Core-shell structured latex particles. III. Structure–properties relationship in toughening of polycarbonate with poly(n-butyl acrylate)/poly(benzyl methacrylate–styrene) structured latex particles

1995 ◽  
Vol 58 (2) ◽  
pp. 419-425 ◽  
Author(s):  
I. Segall ◽  
V. L. Dimonie ◽  
M. S. El-Aasser ◽  
P. R. Soskey ◽  
S. G. Mylonakis
Keyword(s):  
Butyl Acrylate ◽  
Core Shell ◽  
Latex Particles ◽  
Structure Properties

Nanosized Polystyrene/Poly(Butyl Acrylate) Core‐Shell Latex Particles Functionalized with Acrylamides

2005 ◽  
Vol 42 (4) ◽  
pp. 427-439 ◽  
Author(s):  
L'udmila Černáková ◽  
Viera Chrástová ◽  
Petra Volfová
Keyword(s):  
Butyl Acrylate ◽  
Core Shell ◽  
Latex Particles

Preparation and Property Study of Core-Shell Ambient-Temperature Crosslinkable Polyacrylate Binder

2013 ◽  
Vol 469 ◽  
pp. 3-6 ◽  
Author(s):  
Mu Li ◽  
Xiao Song Lin ◽  
Xiao Yu Li ◽  
Hai Qiao Wang
Keyword(s):  
Ambient Temperature ◽  
Butyl Acrylate ◽  
Core Shell ◽  
Drying Time ◽  
Acrylic Polymer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Transmission Electron ◽  
Film Forming ◽  
Water Based

As the binder of waterborne inks, the capability of acrylic polymer has great influences on the quality of inks. In this contribution, structured latex particles with a poly (stryrene-butyl acrylate-methacrylate) core and a poly (butyl acrylate-methyl methacrylate-methacrylic acid-diacetone acrylamide (DAAM)) shell, which can be used as binders of water-based ink, were prepared by emulsion polymerization. The emulsion can cure in the course of film forming at ambient temperature through the reaction between DAAM and the adipic acid dihydrazide (ADH). Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), transmission electron microscopy (TEM), atomic force microscopy (AFM) were used to characterize the structures and study the properties of the latices. The drying time of the crosslinking latices was investigated. In addition, influences of DAAM monomer dosage and the mole ratio of DAAM to ADH on the mechanical properties of self-crosslinkable core-shell latices were also discussed. It was found that the core-shell crosslinkable particles with a low glass transition temperature (Tg) core and a high Tg shell have better film properties and would be more applicable to binders of water-based ink for plastic film, in comparison with those particles with a high Tg core and a low Tg shell.

Toughening polycarbonate with core-shell structured latex particles

1996 ◽  
Vol 62 (12) ◽  
pp. 2005-2013 ◽  
Author(s):  
V. Tanrattanakul ◽  
E. Baer ◽  
A. Hiltner ◽  
R. Hu ◽  
V. L. Dimonie ◽  
...  
Keyword(s):  
Core Shell ◽  
Latex Particles
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