scholarly journals On the Putative Detection ofz> 0 X‐Ray Absorption Features in the Spectrum of Mrk 421

2007 ◽  
Vol 656 (1) ◽  
pp. 129-138 ◽  
Author(s):  
Andrew P. Rasmussen ◽  
Steven M. Kahn ◽  
Frits Paerels ◽  
Jan Willem den Herder ◽  
Jelle Kaastra ◽  
...  
2002 ◽  
Vol 386 (3) ◽  
pp. 910-915 ◽  
Author(s):  
A. N. Parmar ◽  
T. Oosterbroek ◽  
L. Boirin ◽  
D. Lumb

2002 ◽  
Vol 385 (3) ◽  
pp. 940-946 ◽  
Author(s):  
L. Sidoli ◽  
A. N. Parmar ◽  
T. Oosterbroek ◽  
D. Lumb

MRS Advances ◽  
2021 ◽  
Author(s):  
Lewis R. Blackburn ◽  
Max R. Cole ◽  
Laura J. Gardner ◽  
Daniel J. Bailey ◽  
Merve Kuman ◽  
...  

Abstract A sample of zirconolite with nominal composition Ca0.80Ce0.20ZrTi1.60Cr0.40O7 was processed via Hot Isostatic Pressing (HIP), with a dwell temperature and pressure of 1320 °C/100 MPa maintained for 4 h. The produced wasteform was characterised by powder XRD, SEM–EDS, Ce L3 and Cr K-edge XANES. A significant portion of the Ce inventory did not fully partition within the zirconolite phase, instead remaining as CeO2 within the microstructure. Inspection of the stainless steel–ceramic interface detailed the presence of an interaction region dominated by a Cr-rich oxide layer. No significant Cr or Fe migration was observed, although a greater concentration of perovskite was observed at the periphery, relative to the bulk ceramic matrix. The X-ray absorption features of Cr remained analogous with Cr3+ accommodation within TiO6 octahedra in the zirconolite matrix. The absorption edge of Ce was comprised of contributions from zirconolite-2M and unincorporated CeO2, with an average oxidation state of Ce3.9+. As zirconolite-2M accounted for > 92 wt% of the overall phase assemblage, it is clear that the dominant oxidation state of Ce in this phase was Ce4+. Graphic abstract


2006 ◽  
Vol 641 (2) ◽  
pp. L157-L160 ◽  
Author(s):  
E. W. Schmidt ◽  
S. Schippers ◽  
A. Müller ◽  
M. Lestinsky ◽  
F. Sprenger ◽  
...  

1997 ◽  
Vol 166 ◽  
pp. 165-168
Author(s):  
Jürgen Kerp ◽  
Jochen Pietz

AbstractWe present new results based on the analysis of ROSAT PSPC observations towards nearby neutral clouds. These clouds are detectable as deep soft X-ray absorption features within the ¼ keV energy band. Towards one of these clouds, optical absorption line measurements determine an upper distance limit of D ≤ 60 pc. The presented data suggest that this filament is only a part of a much more extended local–cloud structure. Here we demonstrate that we most probably detected a local neutral atomic hydrogen “wall” in the direction of a low–velocity arc (Pietz 1994).


2004 ◽  
Vol 418 (3) ◽  
pp. 1061-1072 ◽  
Author(s):  
L. Boirin ◽  
A. N. Parmar ◽  
D. Barret ◽  
S. Paltani ◽  
J. E. Grindlay

2020 ◽  
Vol 492 (4) ◽  
pp. 5634-5640
Author(s):  
Itay Gissis ◽  
Uria Peretz ◽  
Ehud Behar

ABSTRACT Hot ionized gas is observed in the local vicinity of our galaxy through spectral absorption features. The most common hypothesis is that this gas forms a halo surrounding our Milky Way, in collisional ionization equilibrium. In this paper, we investigate the elemental abundance of this hot and ionized local gas. We use a 2.4 Ms stacked X-ray spectrum of the bright blazar 3C 273 and probe the local absorption features. Using ion-by-ion fitting of the X-ray absorption lines, we derive the column density of each ionization species. Based on the column densities, we reconstruct the absorption measure distribution, namely the hydrogenic column density as a function of temperature. We report the elemental abundances of C, N, Ne, and Fe relative to solar O. Previous measurements of local X-ray emission lines in conjunction with the present column densities indicate a scale height of 1–80 kpc and hydrogen number density of 10−4–10−3 cm−3 for the hot ionized gas. Additionally, we detect He-like O lines from the quasar broad line region with velocities of 6400 ± 1500 km s−1.


2015 ◽  
Vol 17 (43) ◽  
pp. 29000-29006 ◽  
Author(s):  
Ronny Golnak ◽  
Jie Xiao ◽  
Kaan Atak ◽  
Joanna S. Stevens ◽  
Adrian Gainar ◽  
...  

Characteristic X-ray absorption features indicate the extent of hemin intermolecular bonding interaction.


2021 ◽  
Vol 5 (4) ◽  
pp. 28
Author(s):  
Amith G. Anil ◽  
Sufal Swaraj ◽  
Sankaran Subramanian ◽  
Praveen C. Ramamurthy

Scanning transmission X-ray microscopy (STXM) was utilized for analysing the bioremediation of Cr(VI) by Citrobacter freundii, a species of gram-negative bacteria. The biosorption and bioreduction processes were analysed by the chemical mapping of cells biosorbed at different concentrations of Cr(VI). STXM spectromicroscopy images were recorded at O K-edge and Cr L-edge. A thorough analysis of the X-ray absorption features corresponding to different oxidation states of Cr in the biosorbed cell indicated the coexistence of Cr(III) and Cr(VI) at higher concentrations. This signifies the presence of partially reduced Cr(VI) in addition to biosorbed Cr(VI). In addition, the Cr(III) signal is intense compared with Cr(VI) at different regions of the cell indicating excess of reduced Cr. Speciation of adsorbed Cr was analysed for the spectral features of biosorbed cell and comparison with Cr standards. Analysis of absorption onset, L3/L2 ratio and absorption fine structure concludes that adsorbed Cr is predominantly present as Cr(III) hydroxide or oxyhydroxide. The evolution of absorption features in the duration of biosorption process was also studied. These time lapse studies depict the gradual decrement in Cr(VI) signal as biosorption proceeds. A strong evidence of interaction of Cr with the cell material was also observed. The obtained results provide insights into the biosorption process and chemical speciation of Cr on the cells.


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