Kinetic equivalence of the heat and cold structural transitions of λ 6–85

2005 ◽  
Vol 363 (1827) ◽  
pp. 565-573 ◽  
Author(s):  
Wei Y. Yang ◽  
Martin Gruebele
Keyword(s):  
Folding Kinetics ◽  
Native State ◽  
Temperature Changes ◽  
First Order ◽  
Hydrophobic Collapse ◽  
Folding Rates ◽  
Temperature Tuning ◽  
Pass Through ◽  
Denatured States ◽  
First Order Phase

Heat– and cold–denatured proteins are considered separate thermodynamic states because temperature tuning requires the protein to pass through two ‘soft’ first–order phase transitions. When both pressure and temperature changes are allowed, the heat– and cold–denatured states of proteins can be interconverted without going through the native state. This raises the question of whether these states are distinguished from one another by their folding kinetics. For the Tyr22Trp/Ala37Gly/Ala49Gly mutant of the 80 residue five–helix bundle protein λ 6−85 , we show that viscosity–corrected folding rates do not distinguish the cold– and heat–denatured states. We attribute this to a folding mechanism dominated by hydrophobic collapse. Our ‘temperature–symmetric’ approach offers an alternative to viscosity tuning with solvent additives in such cases.

scholarly journals High Pressure Raman Study of Layered Semiconductor Tlgase2

2018 ◽  
Vol 36 (2) ◽  
pp. 203-208 ◽  
Author(s):  
S.H. Jabarov ◽  
V.B. Aliyeva ◽  
T.G. Mammadov ◽  
A.I. Mammadov ◽  
S.E. Kichanov ◽  
...  
Keyword(s):  
Pressure Range ◽  
Layer Structure ◽  
Molecular Crystals ◽  
Layered Semiconductor ◽  
Temperature Changes ◽  
First Order ◽  
First Order Phase Transition ◽  
Raman Study ◽  
First Order Phase ◽  
Intramolecular Forces

Abstract Raman spectroscopy measurements of a monoclinic layered semiconductor TlGaSe2were performed in a pressure range up to 10.24 GPa. The pressure-induced first-order phase transition accompanied by reconstruction of the layer structure was observed at the pressure P ~ 0.9 GPa. The mode-Grüneisen parameters of intralayer bonds were calculated for TlGaSe2. The contribution of thermal expansion to temperature changes of phonon frequencies was defined. The type of intralayer bonds and their pressure transformation were analyzed in layered TlGaSe2. It was shown that the nature of intramolecular forces in molecular crystals and intralayer forces in layered GaS, GaSe and TlGaSe2is similar

scholarly journals Ripples in spacetime from broken supersymmetry

2021 ◽  
Vol 2021 (2) ◽  
Author(s):  
Nathaniel Craig ◽  
Noam Levi ◽  
Alberto Mariotti ◽  
Diego Redigolo
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Susy Breaking ◽  
Low Energy ◽  
Temperature Expansion ◽  
Cosmological Constraints ◽  
First Order ◽  
Hidden Sector ◽  
Pass Through ◽  
First Order Phase

Abstract We initiate the study of gravitational wave (GW) signals from first-order phase transitions in supersymmetry-breaking hidden sectors. Such phase transitions often occur along a pseudo-flat direction universally related to supersymmetry (SUSY) breaking in hidden sectors that spontaneously break R-symmetry. The potential along this pseudo-flat direction imbues the phase transition with a number of novel properties, including a nucleation temperature well below the scale of heavy states (such that the temperature dependence is captured by the low-temperature expansion) and significant friction induced by the same heavy states as they pass through bubble walls. In low-energy SUSY-breaking hidden sectors, the frequency of the GW signal arising from such a phase transition is guaranteed to lie within the reach of future interferometers given existing cosmological constraints on the gravitino abundance. Once a mediation scheme is specified, the frequency of the GW peak correlates with the superpartner spectrum. Current bounds on supersymmetry are compatible with GW signals at future interferometers, while the observation of a GW signal from a SUSY-breaking hidden sector would imply superpartners within reach of future colliders.

Morphological studies of linear (AB)n multiblock copolymers and their blends

1992 ◽  
Vol 50 (1) ◽  
pp. 384-385
Author(s):  
Richard J. Spontak ◽  
Steven D. Smith ◽  
Arman Ashraf
Keyword(s):  
Electron Microscopy ◽  
Microphase Separation ◽  
Multiblock Copolymers ◽  
First Order ◽  
Morphological Studies ◽  
Transmission Electron ◽  
First Order Phase Transition ◽  
Covalently Bonded ◽  
Total Molecular Weight ◽  
First Order Phase

Block copolymers are composed of sequences of dissimilar chemical moieties covalently bonded together. If the block lengths of each component are sufficiently long and the blocks are thermodynamically incompatible, these materials are capable of undergoing microphase separation, a weak first-order phase transition which results in the formation of an ordered microstructural network. Most efforts designed to elucidate the phase and configurational behavior in these copolymers have focused on the simple AB and ABA designs. Few studies have thus far targeted the perfectly-alternating multiblock (AB)n architecture. In this work, two series of neat (AB)n copolymers have been synthesized from styrene and isoprene monomers at a composition of 50 wt% polystyrene (PS). In Set I, the total molecular weight is held constant while the number of AB block pairs (n) is increased from one to four (which results in shorter blocks). Set II consists of materials in which the block lengths are held constant and n is varied again from one to four (which results in longer chains). Transmission electron microscopy (TEM) has been employed here to investigate the morphologies and phase behavior of these materials and their blends.

