scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1944 ◽  
Vol 28 (1) ◽  
pp. 1-15 ◽  
Author(s):  
Karl Sollner ◽  
Charles W. Carr
Keyword(s):  
Experimental Data ◽  
Electrochemical Activity ◽  
Structural Factors ◽  
Electrical Behavior ◽  
Base Exchange ◽  
Basic Assumptions ◽  
Potentiometric Selectivity ◽  
Concentration Potential ◽  
Order Of Magnitude ◽  
Concentration Levels

1. The Teorell, Meyer-Sievers theory characterizes the electrochemical behavior of membranes by their selectivity constant "Ap" which is derived conventionally from concentration potential measurements at various concentration levels. The selectivity constant may, however, be derived also from entirely independent, different experimental data, namely base exchange studies. The constants arrived at in this second way are designated as "Ab." The selectivity constants derived by these two methods must be in reasonable, at least semiquantitative agreement if the basic assumptions of the theory are correct. 2. The selectivity constants Ap and Ab were determined for eleven different sets of membranes of different electrochemical activity and of different (8.2 to 80 volume per cent) water content. 3. The potentiometric selectivity constants Ap are in most cases several orders of magnitude greater than the corresponding Ab values. With membranes of great porosity and high electrochemical activity the Ab values approach at least in order of magnitude the Ap values. 4. It is concluded that the unexpectedly large discrepancy between the Ap and Ab values is due to some inherent weakness of the Teorell, Meyer-Sievers theory, most likely to its neglect of any structural factors.

scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1943 ◽  
Vol 26 (3) ◽  
pp. 309-323 ◽  
Author(s):  
Karl Sollner ◽  
Charles W. Carr
Keyword(s):  
Structural Theory ◽  
Electrochemical Activity ◽  
Electrical Behavior ◽  
Phase Theory ◽  
Varying Thickness ◽  
Maximum Value ◽  
Electrochemically Active ◽  
Concentration Potential ◽  
Characteristic Concentration ◽  
Constant Maximum

1. Experiments were carried out to decide whether or not the electromotive properties of dried collodion membranes depend upon their thickness. 2. A number of dried collodion membranes of varying thickness, 3–160 µ, were prepared from collodion preparations of different electrochemical activity. The characteristic concentration potentials across them were measured and the means of these values determined for each thickness. 3. The characteristic concentration potentials across dried collodion membranes are a function of their thickness. The thinnest membranes yield in all cases the lowest concentration potentials; increasingly thicker membranes give increasingly higher potential values, until a constant value is reached which is characteristic of the particular collodion preparation used. With electrochemically active collodion, characteristic concentration potentials approaching the thermodynamically possible maximum are obtained with membranes of only 10 µ thickness, thinner membranes giving appreciably lower values. With two rather inactive commercial collodion preparations the characteristic concentration potential increases from about 30 mv. for membranes 3 µ thick to about 42 mv. for 20 µ membranes; still thicker membranes do not show a significant increase in the potential values. With a highly purified collodion preparation the constant maximum value was found to be about 32 mv., 4 µ thick membranes giving only about 22 mv. 4. These results do not support the homogeneous phase theory as applied to the dried collodion membrane. They are readily compatible with the micellar-structural theory. Several special possible cases of the latter as applied to the dried collodion membrane are discussed.

scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1942 ◽  
Vol 25 (3) ◽  
pp. 411-429 ◽  
Author(s):  
Karl Sollner ◽  
Charles W. Carr ◽  
Irving Abrams
Keyword(s):  
Quantitative Measure ◽  
Exchange Capacity ◽  
Electrochemical Activity ◽  
Electrical Behavior ◽  
Exchange Method ◽  
Base Exchange ◽  
High Base ◽  
Different Origins ◽  
Theoretical Considerations ◽  
Exchange Properties

1. Theoretical considerations lead to the conclusion that dissociable acidic groups present to a varying extent in different collodion preparations determine the electrochemical behavior of membranes cast from these preparations. It is further reasoned that the base exchange capacity of the collodion surfaces is the true quantitative measure of the abundance of the dissociable groups. 2. The concept of base exchange capacity and the base exchange method are discussed. The conditions which allow a purposeful application of the latter are stated. 3. The base exchange properties of a number of fibrous collodion preparations of different origins and after various types of treatment, having widely varying electrochemical activities, are determined. 4. With the chemical (titration) and physical (electrometric) methods employed, no regular correlation can be found between electrochemical activity and base exchange. The base exchange capacity which is necessary to cause even great electrochemical activity of collodion is extremely small. 5. Measurable to high base exchange capacity always seems to be associated with good or high electrochemical activity; but base exchange capacity too low to be definitely measurable with the available methods may be found with collodion preparations of high as well as with preparations of low electrochemical activity. 6. The bearing of these results upon the problem of the spatial and electrical structure of the collodion membrane is indicated briefly.

