scholarly journals Synthesis and hydrogenation application of Pt–Pd bimetallic nanocatalysts stabilized by macrocycle-modified dendrimer

2017 ◽  
Vol 4 (12) ◽  
pp. 171414 ◽  
Author(s):  
Zhijun Jin ◽  
Haiyan Xiao ◽  
Wei Zhou ◽  
Dongqiao Zhang ◽  
Xiaohong Peng
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Resonance Spectroscopy ◽  
Butadiene Rubber ◽  
Electronic Effects ◽  
X Ray ◽  
Nanoparticle Catalysts ◽  
Bimetallic Nanoparticle ◽  
Bimetallic Nanocatalysts

Different generations of poly(propylene imine) (G n -PPI) terminated with N-containing 15-membered triolefinic macrocycle (G n M) ( n  = 2, 3, 4, 5) were prepared. The bimetallic nanoparticle catalysts G n M-(Pt x /Pd 10− x ) ( x  = 0, 3, 5, 7, 10) were prepared by the synchronous ligand-exchange reaction between G n M and the complexes of Pt(PPh 3 ) 4 and Pd(PPh 3 ) 4 . The structure and catalytic properties of G n M-(Pt x /Pd 10− x ) were characterized via Fourier transform infrared spectroscopy, 1 H nuclear magnetic resonance spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, energy-dispersive spectroscopy and inductively coupled plasma atomic emission spectroscopy. The novel bimetallic Pd–Pt nanoparticle catalysts stabilized by dendrimers (DSNs) present higher catalytic activities for the hydrogenation of dimeric acid (DA) than that of nitrile butadiene rubber (NBR). It can be concluded that bimetallic Pd–Pt DSNs possess alloying and synergistic electronic effects on account of the hydrogenation degree (HD) of DA and NBR. Furthermore, the HD of DA and NBR shows a remarkable decrease with the incremental generations ( n ) of G n M-(Pt 3 /Pd 7 ) ( n  = 2, 3, 4, 5).

Photocatalytic Oxidation of Alcohols Over Magnetically Recoverable Gold Supported Iron Oxide Nanoparticles

2019 ◽  
Vol 11 (12) ◽  
pp. 1731-1738 ◽  
Author(s):  
Ma Hui ◽  
Wu Juzhen ◽  
Zhao Li ◽  
Zhou Zheng ◽  
Guo Jiahu
Keyword(s):  
Electron Microscopy ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Photocatalytic Oxidation ◽  
Organic Dyes ◽  
Atomic Emission ◽  
One Pot ◽  
X Ray ◽  
Inductively Coupled ◽  
Oxidation Of Alcohols

A one-pot simple and efficient synthetic route for the synthesis of Au-loaded Fe2O3 nanoparticles was developed, and this material's photocatalytic activity for visible light assisted oxidation of alcohols and degradation of organic dye were studied. As-synthesized nanostructured catalyst was characterised by powder X-ray diffraction (XRD), transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), SEM-mapping, X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption isotherm (BET), and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). It was observed that 5–10 nm Au-nanoparticles supported on 10–80 nm Fe2O3 shows boomerang-shaped nanoparticle. Gold loading of 1 wt% shows high conversion and selectivity towards the target product aldehyde. The synthesized nanomaterial also proved to be an excellent photocatalyst for degradation of organic dyes such as methylene blue (MB) and rhodamine B (RhB). The catalyst proved to be noteworthy as it does not loss in its catalytic activity even after five cycles of reuse.

Antiphotocorrosive photocatalysts containing CdS nanoparticles and exfoliated TiO2 nanosheets

2010 ◽  
Vol 25 (1) ◽  
pp. 182-188 ◽  
Author(s):  
Xiaoxia Yan ◽  
Gang Liu ◽  
Lianzhou Wang ◽  
Yong Wang ◽  
Xianfang Zhu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Self Assembly ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Cds Nanoparticles ◽  
Visible Absorption ◽  
X Ray ◽  
Tio2 Nanosheets

Aimed at designing an efficient visible light active photocatalyst and suppressing the self-corrosion tendency of CdS nanoparticles, a novel composite consisting of CdS nanoparticles and exfoliated two-dimensional (2D) TiO2 nanosheets was successfully fabricated using a simple self-assembly process. The prepared samples were characterized using various techniques including x-ray diffraction, ultraviolet–visible absorption spectroscopy, x-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. It was found that the exfoliated 2D nanosheets played an important role as an ultrathin coating to suppress the photocorrosion of CdS nanoparticles, evidenced by inductively coupled plasma-atomic emission spectrometer analysis. The resultant CdS/TiO2 composites exhibited enhanced photocatalytic activity in the oxidation of Rhodamine B in water under visible light irradiation (λ > 420 nm).

