scholarly journals Kinetics of [103Ru]phenanthroline and dysprosium particulate markers in the rumen of steers

1983 ◽  
Vol 49 (3) ◽  
pp. 463-473 ◽  
Author(s):  
R. M. Dixon ◽  
J. J. Kennelly ◽  
L. P. Milligan
Keyword(s):  
Medicago Sativa ◽  
Rate Constant ◽  
Large Particle ◽  
Dry Matter ◽  
Turnover Rate ◽  
Small Particles ◽  
Feed Material ◽  
Mesh Screen ◽  
Large Particles ◽  
Kinetics Of

1. Two rumen cannulated steers consuming 5·5 kg air-dry lucerne (Medicago sativa) hay/d given at two-hourly intervals were used to study the kinetics in the rumen of the two particulate markers, 103Ru-labelled Tris-(1,10-phenanthroline) ruthenium II chloride ([103Ru]P) and dysprosium (Dy). Provision of markers was achieved by allowing the steers to eat separatedstems of the hay on to which had been sprayed solutions of the markers.2. The intake of large-particle (retained by a 3·2 mm mesh screen) dry matter (DM) in boluses and the rumen large-particle pool size measured by emptying the rumen wereused to calculate the turnover rate-constant of this pool (1·02 and 1·19/d for steers A and B respectively).3. The decline with time of both [103Ru]P and Dy associated with large-particle DM in raft digesta was best described by two-compartmental kinetics. The first compartment apparently reflected a combination of the processes of mixing of labelled particles throughout the rumen contents, physical migration of marker from the labelled hay, and physical breakdown of large particles to small particles.4. The disappearance with time of [103Ru]P and Dy associated with small particles from the raft, ventral digesta and faeces from 3 to 8 d was well described by a single kinetic compartment with a rate constant similar to that of the second compartment of the large particles from the raft.5. [103Ru]P was rapidly distributed through both the raft and ventral digesta of the rumen. This observation, taken together with measurements of migration of [103Ru]P, suggested that on entering the rumen much of the [103Ru]P did not remain associated with the original feed material.6. The majority (63–64%) of Dy entered the raft digesta and mixed only slowly through the rumen contents. Some Dy (18–27%) apparently migrated rapidly from large particles and to small particles immediately after ingestion and there was also evidence for some slow migration from small to large particles.7. When used under the conditions described for this experiment neither [103Ru]P nor Dy was satisfactory as a marker to trace the passage through the rumen of a particular meal.

Comparison of gut fill in sheep (Ovis aries) measured by intake, digestibility, and digesta retention compared with measurements at harvest

2015 ◽  
Vol 93 (10) ◽  
pp. 747-753 ◽  
Author(s):  
Adam Munn ◽  
Mathew Stewart ◽  
Elizabeth Price ◽  
Alice Peilon ◽  
Tom Savage ◽  
...  
Keyword(s):  
Repeated Measures ◽  
Large Particle ◽  
Dry Matter ◽  
Ovis Aries ◽  
Digestive Physiology ◽  
Small Particles ◽  
Feeding Trial ◽  
Marker Particle ◽  
Empirical Tests ◽  
Gut Fill

Gut capacity is an important factor in digestive physiology and is often measured as dry matter fill (DMF) following dissection, which prevents repeated measures in the same animal. It was proposed to calculate DMF from food intake, digestibility, and gut mean retention time (MRT), but empirical tests of this are few. We calculated DMF from intake, digestibility, and the MRT of small-particle (1 mm) and large-particle (20 mm) markers in 20 sheep (Ovis aries L., 1758) fed at different intake levels and compared results with DMF at dissection at the end of the feeding trial. MRT for smaller particles was significantly shorter than for larger particles (34.4 ± 6.1 vs. 42.5 ± 7.6 h, respectively). Correspondingly, DMF calculated from smaller particles (0.98 ± 0.27 kg) was significantly lower than DMF calculated from larger particles (1.20 ± 0.30 kg). The latter was not significantly different from DMF measured at dissection (1.18 ± 0.34 kg). These results suggest that DMF can be estimated from measures of digestive physiology. The choice of particle marker to determine MRT is crucial for the accuracy of the proxy. In ruminants, where small particles are consistently eliminated faster than larger particles, considerations of marker particle size are particularly important.

