Synthesis and Characterization of a New Polyfluorene Derivative with Well-Defined Conjugation Length

2002 ◽  
Vol 377 (1) ◽  
pp. 73-76
Author(s):  
Doo Jin Park ◽  
Yong Young Noh ◽  
Chae Min Chun ◽  
Jangjoo Kim ◽  
Dong-Yu Kim
2017 ◽  
Vol 5 (31) ◽  
pp. 7777-7783 ◽  
Author(s):  
Yunhao Cai ◽  
Xiaolong Zhang ◽  
Xiaonan Xue ◽  
Donghui Wei ◽  
Lijun Huo ◽  
...  

We demonstrated the synthesis and characterization of two polymers, IDT-T1 and IDTT-T1, to investigate the effect of extending the π-conjugation length on the properties of the copolymers.


2000 ◽  
Vol 363 (1-2) ◽  
pp. 110-113 ◽  
Author(s):  
M Cheng ◽  
Y Xiao ◽  
W.-L Yu ◽  
Z.-K Chen ◽  
Y.-H Lai ◽  
...  

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2279 ◽  
Author(s):  
Rylan Wolfe ◽  
Evan Culver ◽  
Seth Rasmussen

The synthesis of four N-functionalized bis[1]benzothieno[3,2-b:2′,3′-d]pyrroles (BBTPs) is reported in order to provide a more detailed characterization of these fused-ring units, as well as increase the scope of known BBTP units available for application to conjugated materials. The optical, electronic, and structural properties of the resulting BBTP units have been compared to the parent N-alkyl- and N-aryl-dithieno[3,2-b:2′,3′-d]pyrroles (DTPs), as well as their corresponding 2,6-diphenyl derivatives, in order to fully quantify the relative electronic effects resulting from benzannulation of the parent DTP building block. Such comparative analysis reveals that benzannulation results in a red-shifted absorbance, but to a lesser extent than simple phenyl-capping of the DTP. More surprising is that benzannulation results in stabilization of the BBTP HOMO, compared to the destabilization normally observed with extending the conjugation length of the backbone.


1996 ◽  
Vol 61 (10) ◽  
pp. 3572-3572
Author(s):  
Lawrence T. Scott ◽  
Atena Necula

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