scholarly journals The Modification of Pt/Graphene Composites with Oxophilic Metal Bi (Bi2O3) and Its Dual-Functional Electro-Photo Catalytic Performance

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 465
Author(s):  
Yingli Wu ◽  
Xiuyun Duan ◽  
Zhongshui Li ◽  
Shuhong Xu ◽  
Yixin Xie ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Electric Energy ◽  
Atomic Emission ◽  
Catalytic Performance ◽  
Water Soluble ◽  
Methanol Oxidation Reaction ◽  
Solution Synthesis ◽  
X Ray ◽  
Electrocatalytic Properties

The Pt-Bi (Bi2O3)/GNs (PVP) composite was synthesized using aqueous solution synthesis and characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and Raman spectroscopy. It was found that the water-soluble polyvinyl pyrrolidone (PVP) helped to tune the particles’ morphology, resulting in a uniform distribution of Pt-Bi nanoclusters on the surface of graphene. Cyclic voltammetry, chronoamperometry and linear scanning voltammetry (LSV) were used to study the electrocatalytic properties towards a methanol oxidation reaction (MOR) and an oxygen reduction reaction (ORR). The results show that Pt-Bi (Bi2O3)/GNs (PVP) exhibits superior bifunctional electrocatalytic properties for both MOR and ORR, mainly due to the introduction of oxophilic Bi species and the better dispersion of the Pt-Bi nanoclusters. In particular, the electro-photo catalysis for both MOR and ORR occurred under simulated sunlight irradiation due to the existence of photo-responsive Bi species, which is helpful for converting solar energy into electric energy during a traditional electrocatalytic process.

HIGHLY ACTIVE AND REUSABLE RHODIUM CATALYST FOR SELECTIVE HYDROGENATION OF NITRILE–BUTADIENE RUBBER

2015 ◽  
Vol 88 (4) ◽  
pp. 547-559 ◽  
Author(s):  
Peng Cao ◽  
Lin Su ◽  
Cui Li ◽  
Liqun Zhang ◽  
Dongmei Yue
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Active Sites ◽  
Rhodium Catalyst ◽  
Infrared Spectrometry ◽  
Butadiene Rubber ◽  
X Ray ◽  
Inductively Coupled ◽  
Nitrile Butadiene Rubber ◽  
Highly Active

ABSTRACT A recyclable heterogeneous rhodium catalyst (MTS-T-Rh) was prepared by loading Rh species onto an amino-silica support grafted by tannin, an intermediate linker and stabilizer, and fully characterized by X-ray diffraction, infrared spectrometry, scanning electron microscopy, X-ray photoelectron spectroscopy, and inductively coupled plasma. The importance of tannin in improving the activity and stability of the heterogeneous catalyst is discussed. Tannin is a stabilizer for chelating with the Rh-active sites through a chemical bond, which enhances interactions between the Rh nanoparticles and silica. The catalytic hydrogenation of nitrile–butadiene rubber was evaluated in solution. Above 96% conversion and 100% selectivity, the carbon–carbon double bond was obtained at 120 °C and 3.0 MPa H2 after 8 h over MTS-T-Rh. Compared with Rh/SiO2, the as-prepared MTS-T-Rh catalyst exhibited considerably improved reusability, which suffered about 11% deactivation for hydrogenation of nitrile–butadiene rubber, whereas Rh/SiO2 was 53%.

scholarly journals Oxidation of 5-Hydroxymethylfurfural on Supported Ag, Au, Pd and Bimetallic Pd-Au Catalysts: Effect of the Support

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 115
Author(s):  
Dmitrii German ◽  
Ekaterina Pakrieva ◽  
Ekaterina Kolobova ◽  
Sónia A. C. Carabineiro ◽  
Marta Stucchi ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Bimetallic Catalysts ◽  
Inductively Coupled Plasma ◽  
Noble Metals ◽  
Nitrogen Adsorption ◽  
Carbon Support ◽  
Atomic Emission ◽  
Indicator Method ◽  
X Ray ◽  
Effect Of The Support

Oxidation of 5-hydroxymethylfurfural (HMF), a major feedstock derived from waste/fresh biomass, into 2,5-furandicarboxylic acid (FDCA) is an important transformation for the production of biodegradable plastics. Herein, we investigated the effect of the support (unmodified and modified titania, commercial alumina, and untreated and treated Sibunit carbon) of mono- and bimetallic catalysts based on noble metals (Ag, Au, Pd) on selective HMF oxidation with molecular oxygen to FDCA under mild and basic reaction conditions. The higher selectivity to FDCA was obtained when metals were supported on Sibunit carbon (Cp). The order of noble metal in terms of catalyst selectivity was: Ag < Au < Pd < PdAu. Finally, FDCA production on the most efficient PdAu NPs catalysts supported on Sibunit depended on the treatment applied to this carbon support in the order: PdAu/Cp < PdAu/Cp-HNO3 < PdAu/Cp-NH4OH. These bimetallic catalysts were characterized by nitrogen adsorption-desorption, inductively coupled plasma atomic emission spectroscopy, high resolution transmission electron microscopy, energy dispersive spectroscopy, X-ray diffraction, Hammet indicator method and X-ray photoelectron spectroscopy. The functionalization of Sibunit surface by HNO3 and NH4OH led to a change in the contribution of the active states of Pd and Au due to promotion effect of N-doping and, as a consequence, to higher FDCA production. HMF oxidation catalyzed by bimetallic catalysts is a structure sensitive reaction.

