Enhanced Electrokinetic Remediation of Pyrene-Contaminated Soil Through pH Control and Rhamnolipid Addition

2016 ◽  
Vol 33 (7) ◽  
pp. 507-513 ◽  
Author(s):  
Hua Zou ◽  
Wei Du ◽  
Minhui Ji ◽  
Rong Zhu
2020 ◽  
Vol 21 (1) ◽  
pp. 118
Author(s):  
Rudy Syah Putra ◽  
Alfi Ihda Amalia ◽  
Naila Zahrotul Jannah

The removal of cesium from artificially contaminated soil using electrokinetic remediation with nitric and acetic acid as electrolytes had been evaluated. In this study, uncontaminated soil was taken from four different sampling points (i.e., A, B, C, and D) in Kotagede, Yogyakarta, Indonesia. All samples were prepared as cesium contaminated soil (100 mg CsCl/kg soil), which have similar physicochemical characteristics with Fukushima soil, Japan. The electrokinetic remediation (EKR) was conducted using a graphite electrode in a constant voltage of 1.0 Vcm–1 for 7 days without electrolyte pH control, with 1.0 M nitric and acetic acid as electrolytes. The current profile during the EKR was recorded by a data logger for every 10 min. The remaining cesium in the soil was measured by a flame atomic absorption spectrophotometer at a wavelength of 852.1 nm. The results showed that the type of acid used in the experiments affected the removal of cesium. The highest cesium removal was achieved when nitric acid was used in the experiment and then followed by acetic acid. For all acids, the removal ability of cesium from soil was in the following order: soil C > soil A > soil D > soil B.


2021 ◽  
Vol 25 (2) ◽  
pp. 247-253
Author(s):  
Lin Guo ◽  
Xiaocun Zhang ◽  
Yao Chen ◽  
Jun Liu

High concentration of chromium salt has caused serious pollution to the environment since its production. The long-standing chromium residue has polluted the soil, and the total chromium concentration of some polluted soil has reached 30000 mg / kg. For the remediation of chromium contaminated soil, the enhanced electrodynamic method was proposed. In order to improve the efficiency of electrokinetic remediation of chromium contaminated soil, two enhanced electrokinetic remediation technologies were proposed: Electrokinetic oxidation enhanced remediation technology and electrokinetic enhanced remediation technology. (III) in soil was polluted by oxidant chromium oxide to increase the content of dissolved (VI),so as to improve the efficiency of electric repair, in order to find a suitable PRB medium as a breakthrough to improve the repair efficiency. The experimental results show that compared with the traditional electrodynamic technology, the enhanced electrodynamic method can effectively improve the removal rate of total chromium in the soil, and provide technical support for the enhanced electrodynamic remediation of chromium contaminated soil. The pH control system makes the pH of anode and cathode electrolyte always maintain acidic, and the H+ migration speed is faster than that of OH-, and the pH of soil near the anode is lower than that near the cathode.


Chemosphere ◽  
2013 ◽  
Vol 90 (8) ◽  
pp. 2326-2331 ◽  
Author(s):  
Long Cang ◽  
Guang-Ping Fan ◽  
Dong-Mei Zhou ◽  
Quan-Ying Wang

2012 ◽  
Vol 518-523 ◽  
pp. 361-368 ◽  
Author(s):  
Rong Bing Fu ◽  
Xin Xing Liu ◽  
Fang Liu ◽  
Jin Ma ◽  
Yu Mei Ma ◽  
...  

A new permeable reactive composite electrode (PRCE) attached with a permeable reactive layer (PRL) of Fe0 and zeolite has been developed for soil pH control and the improved removal efficiency of heavy metal ions (Cd, Ni, Pb, Cu) from soil in electrokinetic remediation process. The effects of different composite electrodes on pH control and heavy metal removal efficiency were studied, and changes in the forms of heavy metals moved onto the electrodes were analyzed. The results showed that with acidic/alkaline zeolite added and renewed in time, the composite electrodes could effectively neutralize and capture H+ and OH- produced from electrolysis of the anolyte and catholyte, avoiding or delaying the formation of acidic/alkaline front in tested soil, preventing premature precipitation of heavy metal ions and over-acidification of soil, and thus significantly improved the heavy metal removal efficiency. Fe0 in composite electrodes could deoxidize and stabilize the heavy metal ions. After that capture and immobilization of the pollutants were achieved. The results also showed that, using "Fe0 + zeolite" PRCE in the cathode with timely renewal, after 15-day remediation with a DC voltage of 1.5 V/cm, the total removal rates of Cd, Pb, Cu and Ni were 49.4%, 47.1%, 36.7% and 39.2%, respectively.


2021 ◽  
Vol 416 ◽  
pp. 125806
Author(s):  
Yi Zheng ◽  
Huilin Li ◽  
Qiu Yu ◽  
Lin Yu ◽  
Binquan Jiao ◽  
...  

2018 ◽  
Vol 190 ◽  
pp. 297-306 ◽  
Author(s):  
Ming Zhou ◽  
Jingming Xu ◽  
Shufa Zhu ◽  
Yajing Wang ◽  
Hui Gao

2018 ◽  
Vol 777 ◽  
pp. 256-261 ◽  
Author(s):  
André Ribeiro ◽  
André Mota ◽  
Margarida Soares ◽  
Carlos Castro ◽  
Jorge Araújo ◽  
...  

Electrokinetic remediation deserves particular attention in soil treatment due to its peculiar advantages, including the capability of treating fine and low permeability materials, and achieving consolidation, dewatering and removal of salts and inorganic contaminants like heavy metals in a single stage. In this study, the remediation of artificially lead (II) contaminated soil by electrokinetic process, coupled with Eggshell Inorganic Fraction Powder (EGGIF) permeable reactive barrier (PRB), was investigated. An electric field of 2 V cm-1was applied and was used an EGGIF/soil ratio of 30 g kg-1 of contaminated soil for the preparation of the permeable reactive barrier (PRB) in each test. It was obtained high removal rates of lead in both experiments, especially near the cathode. In the normalized distance to cathode of 0.2 it was achieved a maximum removal rate of lead (II) of 68, 78 and 83% in initial lead (II) concentration of 500 mg-1, 200 mg-1 and 100 mg-1, respectively. EGGIF (Eggshell Inorganic Fraction) proved that can be used as permeable reactive barrier (PRB) since in all the performed tests were achieved adsorptions yields higher than 90%.


2021 ◽  
Author(s):  
Zongping Cai ◽  
Yan Sun ◽  
Yanghong Deng ◽  
Xiaojie Zheng ◽  
Shuiyu Sun ◽  
...  

Abstract This study compared electrokinetic (EK) remediation with and without interval power breaking in the removal of total and plant available cadmium (Cd) in the soil. Two laboratory experiments, i.e. EK remediation with interval power breaking (24-12 h power-on-off cycles) and conventional EK remediation (continuous power supply) with the same accumulated time (192 h) of power supply were conducted to remove soil Cd. After the EK remediation by interval power breaking, the total Cd removal efficiency in the soil rose to 38%, in comparison to 28% by the conventional EK remediation. As for the plant available Cd, the removal efficiency was enhanced from 52% to 63%. Additionally, the electric current during the EK remediation and electric conductivity after the EK remediation were higher in the soil treated by interval power breaking, which indicated an enhanced desorption and/or migration of charged species. It further meant that the higher removal efficiency of soil Cd by interval power breaking could be related to the enhanced desorption and/or migration of Cd species. This study indicated that both conventional EK remediation and EK remediation with interval power breaking were effective methods to remove soil Cd but EK remediation with interval power breaking was more efficient.


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