Diagnostics of metal samples using the results of experimental and theoretical study of positively charged microparticles formed upon sample destruction

2018 ◽  
Vol 84 (10) ◽  
pp. 23-28
Author(s):  
D. A. Golentsov ◽  
A. G. Gulin ◽  
Vladimir A. Likhter ◽  
K. E. Ulybyshev
Keyword(s):  
Experimental Data ◽  
Early Stage ◽  
Experimental Studies ◽  
Material Model ◽  
Total Charge ◽  
Cross Sectional ◽  
Practical Applications ◽  
Mechanical And Electrical Properties ◽  
Order Of Magnitude ◽  
Using Data

Destruction of bodies is accompanied by formation of both large and microscopic fragments. Numerous experiments on the rupture of different samples show that those fragments carry a positive electric charge. his phenomenon is of interest from the viewpoint of its potential application to contactless diagnostics of the early stage of destruction of the elements in various technical devices. However, the lack of understanding the nature of this phenomenon restricts the possibility of its practical applications. Experimental studies were carried out using an apparatus that allowed direct measurements of the total charge of the microparticles formed upon sample rupture and determination of their size and quantity. The results of rupture tests of duralumin and electrical steel showed that the size of microparticles is several tens of microns, the particle charge per particle is on the order of 10–14 C, and their amount can be estimated as the ratio of the cross-sectional area of the sample at the point of discontinuity to the square of the microparticle size. A model of charge formation on the microparticles is developed proceeding from the experimental data and current concept of the electron gas in metals. The model makes it possible to determine the charge of the microparticle using data on the particle size and mechanical and electrical properties of the material. Model estimates of the total charge of particles show order-of-magnitude agreement with the experimental data.

Comparison of soot models for reacting sprays in diesel engine-like conditions

2021 ◽  
pp. 095440702110154
Author(s):  
Pavan Prakash Duvvuri ◽  
Rajesh Kumar Shrivastava ◽  
Sheshadri Sreedhara
Keyword(s):  
Experimental Data ◽  
Volume Fraction ◽  
Soot Volume Fraction ◽  
Modeling Framework ◽  
Aerosol Dynamics ◽  
Significant Difference ◽  
Polycyclic Aromatic ◽  
Order Of Magnitude ◽  
Detailed Kinetics ◽  
Soot Model

Stringent emission legislations and growing health concerns have contributed to the evolution of soot modeling in diesel engines from simple empirical relations to methods involving detailed kinetics and complex aerosol dynamics. In this paper, four different soot models have been evaluated for the high temperature, high pressure combusting dodecane spray cases of engine combustion network (ECN) spray A which mimics engine-relevant conditions. The soot models considered include an empirical, a multistep, a method of moments based, and a discrete sectional method soot model. Two experimental cases with ambient oxygen volume of 21% and 15% have been modeled. A good agreement between simulations and experiments for vapor penetration and heat release rate has been obtained. Quasi-steady soot volume fraction contours for the four soot models have been compared with experiments. Contours of the species and source terms involved in soot modeling have also been compared for a better understanding of soot processes. The empirical soot model results in higher magnitude and spread of soot due to a lack of modeling framework for oxidation through OH species. Among the four models studied, the multistep soot model has been observed to provide the most promising agreement with the experimental data in terms of distribution of soot and location of peak soot volume fraction. Due to a two-way coupling of soot models, the detailed models predict an upstream location for soot as compared to the multi-step soot model which is one way coupled. A significant difference (of an order of magnitude) in the concentration of PAH (polycyclic aromatic hydrocarbons) precursor between multistep and detailed soot models has been observed because of precursor consumption due to the coupling of detailed soot models with chemical kinetics. It is recommended that kinetic schemes, especially those concerning PAH, be validated with experimental data with a kinetics-coupled soot model.

Rate of oxygen loss from arterioles is an order of magnitude higher than expected

1989 ◽  
Vol 256 (3) ◽  
pp. H921-H924 ◽  
Author(s):  
A. S. Popel ◽  
R. N. Pittman ◽  
M. L. Ellsworth
Keyword(s):  
Experimental Data ◽  
Oxygen Flux ◽  
Cheek Pouch ◽  
Retractor Muscle ◽  
Hamster Cheek Pouch ◽  
Oxygen Loss ◽  
Order Of Magnitude ◽  
Solubility Coefficients ◽  
Tissue Permeability

