Nanosized Polystyrene/Poly(Butyl Acrylate) Core‐Shell Latex Particles Functionalized with Acrylamides

L'udmila Černáková; Viera Chrástová; Petra Volfová

doi:10.1081/ma-200054336

Nanosized Polystyrene/Poly(Butyl Acrylate) Core‐Shell Latex Particles Functionalized with Acrylamides

Journal of Macromolecular Science Part A ◽

10.1081/ma-200054336 ◽

2005 ◽

Vol 42 (4) ◽

pp. 427-439 ◽

Cited By ~ 6

Author(s):

L'udmila Černáková ◽

Viera Chrástová ◽

Petra Volfová

Keyword(s):

Butyl Acrylate ◽

Core Shell ◽

Latex Particles

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Preparation of core–shell latex particles by emulsion co-polymerization of styrene and butyl acrylate, and evaluation of their pigment properties in emulsion paints

Journal of Coatings Technology and Research ◽

10.1007/s11998-010-9265-2 ◽

2010 ◽

Vol 7 (6) ◽

pp. 765-772 ◽

Cited By ~ 23

Author(s):

Lakhya J. Borthakur ◽

Tirthankar Jana ◽

S. K. Dolui

Keyword(s):

Butyl Acrylate ◽

Core Shell ◽

Latex Particles

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Core-shell structured latex particles. I. Copolymerization of styrene/benzyl methacrylate as a choice for shell material and characterization of poly(n-butyl acrylate) core latex particles

Journal of Applied Polymer Science ◽

10.1002/app.1995.070580218 ◽

1995 ◽

Vol 58 (2) ◽

pp. 385-399 ◽

Cited By ~ 6

Author(s):

I. Segall ◽

V. L. Dimonie ◽

M. S. El-Aasser ◽

P. R. Soskey ◽

S. G. Mylonakis

Keyword(s):

Butyl Acrylate ◽

Core Shell ◽

Shell Material ◽

Latex Particles

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Synthesis and characterization of core–shell polysilsesquioxane-poly(styrene-butyl acrylate-fluorinated acrylate) hybrid latex particles

Colloids and Surfaces A Physicochemical and Engineering Aspects ◽

10.1016/j.colsurfa.2012.01.003 ◽

2012 ◽

Vol 396 ◽

pp. 251-257 ◽

Cited By ~ 32

Author(s):

Ruiqin Bai ◽

Teng Qiu ◽

Min Duan ◽

Guiling Ma ◽

Lifan He ◽

...

Keyword(s):

Butyl Acrylate ◽

Synthesis And Characterization ◽

Core Shell ◽

Latex Particles ◽

Fluorinated Acrylate ◽

Hybrid Latex

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Core-shell structured latex particles. III. Structure–properties relationship in toughening of polycarbonate with poly(n-butyl acrylate)/poly(benzyl methacrylate–styrene) structured latex particles

Journal of Applied Polymer Science ◽

10.1002/app.1995.070580220 ◽

1995 ◽

Vol 58 (2) ◽

pp. 419-425 ◽

Cited By ~ 2

Author(s):

I. Segall ◽

V. L. Dimonie ◽

M. S. El-Aasser ◽

P. R. Soskey ◽

S. G. Mylonakis

Keyword(s):

Butyl Acrylate ◽

Core Shell ◽

Latex Particles ◽

Structure Properties

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Core—shell structured latex particles. II. Synthesis and characterization of poly(n-butyl acrylate)/poly(benzyl methacrylate—styrene) structured latex particles

Journal of Applied Polymer Science ◽

10.1002/app.1995.070580219 ◽

1995 ◽

Vol 58 (2) ◽

pp. 401-417 ◽

Cited By ~ 14

Author(s):

I. Segall ◽

V. L. Dimonie ◽

M. S. El-Aasser ◽

P. R. Soskey ◽

S. G. Mylonakis

Keyword(s):

Butyl Acrylate ◽

Synthesis And Characterization ◽

Core Shell ◽

Latex Particles

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Microstructural Characterization of Methyl Methacrylate andn-Butyl Acrylate Gradient Latex Particles by Nuclear Magnetic Resonance

International Journal of Polymer Analysis and Characterization ◽

10.1080/1023666x.2012.692944 ◽

2012 ◽

Vol 17 (6) ◽

pp. 428-443 ◽

Cited By ~ 2

Author(s):

Xinya Zhang ◽

Hui Su ◽

Delong Xie ◽

Huanqin Chen

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Methyl Methacrylate ◽

Butyl Acrylate ◽

Microstructural Characterization ◽

Latex Particles ◽

Nuclear Magnetic

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Synthesis and properties of fluorine-silicon modified polyacrylate hybrid latex particles with core-shell structure obtained via emulsifier-free emulsion polymerization

Polymer International ◽

10.1002/pi.4926 ◽

2015 ◽

Vol 64 (10) ◽

pp. 1373-1380 ◽

Cited By ~ 7

Author(s):

Jianhua Zhou ◽

Xin Chen ◽

Hao Duan ◽

Jianzhong Ma

Keyword(s):

Emulsion Polymerization ◽

Shell Structure ◽

Core Shell ◽

Latex Particles ◽

Core Shell Structure ◽

Hybrid Latex

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Core-shell and other multiphase latex particles—confirming their morphologies and relating those to synthesis variables

Journal of Coatings Technology and Research ◽

10.1007/s11998-007-9060-x ◽

2008 ◽

Vol 5 (2) ◽

pp. 169-180 ◽

Cited By ~ 21

Author(s):

Jeffrey M. Stubbs ◽

Donald C. Sundberg

Keyword(s):

Core Shell ◽

Latex Particles

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Preparation and Property Study of Core-Shell Ambient-Temperature Crosslinkable Polyacrylate Binder

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.469.3 ◽

2013 ◽

Vol 469 ◽

pp. 3-6 ◽

Cited By ~ 9

Author(s):

Mu Li ◽

Xiao Song Lin ◽

Xiao Yu Li ◽

Hai Qiao Wang

Keyword(s):

Ambient Temperature ◽

Butyl Acrylate ◽

Core Shell ◽

Drying Time ◽

Acrylic Polymer ◽

Force Microscopy ◽

Atomic Force ◽

Transmission Electron ◽

Film Forming ◽

Water Based

As the binder of waterborne inks, the capability of acrylic polymer has great influences on the quality of inks. In this contribution, structured latex particles with a poly (stryrene-butyl acrylate-methacrylate) core and a poly (butyl acrylate-methyl methacrylate-methacrylic acid-diacetone acrylamide (DAAM)) shell, which can be used as binders of water-based ink, were prepared by emulsion polymerization. The emulsion can cure in the course of film forming at ambient temperature through the reaction between DAAM and the adipic acid dihydrazide (ADH). Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), transmission electron microscopy (TEM), atomic force microscopy (AFM) were used to characterize the structures and study the properties of the latices. The drying time of the crosslinking latices was investigated. In addition, influences of DAAM monomer dosage and the mole ratio of DAAM to ADH on the mechanical properties of self-crosslinkable core-shell latices were also discussed. It was found that the core-shell crosslinkable particles with a low glass transition temperature (Tg) core and a high Tg shell have better film properties and would be more applicable to binders of water-based ink for plastic film, in comparison with those particles with a high Tg core and a low Tg shell.

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