Interstellar Sulfur Monoxide

Millimeter Wave Spectroscopy of Unstable Molecular Species. II. Sulfur Monoxide

The Journal of Chemical Physics ◽

10.1063/1.1726146 ◽

1964 ◽

Vol 41 (6) ◽

pp. 1687-1691 ◽

Cited By ~ 50

Author(s):

Manfred Winnewisser ◽

K. V. L. N. Sastry ◽

R. L. Cook ◽

Walter Gordy

Keyword(s):

Millimeter Wave ◽

Molecular Species ◽

Millimeter Wave Spectroscopy ◽

Sulfur Monoxide

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A vacuum-ultraviolet laser pulsed field ionization-photoelectron study of sulfur monoxide (SO) and its cation (SO+)

The Journal of Chemical Physics ◽

10.1063/1.3575227 ◽

2011 ◽

Vol 134 (14) ◽

pp. 144304 ◽

Cited By ~ 10

Author(s):

Chow-Shing Lam ◽

Hailing Wang ◽

Yuntao Xu ◽

Kai-Chung Lau ◽

C. Y. Ng

Keyword(s):

Vacuum Ultraviolet ◽

Field Ionization ◽

Ultraviolet Laser ◽

Pulsed Field ◽

Sulfur Monoxide ◽

Pulsed Field Ionization ◽

Photoelectron Study ◽

Vacuum Ultraviolet Laser

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Spectra of the 10–01 Transition of Sulfur Monoxide in Interstellar Clouds

Interstellar Molecules ◽

10.1007/978-94-009-9097-5_14 ◽

1980 ◽

pp. 71-76

Author(s):

O. E. H. Rydbeck ◽

Å. Hjalmarson ◽

G. Rydbeck ◽

J. Elldér ◽

E. Kollberg ◽

...

Keyword(s):

Interstellar Clouds ◽

Sulfur Monoxide

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Side-On OMoF2(η2-SO) and OWF2(η2-SO) Complexes Featuring Peroxo-Like Sulfur Monoxide Ligand

Inorganic Chemistry ◽

10.1021/acs.inorgchem.9b02766 ◽

2019 ◽

Vol 58 (22) ◽

pp. 15652-15658 ◽

Cited By ~ 2

Author(s):

Rui Wei ◽

Xiuting Chen ◽

Yu Gong

Keyword(s):

Sulfur Monoxide

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Reactivity of Small Oxoacids of Sulfur

Molecules ◽

10.3390/molecules24152768 ◽

2019 ◽

Vol 24 (15) ◽

pp. 2768 ◽

Cited By ~ 4

Author(s):

Sergei V. Makarov ◽

Attila K. Horváth ◽

Anna S. Makarova

Keyword(s):

Atmospheric Chemistry ◽

Sulfide Oxidation ◽

Chemical Properties ◽

Sulfenic Acid ◽

Biochemical Processes ◽

Sulfur Monoxide ◽

Physical And Chemical ◽

Sulfoxylic Acid ◽

Sulfur Containing ◽

Reducing Properties

Oxidation of sulfide to sulfate is known to consist of several steps. Key intermediates in this process are the so-called small oxoacids of sulfur (SOS)—sulfenic HSOH (hydrogen thioperoxide, oxadisulfane, or sulfur hydride hydroxide) and sulfoxylic S(OH)2 acids. Sulfur monoxide can be considered as a dehydrated form of sulfoxylic acid. Although all of these species play an important role in atmospheric chemistry and in organic synthesis, and are also invoked in biochemical processes, they are quite unstable compounds so much so that their physical and chemical properties are still subject to intense studies. It is well-established that sulfoxylic acid has very strong reducing properties, while sulfenic acid is capable of both oxidizing and reducing various substrates. Here, in this review, the mechanisms of sulfide oxidation as well as data on the structure and reactivity of small sulfur-containing oxoacids, sulfur monoxide, and its precursors are discussed.

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