specific nitrosamines, polycyclic aromatic hydrocarbons, etc. The methods for their detection will be discussed in detail, as well as the potential use of threshold values to distinguish between types of exposure.


1990 ◽  
Vol 43 (5) ◽  
pp. 583
Author(s):  
GL Price

Recent developments in the growth of semiconductor thin films are reviewed. The emphasis is on growth by molecular beam epitaxy (MBE). Results obtained by reflection high energy electron diffraction (RHEED) are employed to describe the different kinds of growth processes and the types of materials which can be constructed. MBE is routinely capable of heterostructure growth to atomic precision with a wide range of materials including III-V, IV, II-VI semiconductors, metals, ceramics such as high Tc materials and organics. As the growth proceeds in ultra high vacuum, MBE can take advantage of surface science techniques such as Auger, RHEED and SIMS. RHEED is the essential in-situ probe since the final crystal quality is strongly dependent on the surface reconstruction during growth. RHEED can also be used to calibrate the growth rate, monitor growth kinetics, and distinguish between various growth modes. A major new area is lattice mismatched growth where attempts are being made to construct heterostructures between materials of different lattice constants such as GaAs on Si. Also described are the new techniques of migration enhanced epitaxy and tilted superlattice growth. Finally some comments are given On the means of preparing large area, thin samples for analysis by other techniques from MBE grown films using capping, etching and liftoff.


Author(s):  
Kevork Oskanian

Abstract This article contributes a securitisation-based, interpretive approach to state weakness. The long-dominant positivist approaches to the phenomenon have been extensively criticised for a wide range of deficiencies. Responding to Lemay-Hébert's suggestion of a ‘Durkheimian’, ideational-interpretive approach as a possible alternative, I base my conceptualisation on Migdal's view of state weakness as emerging from a ‘state-in-society's’ contested ‘strategies of survival’. I argue that several recent developments in Securitisation Theory enable it to capture this contested ‘collective knowledge’ on the state: a move away from state-centrism, the development of a contextualised ‘sociological’ version, linkages made between securitisation and legitimacy, and the acknowledgment of ‘securitisations’ as a contested Bourdieusian field. I introduce the concept of ‘securitisation gaps’ – divergences in the security discourses and practices of state and society – as a concept aimed at capturing this contested role of the state, operationalised along two logics (reactive/substitutive) – depending on whether they emerge from securitisations of the state action or inaction – and three intensities (latent, manifest, and violent), depending on the extent to which they involve challenges to state authority. The approach is briefly illustrated through the changing securitisation gaps in the Republic of Lebanon during the 2019–20 ‘October Uprising’.


Water ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 474
Author(s):  
Daniel Constantin Diaconu ◽  
Romulus Costache ◽  
Mihnea Cristian Popa

Scientific papers present a wide range of methods of flood analysis and forecasting. Floods are a phenomenon with significant socio-economic implications, for which many researchers try to identify the most appropriate methodologies to analyze their temporal and spatial development. This research aims to create an overview of flood analysis and forecasting methods. The study is based on the need to select and group papers into well-defined methodological categories. The article provides an overview of recent developments in the analysis of flood methodologies and shows current research directions based on this overview. The study was performed taking into account the information included in the Web of Science Core Collection, which brought together 1326 articles. The research concludes with a discussion on the relevance, ease of application, and usefulness of the methodologies.


2001 ◽  
Vol 28 (1) ◽  
pp. 98-110 ◽  
Author(s):  
Bruce F Sparling ◽  
Alan G Davenport

Large amplitude cable vibrations are difficult to predict using linear theory due to the presence of sag in the suspended profile. A numerical study was therefore undertaken to investigate the dynamic behaviour of inclined cables excited by imposed displacements. To model the nonlinear nature of cable response, a time domain finite element approach was adopted using nonlinear catenary cable elements. Two types of horizontal displacement patterns were enforced at the upper end of the guy. In the first phase of the study, harmonic displacement histories with a wide range of forcing frequencies were considered. In the second phase, random enforced displacements were used to simulate the motion of a guyed mast in gusty winds. The influence of aerodynamic drag and damping forces was investigated by performing analyses under still air, steady wind, and turbulent wind conditions. It was found that nonlinear coupling of related harmonic response components was significant at certain critical frequencies, particular when the excitation was harmonic and acted in the plane of the guy. Positive aerodynamic damping was shown to effectively suppress resonant and nonlinear coupling response.Key words: cables, structural dynamics, wind loading, finite element method, nonlinear analysis, guyed towers.