The experimental data on oxygen flux from arterioles in the hamster cheek pouch retractor muscle [L. Kuo and R. N. Pittman, Am. J. Physiol. 254 (Heart Circ. Physiol. 23): H331-H339, 1988] were analyzed under the assumption that the permeability to oxygen is the same in both perfused and unperfused tissue; permeability is defined as the product of the diffusion and solubility coefficients. However, our analysis indicated that the observed oxygen flux was inconsistent with this assumption and that permeability to oxygen of a blood-perfused tissue may be an order of magnitude higher than previously assumed.

scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1944 ◽  
Vol 27 (5) ◽  
pp. 433-449 ◽  
Author(s):  
Karl Sollner ◽  
Joan Anderman
Keyword(s):  
Solvent Mixture ◽  
Exchange Capacity ◽  
Acid Number ◽  
Electrochemical Activity ◽  
Time Base ◽  
Equivalent Weight ◽  
Base Exchange ◽  
Electrochemically Active ◽  
Organic Solvent Mixture ◽  
High Base

1. The electrochemical behavior ("activity") of collodion membranes depends upon acidic, dissociable groups located in the interstices of the membranes. The active groups can be determined by base exchange measurements. High base exchange capacity is always found with preparations of great "electrochemical activity;" medium and low base exchange capacities occur with electrochemically active as well as with inactive preparations. The observed base exchange capacity is determined by two factors: the inherent acidity of the collodion (its mean equivalent weight) and the submicroscopic micellar structure of the collodion. A comparison of the base exchange capacity of various collodion preparations and their inherent acidities therefore allows certain conclusions to be drawn concerning the relative availability of the micellar surfaces in the different preparations. 2. The inherent acidity of various collodion preparations, their "acid number," was determined by electrometric titration. Collodion in the acidic state, i.e. after exchange of all other cations for H+ ions, was titrated in an organic solvent mixture with alcoholic KOH using a quinhydrone electrode. Details of the experimental procedure are given in the paper. The acid numbers, expressed in milliliters of 0.01 N KOH per gram dry collodion, vary from 1.0 for a highly purified collodion preparation of very low electrochemical activity to 3.3 for a highly oxidized sample of very high activity. Acid numbers of about 1.5 (corresponding to an equivalent weight of about 67,000) are found both with inactive commercial and with fairly active oxidized preparations. The base exchange capacity of the same preparations in the fibrous state as measured after 48 hours of exchange time varies from 0.0013 ml. 0.01 N NaOH per gm. dry collodion for the most inactive preparation up to 0.26 ml. 0.01 N NaOH per gm. for the most active preparation. Thus the acid numbers over the whole range investigated differ only in the ratio of 1:3.3, whereas the base exchange values differ in the range of 1:200. 3. In the inactive preparation only one in 770 acid groups is available for base exchange, in the most active collodion one group in 13; values between these extremes are found with commercial and alcohol purified oxidized preparations. 4. The high base exchange capacity of the electrochemically active preparations is not so much due to their higher acid number as to their more open structure. This difference in structure is ascribed to the presence of a small fraction of low molecular weight material which inhibits normal formation and arrangement of the micelles. 5. Short time base exchange experiments with fibrous collodion indicate that the number of acid groups available for the typical electrochemical membrane functions may be estimated to be about 50 to 1000 times less numerous than those found in the 48 hour base exchange experiments. It is estimated that in membranes prepared even from the most active collodion not more than one in 500 acid groups may be available for the typical membrane functions; with the less active preparations this ratio is estimated to be as high as one in 1,000,000 or more.

scholarly journals Design aspects of Bi2Sr2CaCu2O8+δ THz sources: optimization of thermal and radiative properties

2021 ◽  
Author(s):  
Mikhail M Krasnov ◽  
Natalia D Novikova ◽  
Roger Cattaneo ◽  
Alexey A Kalenyuk ◽  
Vladimir M Krasnov
Keyword(s):  
Experimental Data ◽  
Power Efficiency ◽  
Open Space ◽  
Radiation Power ◽  
Impedance Matching ◽  
Dipole Antenna ◽  
Radiative Properties ◽  
Heat Management ◽  
Order Of Magnitude ◽  
Thz Sources

Impedance matching and heat management are important factors influencing performance of THz sources. In this work we analyze thermal and radiative properties of such devices based on mesa structures of a layered high-temperature superconductor Bi2Sr2CaCu2O8+δ. Two types of devices are considered, containing either a conventional large single crystal, or a whisker. We perform numerical simulations for various geometrical configurations and parameters and make a comparison with experimental data for the two types of devices. It is demonstrated that the structure and the geometry of both the superconductor and the electrodes are playing important roles. In crystal-based devices an overlap between the crystal and the electrode leads to appearance of a large parasitic capacitance, which shunts THz emission and prevents impedance matching with open space. The overlap is avoided in whisker-based devices. Furthermore, the whisker and the electrodes form a turnstile (crossed-dipole) antenna facilitating good impedance matching. This leads to more than an order of magnitude enhancement of the radiation power efficiency in whisker-based, compared to crystal-based devices. These results are in good agreement with presented experimental data.