scholarly journals A quantitative model of reticulo-rumen particle degradation and passage

1989 ◽  
Vol 62 (2) ◽  
pp. 465-479 ◽  
Author(s):  
A. Lirette ◽  
L. P. Milligan
Keyword(s):  
Small Particle ◽  
Large Particle ◽  
Dry Matter ◽  
Volatile Fatty Acids ◽  
Quantitative Description ◽  
Dry Weight ◽  
Quantitative Model ◽  
Total Flow ◽  
Low Concentrations ◽  
Large Particles

Labelled particles were prepared by mordanting low concentrations (0.1 or 5 g/kg dry matter) of chromium to neutral-detergent-extracted stems (1–2 mm or 10 mm in length) of bromegrass (Bromus inermis). These were used in the study of reticulo-rumen particle kinetics of four steers given bromegrass hay and from the results a quantitative model of particle digestion and passage was developed. At the 0.1 g Cr/kg concentration there was minimal interference with digestibility of the feedstuff. The ratio, dry weight of the reticulo-rumen large-particle pool (> 3.35 mm):small-particle pool (< 3.35 mm) was 2:1. It was derived from the model that volatile fatty acids (VFA) and carbon dioxide in the rumen were produced mainly from large particles, and that between 500 and 700 g/kg hay dry matter was digested in the reticulo-rumen. It was also derived from the model that a major portion, 200 (SE 110) g/kg, of the hay dry matter was rapidly solubilized and that the material leaving the reticulo-rumen was composed of small particles (500–840 g/kg), large particles (100–160 g/kg) and an unknown portion of soluble dry matter of hay (0-400 g/kg). Disappearance from the large-particle pool in the model involving the lowest Cr level was directed to formation of VFA and CO2(0.68 (SE 0.04) of total flow) to the small-particle pool (0.25 (SE 0.06) of total flow) and direct passage from the reticulo-rumen (0.07 (SE 0.002) of total flow). The disappearance from the small-particle pool was to VFA and CO2production and to the omasum accounting for 0.14 (SE 0.18) and 0.86 (SE 0.24) respectively, of the total flow. It was concluded that the low-level-mordanting technique in combination with appropriate sampling yielded a realistic quantitative description of forage breakdown and movement processes in the digestive tract of cattle.

Studies of cattle and sheep eating leaf and stem fractions of grasses. 3. The retention time in the rumen of large feed particles

1981 ◽  
Vol 32 (1) ◽  
pp. 123 ◽  
Author(s):  
DP Poppi ◽  
DJ Minson ◽  
JH Ternouth
Keyword(s):  
Particle Size ◽  
Retention Time ◽  
Dry Matter ◽  
Simulation Studies ◽  
Small Particles ◽  
Dry Matter Distribution ◽  
Rhodes Grass ◽  
Large Particles ◽  
Voluntary Intake ◽  
Cattle And Sheep