2002 ◽  
Vol 124 (4) ◽  
pp. 762-770 ◽  
Author(s):  
G. S. Zhu ◽  
S. K. Aggarwal

This paper reports a numerical investigation of the transcritical droplet vaporization phenomena. The simulation is based on the time-dependent conservation equations for liquid and gas phases, pressure-dependent variable thermophysical properties, and a detailed treatment of liquid-vapor phase equilibrium at the droplet surface. The numerical solution of the two-phase equations employs an arbitrary Eulerian-Lagrangian, explicit-implicit method with a dynamically adaptive mesh. Three different equations of state (EOS), namely the Redlich-Kwong (RK), the Peng-Robinson (PR), and Soave-Redlich-Kwong (SRK) EOS, are employed to represent phase equilibrium at the droplet surface. In addition, two different methods are used to determine the liquid density. Results indicate that the predictions of RK-EOS are significantly different from those obtained by using the RK-EOS and SRK-EOS. For the phase-equilibrium of n-heptane-nitrogen system, the RK-EOS predicts higher liquid-phase solubility of nitrogen, higher fuel vapor concentration, lower critical-mixing-state temperature, and lower enthalpy of vaporization. As a consequence, it significantly overpredicts droplet vaporization rates, and underpredicts droplet lifetimes compared to those predicted by PR and SRK-EOS. In contrast, predictions using the PR-EOS and SRK-EOS show excellent agreement with each other and with experimental data over a wide range of conditions. A detailed investigation of the transcritical droplet vaporization phenomena indicates that at low to moderate ambient temperatures, the droplet lifetime first increases and then decreases as the ambient pressure is increased. At high ambient temperatures, however, the droplet lifetime decreases monotonically with pressure. This behavior is in accord with the reported experimental data.


2015 ◽  
Vol 7 (4) ◽  
pp. 421-445 ◽  
Author(s):  
James R. Barth ◽  
Tong Li ◽  
Wen Shi ◽  
Pei Xu

Purpose – The purpose of this paper is to examine recent developments pertaining to China’s shadow banking sector. Shadow banking has the potential not only to be a beneficial contributor to continued economic growth, but also to contribute to systematic instability if not properly monitored and regulated. An assessment is made in this paper as to whether shadow banking is beneficial or harmful to China’s economic growth. Design/methodology/approach – The authors start with providing an overview of shadow banking from a global perspective, with information on its recent growth and importance in selected countries. The authors then focus directly on China’s shadow banking sector, with information on the various entities and activities that comprise the sector. Specifically, the authors examine the interconnections between shadow banking and regular banking in China and the growth in shadow banking to overall economic growth, the growth in the money supply and the growth in commercial bank assets. Findings – Despite the wide range in the estimates, the trend in the size of shadow banking in China has been upward over the examined period. There are significant interconnections between the shadow banking sector and the commercial banking sector. Low deposit rate and high reserve requirement ratios have been the major factors driving its growth. Shadow banking has been a contributor, along with money growth, to economic growth. Practical implications – The authors argue that shadow banking may prove useful by diversifying China’s financial sector and providing greater investments and savings opportunities to consumers and businesses throughout the country, if the risks of shadow banking are adequately monitored and controlled. Originality/value – To the authors’ knowledge, this paper is among the few to systematically evaluate the influence of shadow banking on China’s economic growth.


2014 ◽  
Vol 22 (1) ◽  
pp. 159-188 ◽  
Author(s):  
Mikdam Turkey ◽  
Riccardo Poli

Several previous studies have focused on modelling and analysing the collective dynamic behaviour of population-based algorithms. However, an empirical approach for identifying and characterising such a behaviour is surprisingly lacking. In this paper, we present a new model to capture this collective behaviour, and to extract and quantify features associated with it. The proposed model studies the topological distribution of an algorithm's activity from both a genotypic and a phenotypic perspective, and represents population dynamics using multiple levels of abstraction. The model can have different instantiations. Here it has been implemented using a modified version of self-organising maps. These are used to represent and track the population motion in the fitness landscape as the algorithm operates on solving a problem. Based on this model, we developed a set of features that characterise the population's collective dynamic behaviour. By analysing them and revealing their dependency on fitness distributions, we were then able to define an indicator of the exploitation behaviour of an algorithm. This is an entropy-based measure that assesses the dependency on fitness distributions of different features of population dynamics. To test the proposed measures, evolutionary algorithms with different crossover operators, selection pressure levels and population handling techniques have been examined, which lead populations to exhibit a wide range of exploitation-exploration behaviours.


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