Parallel Multi-Cycle LES of an Optical Pent-Roof DISI Engine Under Motored Operating Conditions

2017 ◽  
Author(s):  
Noah Van Dam ◽  
Wei Zeng ◽  
Magnus Sjöberg ◽  
Sibendu Som
Keyword(s):  
Experimental Data ◽  
Direct Injection ◽  
Operating Conditions ◽  
New Strategy ◽  
Long Time ◽  
Order Of Magnitude ◽  
Structure Index ◽  
Number Of Cycles ◽  
The Many ◽  
Direct Injection Spark Ignition

The use of Large-eddy Simulations (LES) has increased due to their ability to resolve the turbulent fluctuations of engine flows and capture the resulting cycle-to-cycle variability. One drawback of LES, however, is the requirement to run multiple engine cycles to obtain the necessary cycle statistics for full validation. The standard method to obtain the cycles by running a single simulation through many engine cycles sequentially can take a long time to complete. Recently, a new strategy has been proposed by our research group to reduce the amount of time necessary to simulate the many engine cycles by running individual engine cycle simulations in parallel. With modern large computing systems this has the potential to reduce the amount of time necessary for a full set of simulated engine cycles to finish by up to an order of magnitude. In this paper, the Parallel Perturbation Methodology (PPM) is used to simulate up to 35 engine cycles of an optically accessible, pent-roof Direct-injection Spark-ignition (DISI) engine at two different motored engine operating conditions, one throttled and one un-throttled. Comparisons are made against corresponding sequential-cycle simulations to verify the similarity of results using either methodology. Mean results from the PPM approach are very similar to sequential-cycle results with less than 0.5% difference in pressure and a magnitude structure index (MSI) of 0.95. Differences in cycle-to-cycle variability (CCV) predictions are larger, but close to the statistical uncertainty in the measurement for the number of cycles simulated. PPM LES results were also compared against experimental data. Mean quantities such as pressure or mean velocities were typically matched to within 5–10%. Pressure CCVs were under-predicted, mostly due to the lack of any perturbations in the pressure boundary conditions between cycles. Velocity CCVs for the simulations had the same average magnitude as experiments, but the experimental data showed greater spatial variation in the root-mean-square (RMS). Conversely, circular standard deviation results showed greater repeatability of the flow directionality and swirl vortex positioning than the simulations.

Drill String Vibrations Due to Intermittent Contact of Bit Teeth

1963 ◽  
Vol 85 (2) ◽  
pp. 187-194 ◽  
Author(s):  
P. R. Paslay ◽  
D. B. Bogy
Keyword(s):  
Experimental Data ◽  
Penetration Rate ◽  
Drill String ◽  
String Vibrations ◽  
Order Of Magnitude ◽  
Intermittent Contact ◽  
Maximum Penetration ◽  
Sufficient Magnitude ◽  
Force Excitation ◽  
Practical Measurement

An analysis of the longitudinal forces and the resulting longitudinal motions of an idealized drill string is presented. The only external force excitation considered occurs at the bit and is due to the intermittent contact of the teeth with the bottom of the hole. Attention has been restricted to the following two salient possibilities: 1 - Excitation at the bit may develop oscillating forces at the bit with amplitudes of the same order of magnitude as those of the bit load. 2 - Appreciable bit load variation may be detected by instruments which measure the motion of the drill string near its top. The first possibility is important if maximum penetration rate is to be achieved, and the second possibility is important in implementing practical measurement of the phenomenon. From the results of the specific example considered in this report, it is concluded that possibilities 1 and 2 may occur in sufficient magnitude to be influential, but experimental data on the actual bit motion and the damping will be required to evaluate the effect. The analysis is presented in such form that the influence of the various parts of the system can easily be evaluated.

An improved value for the electron affinity of the negative hydrogen ion

1979 ◽  
Vol 57 (4) ◽  
pp. 558-563 ◽  
Author(s):  
Leonard R. Scherk
Keyword(s):  
Experimental Data ◽  
Electric Field ◽  
Electron Affinity ◽  
Hydrogen Ion ◽  
Negative Ion ◽  
Static Electric Field ◽  
Order Of Magnitude ◽  
Negative Hydrogen Ion

An expression is derived for the lifetime of a negative ion in a weak and static electric field. Using this expression, existing experimental data are analyzed to improve the empirical value of the electron affinity of the negative hydrogen ion by an order of magnitude.

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