Pangola grass (Digitavia decumbens) and Rhodes grass (Chlovis gayana) cut as 6 and 12 week regrowths were separated into leaf and stem fractions and fed ad libitum to four cattle and eight sheep fitted with ruminal fistulae to determine the importance of particle size in controlling the retention time of feed in the rumeno-reticulum (rumen). Particle size was determined by using a wet sieving technique, and based on the cumulative dry matter distribution on the sieves of faeces from cattle and sheep; all particles >1.18 mm were described as large particles. The proportion of large particles was measured in the chopped diet offered, the masticated diet, the ruminal contents and the faeces. Chopped leaf and stem fractions contained 0.85 and 0.86 g/g large particles respectively. Mastication by cattle reduced the proportion of large particles in leaf and stem to 0.58 and 0.76 (P < 0.01), and mastication by sheep to 0.56 and 0.67 (P < 0.01). The proportion of large particles in the rumen of sheep was 0.236 and 0.249 for leaf and stem respectively (P > 0.05) and in cattle 0.272 and 0.345 (P < 0.05). The faeces contained relatively few large feed particles (< 0.045 for cattle and <0.018 for sheep). Cattle eating leaf and stem produced faeces containing 0.027 and 0.040 (g/g) large particles (P <0.05), compared with only 0,008 and 0.013 (P < 0.05) in sheep. Most of the large particles entering the rumen in the masticated feed disappeared in the rumen by breakdown to smaller particles or by digestion. In cattle the proportions that disappeared were 0.978 and 0.976 (P > 0.05) for leaf and stem, and in sheep 0.993 and 0.991 (P > 0.05). Large particles in leaf and stem were retained in the rumen of the sheep for 11.0 and 11.7 h (P > 0.05). Cattle retained large particles in all diets for a longer time (P < 0.01); 16.1 h for leaf and 20,2 h for stem (P > 0.05). Differences in retention time of large particles in the rumen did not appear to be the only factor controlling the retention of dry matter in the rumen and voluntary intake. A model was developed to describe the flow of large and small particles through the rumen. Intake simulation studies indicated that the most important factor influencing dry matter retention time in the rumen was the retention time of small particles (> 1.18 mm). Changes in the rate of breakdown of large particles had a small effect on dry matter retention time.

An experimental study of the motion of concentrated suspensions in two-dimensional channel flow. Part 2. Bidisperse systems

1998 ◽  
Vol 363 ◽  
pp. 57-77 ◽  
Author(s):  
M. K. LYON ◽  
L. G. LEAL
Keyword(s):  
Large Particle ◽  
Particle Concentration ◽  
Volume Fraction ◽  
Balance Model ◽  
Concentration Profiles ◽  
Size Segregation ◽  
Small Particles ◽  
Concentrated Suspensions ◽  
Particle Volume ◽  
Large Particles

In this paper we report experimental velocity and concentration profiles for suspensions possessing a bidisperse distribution of particle size undergoing pressure-driven flow through a parallel-wall channel. In addition to the overall concentration distributions determined by implementing the modified laser Doppler velocimetry method described in Part 1 (Lyon & Leal 1998), concentration profiles for the particles of each size were measured by sampling the position of marked tracer particles across 60% of the channel gap. Non-uniform overall particle concentration distributions and blunted velocity profiles were found at bulk particle volume fractions of 0.30 and 0.40, which were equal to the monodisperse data of Part 1, within experimental uncertainty. The large-particle concentration profiles were non-uniform down to a large-particle bulk volume fraction of 0.075, while non-uniform distributions of the small particles were only found when the volume fraction of small particles in the bulk was greater than or equal to 0.20. Experiments in which at least half the suspended particulate volume was occupied by large particles revealed enrichment of the large particles in the centreline region of the channel. This size segregation was found to increase as the total number of suspended particles decreased. Finally, the data from experiments in which a uniform small-particle concentration profile was measured were compared with suspension balance model (McTigue & Jenkins 1992; Nott & Brady 1994) predictions for parameter values that corresponded only to the large particles. While close agreement with the large-particle concentration profiles was found, this comparison also reflected the fact that the small particles bring the suspension viscosity to a regime that is more sensitive to the particle concentration, rather than simply providing an increment in background viscosity to the suspending liquid.

Large Particle Separation From Non-Newtonian Slurries Using Bump Arrays

2021 ◽  
Author(s):  
Leonard F. Pease ◽  
Judith Ann Bamberger ◽  
Carolyn A. Burns ◽  
Michael J. Minette
Keyword(s):  
Nuclear Waste ◽  
Blood Cells ◽  
Large Particle ◽  
Lateral Displacement ◽  
Particle Separation ◽  
Small Particle Size ◽  
Small Particles ◽  
Deterministic Lateral Displacement ◽  
Significant Difference ◽  
Large Particles

