Polymer molecular-weight and degree of drying effects on infiltration and erosion of three different soils

Soil Research ◽  
1995 ◽  
Vol 33 (6) ◽  
pp. 1007 ◽  
Author(s):  
GJ Levy ◽  
M Agassi

Low infiltration rate and high levels of soil erosion are critical problems in many soils worldwide. Amendment of soils with organic polymers could alleviate these problems. The objective of the present study is to investigate the effects of polymer molecular weight and the degree of drying on the infiltration rate of, and erosion from, three different soil types from Israel. A solution of high-molecular-weight (2x107 Da) or low-molecular-weight (2x105 Da) negatively charged polyacrylamide (PAMH and PAML, respectively) was added to the surface of soil samples packed in trays, at a rate of 20 kg ha-1. The soil samples were allowed to dry to varying degrees and were then exposed to 60 mm of simulated rain during which infiltration rate and soil loss were determined. The ability of the polymer to maintain high final infiltration rates (FIR) depended on its molecular weight and the clay content of the soils. In the coarse- and medium-textured soils, the PAMH was more effective than the PAML in maintaining high FIR. In the fine-textured soil, the effects of both polymers on Fm. were comparable; the use of the PAML is therefore preferable since it is easier to handle. Both polymers had reduced soil loss comparably. The effects of drying were similar for both polymers: the FIR and soil loss values with the intermediate degrees of drying were higher and lower, respectively, than they were with the no-drying or complete-drying treatments.

Soil Research ◽  
2001 ◽  
Vol 39 (6) ◽  
pp. 1293 ◽  
Author(s):  
A. I. Mamedov ◽  
G. J. Levy ◽  
I. Shainberg ◽  
J. Letey

Surface sealing is determined by aggregate disintegration and clay dispersion, which in turn depend on aggregate wetting rate, and soil sodicity and texture. We hypothesised that soil susceptibility to seal formation increases when the aggregate wetting rate (WR) is increased, and that the effect of WR depends on soil texture and soil sodicity. The objective of this study was to investigate the effects of WR on seal formation, by observing infiltration rate (IR) and runoff, in cultivated soils varying in clay content and exchangeable sodium percent (ESP). Effects of 3 wetting rates (2, 8, and 64 mm/h) on IR and runoff from 6 Israeli soils exposed to 60 mm of simulated rain of deionised water were studied in the laboratory. The soils ranged in clay from 8.8 to 68.3% and ESP levels from 0.9 to 20.4. Effects of WR on soil infiltration rate and runoff depended on soil texture and soil ESP. In soils with low clay content (8.8%), the effect of WR on seal formation was negligible, whereas effect of ESP was significant. Conversely, in clay soils (>52.1%), WR had a predominant effect on IR and runoff, while the effect of ESP was notable yet secondary to that of WR. The soils with intermediate clay content (22.5–40.2% clay) were the soils most susceptible to seal formation, with WR and ESP having moderate effects on seal formation. Effects of WR on aggregate disintegration and seal formation increased with increasing clay content and aggregate stability. Conversely, the role of ESP in determining sealing decreased with an increase in clay content and in WR.


Soil Research ◽  
2008 ◽  
Vol 46 (3) ◽  
pp. 191 ◽  
Author(s):  
Meni Ben-Hur ◽  
Marcos Lado

Soil surface sealing is one of the main causes for low infiltration rate (IR) and high runoff and soil loss under raindrop impact conditions in arid and semiarid regions. Many studies have focused on the effects of soil properties on seal formation under fast wetting conditions. However, in the field, soils can be exposed to different wetting conditions, before an intense rainfall event, which can affect the role of the soil properties on seal formation. The present paper reviews the effects of different initial wetting conditions and their interactions with soil properties on seal formation, IR, runoff, and soil loss in smectitic soils. Fast wetting of soil causes aggregate slaking, which enhances seal formation, runoff, and soil loss under rainfall, mainly in soils with > 40% clay content. An increase in clay content of the soil increases aggregate strength, but at the same time increases the slaking forces. Hence, in soils with low clay content (<40%) and low aggregate stability, raindrop impact alone was sufficient to break down the aggregates and to develop a seal. In contrast, in soils with > 40% clay content and high aggregate stability, slaking plays an important role in aggregate breakdown and seal formation. An increase of raindrop kinetic energy, from 8 to 15.9 kJ/m3, decreased the effect of the slaking forces on seal formation and runoff. It was suggested that the effects of raindrop kinetic energy and of the slaking forces on aggregate disintegration and seal formation are complementary. An increase in soil exchangeable sodium percentage (ESP), from 0.9 to 20.4%, decreased the effect of slaking forces on seal formation and runoff production under rainfall with 15.9 kJ/m3 kinetic energy. Probably, increasing the ESP increased the soil dispersivity, and therefore diminished the effect of the slaking forces on aggregate disintegration and seal formation. Aging (the time since wetting) of soil increased the stability of soil structure, decreased the seal formation, maintained high IR, and diminished soil loss amounts. These effects of soil aging depend on both the prewetting rate of the soil and soil texture.


1995 ◽  
Vol 60 (11) ◽  
pp. 1905-1924 ◽  
Author(s):  
Hong Phuong-Nguyen ◽  
Geneviève Delmas

Dissolution, crystallization and second dissolution traces of isotactic poly(propylene) have been obtained in a slow temperature ramp (3 K h-1) with the C80 Setaram calorimeter. Traces of phase-change, in presence of solvent, are comparable to traces without solvent. The change of enthalpy on heating or cooling, ∆Htotal, over the 40-170 °C temperature range, is the sum of two contributions, ∆HDSC and ∆Hnetwork. The change ∆HDSC is the usual heat obtained in a fast temperature ramp and ∆Hnetwork is associated with a physical network whose disordering is slow and subject to superheating due to strain. When dissolution is complete, ∆Htotal is equal to ∆H0, the heat of fusion of perfect crystals. The values of ∆Htota for nascent and recrystallized samples are compared. Dissolution is the tool to evaluate the quality of the crystals. The repartition of ∆Htotal, into the two endotherms, reflects the quality of crystals. The crystals grown more rapidly have a higher fraction of network crystals which are stable at high T in the solvents. A complete dissolution, i.e. a high temperature (170 °C or more) is necessary to obtain good crystals. The effect of concentration, polymer molecular weight and solvent quality on crystal growth is analyzed.


1998 ◽  
Vol 75 (1) ◽  
pp. 272-293 ◽  
Author(s):  
Heidi E. Warriner ◽  
S.L. Keller ◽  
Stefan H.J. Idziak ◽  
Nelle L. Slack ◽  
Patrick Davidson ◽  
...  

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