scholarly journals Fabricating Antibacterial and Antioxidant Electrospun Hydrophilic Polyacrylonitrile Nanofibers Loaded with AgNPs by Lignin-Induced In-Situ Method

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 748
Author(s):  
Md. Kaiser Haider ◽  
Azeem Ullah ◽  
Muhammad Nauman Sarwar ◽  
Takumi Yamaguchi ◽  
Qianyu Wang ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Emission Spectrometry ◽  
Burst Release ◽  
Bacterial Strains ◽  
Plasma Atomic Emission Spectrometry ◽  
Water Contact ◽  
X Ray ◽  
E Coli

Concerning the environmental hazards owing to the chemical-based synthesis of silver nanoparticles (AgNPs), this study aimed to investigate the possibility of synthesizing AgNPs on the surface of polyacrylonitrile (PAN) nanofibers utilizing biomacromolecule lignin. SEM observations revealed that the average diameters of the produced nanofibers were slightly increased from ~512 nm to ~673 nm due to several factors like-swellings that happened during the salt treatment process, surface-bound lignin, and the presence of AgNPs. The presence of AgNPs was validated by transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) analysis. The amount of synthesized AgNPs on PAN nanofibers was found to be dependent on both precursor silver salt and reductant lignin concentration. Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectra confirm the presence of lignin on PAN nanofibers. Although the X-ray diffraction pattern did not show any AgNPs band, the reduced intensity of the stabilized PAN characteristics bands at 2θ = 17.28° and 29.38° demonstrated some misalignment of PAN polymeric chains. The water contact angle (WCA) of hydrophobic PAN nanofibers was reduced from 112.6 ± 4.16° to 21.4 ± 5.03° for the maximum AgNPs coated specimen. The prepared membranes exhibited low thermal stability and good swelling capacity up to 20.1 ± 0.92 g/g and 18.05 ± 0.68 g/g in distilled water and 0.9 wt% NaCl solution, respectively. Coated lignin imparts antioxidant activity up to 78.37 ± 0.12% at 12 h of incubation. The resultant nanofibrous membranes showed a proportional increase in antibacterial efficacy with the rise in AgNPs loading against both Gram-positive S. aureus and Gram-negative E. coli bacterial strains by disc diffusion test (AATCC 147-1998). Halos for maximum AgNPs loading was calculated to 18.89 ± 0.15 mm for S. aureus and 21.38 ± 0.17 mm for E. coli. An initial burst release of silver elements within 24 h was observed in the inductively coupled plasma-atomic emission spectrometry (ICP-AES) test, and the release amounts were proportionally expansive with the increase in Ag contents. Our results demonstrated that such types of composite nanofibers have a strong potential to be used in biomedicine.

scholarly journals A Tribological and Ion Released Research of Ti-Materials for Medical Devices

Materials ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 131
Author(s):  
Daniela Silva ◽  
Camila Arcos ◽  
Cecilia Montero ◽  
Carolina Guerra ◽  
Carola Martínez ◽  
...  
Keyword(s):  
Metal Ions ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Biological Fluid ◽  
Pure Titanium ◽  
Atomic Emission ◽  
Surface Enhanced Raman Spectroscopy ◽  
Commercially Pure Titanium ◽  
X Ray ◽  
Commercially Pure

The increase in longevity worldwide has intensified the use of different types of prostheses for the human body, such as those used in dental work as well as in hip and knee replacements. Currently, Ti-6Al-4V is widely used as a joint implant due to its good mechanical properties and durability. However, studies have revealed that this alloy can release metal ions or particles harmful to human health. The mechanisms are not well understood yet and may involve wear and/or corrosion. Therefore, in this work, commercial pure titanium and a Ti-6Al-4V alloy were investigated before and after being exposed to a simulated biological fluid through tribological tests, surface analysis, and ionic dissolution characterization by ICP-AES. Before exposure, X-ray diffraction and optical microscopy revealed equiaxed α-Ti in both materials and β-Ti in Ti-6Al-4V. Scratch tests exhibited a lower coefficient of friction for Ti-6Al-4V alloy than commercially pure titanium. After exposure, X-ray photoelectron spectroscopy and surface-enhanced Raman spectroscopy results showed an oxide film formed by TiO2, both in commercially pure titanium and in Ti-6Al-4V, and by TiO and Al2O3 associated with the presence of the alloys. Furthermore, inductively coupled plasma atomic emission spectroscopy revealed that aluminum was the main ion released for Ti-6Al-4V, giving negligible values for the other metal ions.