Abstract Here we evaluate the performance of bump arrays to separate large particles from non-Newtonian slurries with Bingham and Cross rheology. Bump arrays in deterministic lateral displacement devices separate large particles from small particles using arrays of staggered posts. Large particles, defined as those with radii larger than the distance between the edge of a post and the stagnation streamline from the next downstream post, must bump toward one side of the device, whereas particles smaller than this distance slalom from entrance to exit without net lateral displacement. Although these devices have been used to separate a wide variety of large particles from blood cells to sand, partition of large particles from non-Newtonian fluids remains unexplored. Yet, an important set of modestly concentrated slurries, including Hanford nuclear waste, displays non-Newtonian rheology. Here we evaluate the influence of non-Newtonian rheology on the large-small particle size cutoff in bump arrays using a model that explores the influence of yield stresses, ratios of zero and infinite shear viscosities, and Cross’s exponent under strictly laminar well-developed conditions. Surprisingly, we find that viscosity ratios and Cross’s exponent make no significant difference on the particle cutoffs between large particles that bump and small particles that slalom around the posts from entrance to exit. In contrast, we find that yield stresses do significantly affect the size cutoff. As the yield stress increases, velocity profiles become more plug like lowering the size cutoff. For nuclear waste separations where removing large particles is a priority, increasing yield stresses is conservative.

ALFALFA VARIETIES ZONED IN THE CENTRAL CHERNOZEM ZONE OF THE RUSSIAN FEDERATION

2020 ◽  
Author(s):  
Galina Stepanova
Keyword(s):  
Medicago Sativa ◽  
Dry Matter ◽  
Maximum Yield ◽  
The State ◽  
Average Yield ◽  
State Register ◽  
Independent Evaluation ◽  
Medicago Sativa L ◽  
Alfalfa Varieties ◽  
Central Chernozem

The article describes the main morphological and biological features of alfalfa varieties included in the State register of breeding achievements approved for use in the Central Chernozem zone of Russia. A total of 32 alfalfa varieties are included in the State register. This is 9 varieties of blue alfalfa (Medicago sativa L. subsp. Sativa) of domestic selection and 8 foreign, 11 varieties of variable alfalfa (Medicago sativa L. nothosubsp. varia (Martyn) Arcang.) domestic selection and 1 variety of foreign and 3 varieties of yellow alfalfa (Medicago sativa L. subsp. falcata (L.) Arcang.). It shows the average and maximum yield of varieties determined in the process of state variety testing, as well as independent evaluation in research institutions in the region. Varieties of blue alfalfa of domestic selection Kevsala, Elena, Satellite, Vavilovskaya Yubileynaya were the most productive. The average yield of dry matter of these varieties reaches 8.4–9.2 t/ha, the maximum — 15.3–17.7 t/ha. Alfalfa varieties Timbale and Galaxy were the most productive among foreign varieties: the average yield of dry matter was 8.1 and 8.3 t/ha, the maximum – 15.5 and 17.2 t/ha. Varieties of alfalfa variable Vitalina and Vela provided an average yield of dry matter of 7.6 and 9.0 t/ha, the maximum yield reached 15.4 and 18.1 t/ha.

Kinetics of Substitution of 4-Methoxyphenylazo Groups of 2,6-Dioxo-5(3)-(4-methoxyphenylazo)-3(5)-(4-methoxyphenylhydrazono)-1,2,3,6-tetrahydropyridine-4-carboxylic Acid by Reaction with 4-Nitrobenzenediazonium Cation

1994 ◽  
Vol 59 (7) ◽  
pp. 1665-1672 ◽  
Author(s):  
Jaroslava Horáčková ◽  
Vojeslav Štěrba
Keyword(s):  
Carboxylic Acid ◽  
Rate Constant ◽  
Kinetics Of

Kinetics have been studied of gradual replacement of 4-methoxyphenylazo groups in 2,6-dioxo-5(3)-(4-methoxyphenylazo)-3(5)-(4-methoxyphenylhydrazono)-1,2,3,6-tetrahydropyridine-4-carboxylic acid (IIIa) by 4-nitrophenylazo groups using the reaction with 4-nitrobenzenediazonium cation (IIc) in acetate and phosphate buffers. The rate constant of replacement of the second methoxyphenylazo group is lower by a factor of ca 60. From the experimentally found pKa values of the corresponding azohydrazone compounds with methoxy, chloro, or nitro substituent at 4-position (IIIa - IIIf) it has been concluded that the 5(3)-(4-methoxyphenylazo)-3(5)-(4-nitrophenylhydrazono) derivative is formed in the first step.

