Magnetic Materials Based on Nitronyl Nitroxide Radicals Complexes: From Mononuclear Building Blocks to One- and Two-Dimensional Compounds

1999 ◽  
Vol 334 (1) ◽  
pp. 521-532 ◽  
Author(s):  
Karine Fegy ◽  
Christophe Lescop ◽  
Dominique Luneau ◽  
Paul Rey
Keyword(s):  
Magnetic Materials ◽  
Building Blocks ◽  
Two Dimensional ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals

Slow magnetic relaxation in two-dimensional 3d–4f complexes based on phenyl pyrimidyl substituted nitronyl nitroxide radicals

2015 ◽  
Vol 44 (21) ◽  
pp. 9815-9822 ◽  
Author(s):  
Mei Zhu ◽  
Juanjuan Wang ◽  
Meng Yang ◽  
Yue Ma ◽  
Licun Li
Keyword(s):  
Magnetic Relaxation ◽  
Relaxation Behavior ◽  
Two Dimensional ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Slow Magnetic Relaxation

Three isostructural two-dimensional nitronyl nitroxide bridged 3d–4f complexes have been achieved. The Tb complex shows field-induced two-step magnetic relaxation behavior.

Cytosine-substituted nitronyl nitroxide radicals as building blocks for generalized ferrimagnetic system

Polyhedron ◽  
2007 ◽  
Vol 26 (9-11) ◽  
pp. 2347-2352 ◽  
Author(s):  
Kensuke Maekawa ◽  
Tomoaki Ise ◽  
Daisuke Shiomi ◽  
Kazunobu Sato ◽  
Takeji Takui
Keyword(s):  
Building Blocks ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

Discovery of intrinsic two-dimensional antiferromagnets from transition-metal borides

Nanoscale ◽  
2021 ◽  
Author(s):  
Shiyao Wang ◽  
Nanxi Miao ◽  
Kehe Su ◽  
Vladislav A. Blatov ◽  
Junjie Wang
Keyword(s):  
Transition Metal ◽  
Magnetic Materials ◽  
Van Der Waals ◽  
Two Dimensional ◽  
Spintronic Devices ◽  
Metal Borides

Intrinsic two-dimensional (2-D) magnets are promising materials for developing advanced spintronic devices. Few have already been synthesized from the exfoliation of the van der Waals magnetic materials. In this work,...

scholarly journals Anisotropic nanocrystal shape and ligand design for co-assembly

2021 ◽  
Vol 7 (23) ◽  
pp. eabf9402
Author(s):  
Katherine C. Elbert ◽  
William Zygmunt ◽  
Thi Vo ◽  
Corbin M. Vara ◽  
Daniel J. Rosen ◽  
...  
Keyword(s):  
Rational Design ◽  
Ligand Design ◽  
Building Blocks ◽  
Two Dimensional ◽  
Secondary System ◽  
Assembly Design ◽  
Ligand Shell ◽  
Powerful Approach ◽  
Anisotropic Systems ◽  
Direct Materials

The use of nanocrystal (NC) building blocks to create metamaterials is a powerful approach to access emergent materials. Given the immense library of materials choices, progress in this area for anisotropic NCs is limited by the lack of co-assembly design principles. Here, we use a rational design approach to guide the co-assembly of two such anisotropic systems. We modulate the removal of geometrical incompatibilities between NCs by tuning the ligand shell, taking advantage of the lock-and-key motifs between emergent shapes of the ligand coating to subvert phase separation. Using a combination of theory, simulation, and experiments, we use our strategy to achieve co-assembly of a binary system of cubes and triangular plates and a secondary system involving two two-dimensional (2D) nanoplates. This theory-guided approach to NC assembly has the potential to direct materials choices for targeted binary co-assembly.

Synthesis, structure, and magnetic properties of two dimer paddle-wheel CuII toluate complexes with nitronyl nitroxide radicals

2013 ◽  
Vol 66 (12) ◽  
pp. 2166-2177 ◽  
Author(s):  
Jie Zhou ◽  
Lin Du ◽  
Zongze Li ◽  
Yongfeng Qiao ◽  
Jing Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Paddle Wheel

scholarly journals Analysis of the Magnetic Exchange Interactions in Yttrium(III) Complexes Containing Nitronyl Nitroxide Radicals

2017 ◽  
Vol 56 (12) ◽  
pp. 6788-6801 ◽  
Author(s):  
Julie Jung ◽  
Marin Puget ◽  
Olivier Cador ◽  
Kevin Bernot ◽  
Carmen J. Calzado ◽  
...  
Keyword(s):  
Exchange Interactions ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Magnetic Exchange

Crystal Structures and Magnetic Properties of Hydrogen-Bonded Nitronyl Nitroxide Radicals and Their Metal Complexes

2002 ◽  
Vol 379 (1) ◽  
pp. 153-158 ◽  
Author(s):  
Mikio Ueda ◽  
Tomoyuki Mochida ◽  
Sachie Furukawa ◽  
Hideaki Suzuki ◽  
Hirosi Moriyama ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Nitronyl Nitroxide ◽  
Nitroxide Radicals ◽  
Hydrogen Bonded
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