Sorption-desorption behaviour of caesium in some Western Australian soils

Soil Research ◽  
1990 ◽  
Vol 28 (6) ◽  
pp. 929 ◽  
Author(s):  
B Singh ◽  
RJ Gilkes

Soil caesium-137 derived from past atmospheric nuclear tests is increasingly being used as an indicator of soil erosion and deposition on the basis that fallout 137Cs has been retained by soils, although this assumption has not been thoroughly tested for different soils. The sorption behaviour of some Western Australian soils indicates that Cs is differentially sorbed as a consequence of differences in clay mineralogy. Kaolinitic sandy soils of low exchange capacity sorb Cs in preference to Ca and Na, with the specificity for Cs being higher at lower concentrations of Cs in solution. lllitic and smectitic soils sorbed more Cs than kaolinitic soils and retained more than 50% of sorbed Cs after a series of extractions with salt solutions. Retention by kaolinitic soils was less but, for the concentrations of Cs likely to occur in soils, it seems that most Cs is retained so that it is probable that the 137Cs technique can be used with confidence for the measurement of soil erosion and deposition for many Western Australian soils.

2003 ◽  
Vol 69 (1-2) ◽  
pp. 153-162 ◽  
Author(s):  
S.P. Theocharopoulos ◽  
H. Florou ◽  
D.E. Walling ◽  
H. Kalantzakos ◽  
M. Christou ◽  
...  

1982 ◽  
Vol 33 (2) ◽  
pp. 275 ◽  
Author(s):  
NJ Barrow

Large quantities of alkaline red mud are produced as a waste product from the extraction of alumina from bauxite. Its chemical and physical properties and the way that it could be modified to produce good growth of plants were investigated. The cation exchange capacity of the red mud increased with pH, the adsorption of phosphate decreased, and the adsorption of cadmium increased. A pH of just above eight seemed to provide a good combination of desirable properties. This could be achieved by exposing the red mud to air and mixing it with gypsum - also available as a waste product. Carbon dioxide was absorbed by alkaIi in the red mud, and then precipitated by the gypsum as calcium carbonate. This released sodium sulfate which could be leached from the mud. Medic species could then be grown, provided that phosphate, potassium and manganese were supplied. Residual sodium sulfate from incomplete leaching seemed to limit the growth of other species. There seemed to be a potential to use the amended red mud to improve the waterholding properties and the chemical properties of sandy soils of the Western Australian coastal plain.


1983 ◽  
Vol 34 (4) ◽  
pp. 341 ◽  
Author(s):  
SC Jarvis ◽  
AD Robson

Subterranean clover was grown, under leaching conditions, in pots on cultivated and virgin acidic sandy soils from two sites in Western Australia. Nitrogen (N) was supplied to the plants either as NH+4, NO-3 or through symbiotic fixation. There were marked changes in the acidity of the soil as the result of the differences in catiot/anion balance induced by the different forms of N supplied. Thus plants supplied with NH+4 depressed the pH by 0.9 pH units, and those dependent upon fixation by 0.5 pH units. There was little change in pH when NO-3 was supplied. Changes in soil pH were strongly related to cation/ anion balance, with increasing acidity resulting from the decreasing ash alkalinity of shoots of plants supplied with NH+4. There were marked differences both between the two soils from the same site, as well as between soils from the two different sites, in the relationships between pH and soluble aluminium and pH and exchange acidity. It is suggested that differences in the form, as well as differences in the total amount, of organic matter could play a major role in controlling the development of acidity in such soils of low, permanent cation exchange capacity.


2021 ◽  
Vol 14 (2) ◽  
Author(s):  
Shamsollah Ayoubi ◽  
Shirin Rabiee ◽  
Mohammad Reza Mosaddeghi ◽  
Mohammad Reza Abdi ◽  
Farideh Abbaszadeh Afshar
Keyword(s):  

Soil Research ◽  
2012 ◽  
Vol 50 (1) ◽  
pp. 1 ◽  
Author(s):  
Philip M. Bloesch

The ratio of cation exchange capacity to clay (CCR) has been used as an index of clay mineralogy in subsoils low in organic matter in place of the standard X-ray diffraction measurement. Laboratory determination of this ratio is time-consuming and expensive and involves two analyses. In this paper, the CCR has been successfully predicted from mid-infrared diffuse reflectance spectra using partial least-squares regression (PLSR) with a square-root transformation of the CCR values (R2 = 0.860; root mean squared error of prediction = 0.089; relative per cent deviation = 2.660 for an independent validation set). The most important wavelengths used in the PLSR calibration were identified. The prediction of CCR using mid-infrared spectroscopy provides a cheaper and faster alternative to laboratory determination.


RSC Advances ◽  
2017 ◽  
Vol 7 (4) ◽  
pp. 1989-2001 ◽  
Author(s):  
Mylène Trublet ◽  
Marina V. Maslova ◽  
Daniela Rusanova ◽  
Oleg N. Antzutkin

The first report on sorption behaviour of a titanium phosphate sorbent containing entirely –H2PO4 groups reveals a high exchange capacity and fast kinetics.


2007 ◽  
Vol 50 (6) ◽  
pp. 1051-1060 ◽  
Author(s):  
Avacir Casanova Andrello ◽  
Carlos Roberto Appoloni ◽  
Virgílio Franco do Nascimento Filho

The aim of this work was to assess the soil erosion process in native forest by the 137Cs methodology. The mass balance model was applied to assess the rates of soil loss in three native forests around of Londrina city, Paraná, Brazil. 137Cs distribution depth was of exponential type for the three forests and 137Cs inventory was 241 Bq m-2 for Mata 1, 338 Bq m-2 for Mata 2 and 325 Bq m-2 for Mata UEL. The soil loss value calculated for three native forests was: 6,684 kg ha-1 yr-1 for Mata 1, 1,788 kg ha-1 yr-1 for Mata 2 and 4,524 kg ha-1 yr-1 for Mata UEL.


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