scholarly journals Simultaneous Kinetics of Selenite Oxidation and Sorption on δ-MnO2 in Stirred-Flow Reactors

2021 ◽  
Vol 18 (6) ◽  
pp. 2902
Author(s):  
Zheyong Li ◽  
Yajun Yuan ◽  
Lin Ma ◽  
Yihui Zhang ◽  
Hongwei Jiang ◽  
...  
Keyword(s):  
Rate Constant ◽  
Photoelectron Spectroscopy ◽  
Oxide Surfaces ◽  
Kinetic Rate Constant ◽  
Flow Reactors ◽  
Mn Oxide ◽  
Remediation Strategies ◽  
Process Of Se ◽  
Kinetics Of

Selenium (Se) is an essential and crucial micronutrient for humans and animals, but excessive Se brings negativity and toxicity. The adsorption and oxidation of Se(IV) on Mn-oxide surfaces are important processes for understanding the geochemical fate of Se and developing engineered remediation strategies. In this study, the characterization of simultaneous adsorption, oxidation, and desorption of Se(IV) on δ-MnO2 mineral was carried out using stirred-flow reactors. About 9.5% to 25.3% of Se(IV) was oxidized to Se(VI) in the stirred-flow system in a continuous and slow process, with the kinetic rate constant k of 0.032 h−1, which was significantly higher than the apparent rate constant of 0.0014 h−1 obtained by the quasi-level kinetic fit of the batch method. The oxidation reaction was driven by proton concentration, and its rate also depended on the Se(IV) influent concentration, flow rate, and δ-MnO2 dosage. During the reaction of Se(IV) and δ-MnO2, Mn(II) was produced and adsorbed strongly on Mn oxide surfaces, which was evidenced by the total reflectance Fourier transform infrared (ATR-FTIR) results. The X-ray photoelectron spectroscopy (XPS) data indicated that the reaction of Se(VI) on δ-MnO2 produced Mn(III) as the main product. These results contribute to a deeper understanding of the interface chemical process of Se(IV) with δ-MnO2 in the environment.

scholarly journals Physical properties and water absorption kinetics of three varieties of Mucuna beans

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ajibola B. Oyedeji ◽  
Olajide P. Sobukola ◽  
Ezekiel Green ◽  
Oluwafemi A. Adebo
Keyword(s):  
Physical Properties ◽  
Water Absorption ◽  
Rate Constant ◽  
Geometric Mean ◽  
Seed Mass ◽  
Activation Energies ◽  
Mucuna Pruriens ◽  
Absorption Kinetics ◽  
Kinetics Of ◽  
Soaking Temperature

AbstractThe physical properties and water absorption kinetics of three varieties of Mucuna beans (Mucuna pruriens, Mucuna rajada and Mucuna veracruz) were determined in this study. Physical properties including length, width, thickness, geometric mean diameter, sphericity, porosity, bulk density, area, volume and one thousand seed mass were calculated while hydration kinetics was studied by soaking Mucuna beans in water at 30 °C, 40 °C and 50 °C and measuring water uptake at 9 h interval. Peleg’s equation was used to model the hydration characteristics and Arrhenius equation was used to describe the effect of temperature on Peleg’s rate constant k1 and to obtain the activation energies for soaking. Significant variations were observed in almost all the physical properties of the different varieties, however, there were no significant differences (p < 0.05) in their thicknesses and bulk densities. The effectiveness of fit of Peleg’s model (R2) increased with increase in soaking temperature. Peleg’s rate constant k1 decreased with increase in soaking temperature while k2 increased with temperature increase. Activation energies of Mucuna pruriens, Mucuna rajada and Mucuna veracruz were 1613.24 kJ/mol, 747.95 kJ/mol and 2743.64 kJ/mol, respectively. This study provides useful information about the properties of three varieties of Mucuna beans that could be of importance to processors and engineers for process design and optimization.

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