scholarly journals In vitro bioactivity of glass-ceramic/fibroin composites

2017 ◽  
Vol 11 (2) ◽  
pp. 136-146 ◽  
Author(s):  
Lachezar Radev ◽  
Irena Michailova ◽  
Silviya Stateva ◽  
Diana Zaimova ◽  
Hristo Georgiev ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Atomic Emission ◽  
Xrd Analysis ◽  
In Vitro Tests ◽  
In Vitro Bioactivity ◽  
X Ray ◽  
Before And After ◽  
Static Conditions

Bioactive composite materials were prepared by mixing 20 wt.% of silk fibroin (SF) and 80 wt.% of glassceramics from CaO-SiO2-P2O5-MgO system. In vitro bioactivity of the prepared composites was evaluated in 1.5 simulated body fluid (1.5 SBF) in static conditions. The obtained samples before and after in vitro tests were characterized by X-ray diffraction (XRD) analysis, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The changes in 1.5 SBF solutions after soaking the samples were evaluated by inductively coupled plasma atomic emission spectroscopy (ICP-AES). MG63 osteosarcoma cells were used for the biological experiments. The obtained experimental data proved that the synthesized composites exhibit excellent in vitro bioactivity.

Effect of Aging Methods on CuZnAl Catalysts for Methyl Acetate Hydrogenation

2019 ◽  
Vol 72 (6) ◽  
pp. 417
Author(s):  
Changna Gan ◽  
Yunhao Wang ◽  
Chenliang Ye ◽  
Cuili Guo
Keyword(s):  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Methyl Acetate ◽  
Copper Particle ◽  
Atomic Emission ◽  
Catalytic Performance ◽  
Precipitation Method ◽  
Molar Ratio ◽  
X Ray ◽  
Temperature Programmed

A series of CuZnAl catalysts derived from layered double hydroxide precursors with different Cu/Zn molar ratios were synthesised by a co-precipitation method for methyl acetate hydrogenation. The best catalytic performance was obtained when the Cu/Zn molar ratio reached 0.25:1. After fixing the Cu/Zn molar ratio at 0.25:1, the effect of aging methods, including ultrasound, high shear mixer stirring, and magnetic stirring, were investigated, which showed that 0.25CuZnAl-u and 0.25CuZnAl-h exhibited a higher conversion and selectivity than that of 0.25CuZnAl-m, especially under low reaction temperatures. The physicochemical properties of the CuZnAl catalysts were characterised by X-ray diffraction, inductively coupled plasma–atomic emission spectroscopy, N2 physisorption, N2O chemisorption, transmission electron microscopy, H2-temperature-programmed reduction, X-ray photoelectron spectroscopy, and H2-temperature-programmed desorption. It was found that compared with 0.25CuZnAl-m, 0.25CuZnAl-u and 0.25CuZnAl-h possessed a stronger interaction between Cu and the support, smaller copper particle size, and higher copper dispersion, which improved the catalytic performance.

Solid-solid intercalation and optical properties of VO-8-hydroxyquinoline decoration of layered silicate magadiite

2018 ◽  
Vol 36 (1) ◽  
pp. 134-140
Author(s):  
Yifu Zhang
Keyword(s):  
Optical Properties ◽  
Photoelectron Spectroscopy ◽  
Inductively Coupled Plasma ◽  
Interlayer Space ◽  
Layered Silicate ◽  
Atomic Emission ◽  
Basal Spacing ◽  
Infrared Spectrometry ◽  
Confined Space ◽  
X Ray

AbstractCoordination of vanadyl (VO2+) ions with 8-hydroxyquinoline (8Hq) in the interlayer space of layered silicate magadiite (mag) was realized by solid-solid intercalation. Composition, structure and morphology of this compound were studied by X-ray diffraction (XRD), Fourier-transform infrared spectrometry (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The obtained results indicate that the basal spacing of decorated mag increased after intercalation and suggest that VO-8Hq decorated into the interlayer of mag (VO-mag-8Hq) was successfully synthesized for the first time. Optical properties of VO-mag-8Hq were studied by ultraviolet-visible (UV-Vis) and photoluminescence spectroscopy (PL). The findings reveal that VO-8Hq complexes in the interlayer space exhibit extraordinary fluorescence properties and the confined space of mag influences the optical properties of VO-8Hq complexes.

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