scholarly journals Electric properties of olive oil under pressure

2021 ◽  
Author(s):  
L. T. Pawlicki ◽  
R. M. Siegoczyński ◽  
S. Ptasznik ◽  
K. Marszałek
Keyword(s):  
Molecular Structure ◽  
Phase Transition ◽  
Phase Diagram ◽  
Phase Transitions ◽  
Olive Oil ◽  
Material Parameters ◽  
First Order ◽  
Long Time ◽  
Capacitive Reactance ◽  
First Order Phase

AbstractThe main purpose of the experiment was a thermodynamic research with use of the electric methods chosen. The substance examined was olive oil. The paper presents the resistance, capacitive reactance, relative permittivity and resistivity of olive. Compression was applied with two mean velocities up to 450 MPa. The results were shown as functions of pressure and time and depicted on the impedance phase diagram. The three first order phase transitions have been detected. All the changes in material parameters were observed during phase transitions. The material parameters measured turned out to be the much more sensitive long-time phase transition factors than temperature. The values of material parameters and their dependence on pressure and time were compared with the molecular structure, arrangement of molecules and interactions between them. Knowledge about olive oil parameters change with pressure and its phase transitions is very important for olive oil production and conservation.

scholarly journals Fate of false vacua in holographic first-order phase transitions

2020 ◽  
Vol 2020 (12) ◽  
Author(s):  
Francesco Bigazzi ◽  
Alessio Caddeo ◽  
Aldo L. Cotrone ◽  
Angel Paredes
Keyword(s):  
Phase Transitions ◽  
Chiral Symmetry ◽  
Metastable Phase ◽  
Chiral Symmetry Breaking ◽  
Model Parameters ◽  
Temperature Phase ◽  
Thin Wall ◽  
Critical Temperatures ◽  
First Order ◽  
First Order Phase

Abstract Using the holographic correspondence as a tool, we study the dynamics of first-order phase transitions in strongly coupled gauge theories at finite temperature. Considering an evolution from the large to the small temperature phase, we compute the nucleation rate of bubbles of true vacuum in the metastable phase. For this purpose, we find the relevant configurations (bounces) interpolating between the vacua and we compute the related effective actions. We start by revisiting the compact Randall-Sundrum model at high temperature. Using holographic renormalization, we compute the derivative term in the effective bounce action, that was missing in the literature. Then, we address the full problem within the top-down Witten-Sakai-Sugimoto model. It displays both a confinement/deconfinement and a chiral symmetry breaking/restoration phase transition which, depending on the model parameters, can happen at different critical temperatures. For the confinement/deconfinement case we perform the numerical analysis of an effective description of the transition and also provide analytic expressions using thick and thin wall approximations. For the chiral symmetry transition, we implement a variational approach that allows us to address the challenging non-linear problem stemming from the Dirac-Born-Infeld action.

scholarly journals Gravitational wave signals of dark matter freeze-out

2021 ◽  
Vol 2021 (2) ◽  
Author(s):  
Danny Marfatia ◽  
Po-Yan Tseng
Keyword(s):  
Phase Transition ◽  
Dark Matter ◽  
Gravitational Waves ◽  
Order Phase Transition ◽  
First Order ◽  
Stochastic Background ◽  
First Order Phase Transition ◽  
Relic Abundance ◽  
First Order Phase ◽  
Freeze Out

Abstract We study the stochastic background of gravitational waves which accompany the sudden freeze-out of dark matter triggered by a cosmological first order phase transition that endows dark matter with mass. We consider models that produce the measured dark matter relic abundance via (1) bubble filtering, and (2) inflation and reheating, and show that gravitational waves from these mechanisms are detectable at future interferometers.

scholarly journals Charge density waves and their transitions in anisotropic quantum Hall systems

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Yuchi He ◽  
Kang Yang ◽  
Mark Oliver Goerbig ◽  
Roger S. K. Mong
Keyword(s):  
Phase Transitions ◽  
Charge Density ◽  
Density Wave ◽  
Quantum Hall ◽  
Charge Density Waves ◽  
Stripe Phase ◽  
Electron Bubble ◽  
First Order ◽  
Bubble Phase ◽  
First Order Phase

AbstractIn recent experiments, external anisotropy has been a useful tool to tune different phases and study their competitions. In this paper, we look at the quantum Hall charge density wave states in the N = 2 Landau level. Without anisotropy, there are two first-order phase transitions between the Wigner crystal, the 2-electron bubble phase, and the stripe phase. By adding mass anisotropy, our analytical and numerical studies show that the 2-electron bubble phase disappears and the stripe phase significantly enlarges its domain in the phase diagram. Meanwhile, a regime of stripe crystals that may be observed experimentally is unveiled after the bubble phase gets out. Upon increase of the anisotropy, the energy of the phases at the transitions becomes progressively smooth as a function of the filling. We conclude that all first-order phase transitions are replaced by continuous phase transitions, providing a possible realisation of continuous quantum crystalline phase transitions.

scholarly journals Dark Matter production from relativistic bubble walls

2021 ◽  
Vol 2021 (3) ◽  
Author(s):  
Aleksandr Azatov ◽  
Miguel Vanvlasselaer ◽  
Wen Yin
Keyword(s):  
Phase Transition ◽  
Dark Matter ◽  
Electroweak Phase Transition ◽  
First Order ◽  
Matter Production ◽  
First Order Phase Transition ◽  
Relic Abundance ◽  
Higgs Portal ◽  
First Order Phase ◽  
Gravitational Background

Abstract In this paper we present a novel mechanism for producing the observed Dark Matter (DM) relic abundance during the First Order Phase Transition (FOPT) in the early universe. We show that the bubble expansion with ultra-relativistic velocities can lead to the abundance of DM particles with masses much larger than the scale of the transition. We study this non-thermal production mechanism in the context of a generic phase transition and the electroweak phase transition. The application of the mechanism to the Higgs portal DM as well as the signal in the Stochastic Gravitational Background are discussed.

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