Influence of organic matter and phosphate content on the point of zero charge of variable charge components in oxidic soils

Soil Research ◽  
1985 ◽  
Vol 23 (4) ◽  
pp. 643 ◽  
Author(s):  
GP Gillman
Keyword(s):  
Organic Matter ◽  
Organic Matter Content ◽  
Matter Content ◽  
Parent Material ◽  
Point Of Zero Charge ◽  
Average Amount ◽  
Ph Values ◽  
Variable Charge ◽  
Zero Charge ◽  
Extractable Phosphorus

The point of zero charge of the variable charge components (pH,) of oxidic soils formed on basaltic parent material in humid tropical Queensland has been measured on samples from virgin rainforest and cultivated fertilized fields. The average amount of free iron in these soils is about 10%. Soils with low organic matter content and low extractable phosphorus have high pH, values. Regression analysis showed pH, to be reduced by about one pH unit for each 1% increase in organic carbon or for each 100 �g/g increase in extractable phosphorus. Implications with respect to cation and anion exchange capacities are briefly discussed.

scholarly journals CHEMICAL AND MINERALOGICAL PROPERTIES OF ULTISOLS OF SASAMBA AREA, EAST KALIMANTAN

2016 ◽  
Vol 2 (2) ◽  
pp. 37
Author(s):  
B.H. Prasetyo ◽  
N. Suharta ◽  
Subagyo H. ◽  
Hikmatullah Hikmatullah
Keyword(s):  
Organic Matter ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Matter Content ◽  
Point Of Zero Charge ◽  
East Kalimantan ◽  
Mineralogical Characteristics ◽  
Marginal Soils ◽  
Acid Reaction ◽  
Phosphate Fixation

Ultisols are a major group of marginal soils extensively found in the upland area of Indonesia. To better understand the potential of the Ultisols developed from claystone and sandstone in the Sasamba Integrated Economical Development Area in East Kalimantan, chemical and mineralogical characteristics of 27 Ultisols pedons consisting of 76 topsoil and 118 subsoil samples were investigated. Besides analysis and interpretation of data, relationships of several soil characteristics were constructed using simple regression. The results indicated that Ultisols showed acid to very acid reaction, had low content of organic matter and low base saturation. Soils generally exhibited net negative charge, and the point of zero charge was reached at pH 3.6. Both potential and available phosphates were low, and there was a trend that amorphous aluminum was responsible for phosphate fixation. The low content of exchangeable potassium in topsoil and subsoil indicated a positive correlation with potential potassium. Clay mineral was composed chiefly of kaolinite, with small amounts of illite, vermiculite, and quartz. The domination of kaolinite and low organic matter content causes the soils to have low cation exchange capacity. Soil management in this area should be focused on building up and maintaining soil fertility, and applying appropriate soil conservation techniques to minimize erosion. To obtain sustained productivity, various soil amendments including the use of farm and/or green manure, liming with agricultural lime, and application of rock phosphate and K fertilizers were highly recommended.

scholarly journals Changes in the forms of cadmium with time in some Western Australian soils

Soil Research ◽  
1994 ◽  
Vol 32 (2) ◽  
pp. 241 ◽  
Author(s):  
SS Mann ◽  
GSP Ritchie
Keyword(s):  
Organic Matter ◽  
Podzolic Soil ◽  
Ammonium Oxalate ◽  
Organic Matter Content ◽  
Matter Content ◽  
Potential Toxicity ◽  
Time Intervals ◽  
Ph Values ◽  
Western Australian ◽  
Exchangeable Form

Changes in the forms of Cd with time could affect its uptake by plants and hence potential toxicity to animals and humans. The effect of time on the forms of native and added Cd was studied in four West Australian soils which differed in their clay, hydrous oxide and organic matter content. Sequential extraction of soluble (KCl), exchangeable (BaCl2), bound to organic matter (NaOCl), bound to oxides/clays (ammonium oxalate) and residual (concentrated acids) forms of Cd was carried out at different time intervals after the addition of Cd. The Cd that was added to the soils transformed with time to less soluble forms; the extent depending upon the type of soil. In addition, the rate of transformation in a particular type of soil was affected by both pH and rate of Cd addition. Soluble cadmium in the sandy soil decreased with time whereas the exchangeable form increased. The extent of the changes increased with increase in pH. In the peaty sand at pH < 5, exchangeable Cd increased apparently at the expense of soluble Cd. At higher pH values, however, Cd bound to organic matter increased with time as exchangeable Cd decreased. In the lateritic podzolic soil (dominated by kaolinite), there was no effect of time on the forms of Cd at pH values <. At pH > 6, the exchangeable form of Cd decreased whereas Cd bound to organic matter and residual Cd increased with time. In the yellow earth (dominated mainly by goethite), soluble Cd decreased with time at pH values < 5 and became a negligible fraction at pH 6. Exchangeable Cd decreased with time at pH values > 5 whereas Cd bound to oxides and residual Cd increased with time at all the pH values.

THE AVAILABLE BORON CONTENT OF THE GENETIC HORIZONS OF SOME ONTARIO SOILS: I. THE RELATIONSHIP BETWEEN WATER-SOLUBLE BORON AND OTHER SOIL PROPERTIES

1966 ◽  
Vol 46 (2) ◽  
pp. 133-138 ◽  
Author(s):  
N. S. Miljkovic ◽  
B. C. Matthews ◽  
M. H. Miller
Keyword(s):  
Organic Matter ◽  
Boron Content ◽  
Organic Matter Content ◽  
Clay Content ◽  
Important Variable ◽  
Matter Content ◽  
Parent Material ◽  
Water Soluble ◽  
Hot Water ◽  
The Relationship

The available boron content of the genetic horizons of eight Ontario soils was determined using a hot-water extraction and a sunflower test. The available boron was highest in the surface horizons and decreased in the zones of eluviation to a level equal to or lower than that in the parent material. The content in the horizons was generally higher than that in the C horizons.The water-soluble boron was closely related to the organic matter content in a quadratic regression (R2 = 0.691). When pH and clay content were included in regressions, a positive organic matter × pH component was the single most important variable, explaining 64.4% of the variability. Additional terms involving clay content and pH did not greatly increase the R2 value.

Organic matter and mineral distribution in an old-growth Acersaccharum forest near the northern limit of its range

1990 ◽  
Vol 20 (9) ◽  
pp. 1332-1342 ◽  
Author(s):  
I. K. Morrison
Keyword(s):  
Organic Matter ◽  
Forest Floor ◽  
Mineral Soil ◽  
Organic Matter Content ◽  
Matter Content ◽  
Parent Material ◽  
Old Growth ◽  
Northern Ontario ◽  
Cu Content ◽  
Base Soil

Two sites, both supporting old-growth Acersaccharum Marsh, dominated forest on rugged topography in central northern Ontario, were compared in terms of organic matter and N, P, K, Ca, Mg, S, Fe, Mn, Zn, and Cu content in the tree- and field-layer phytomass, the forest floor, and the mineral soil. One site was on a shallow, low-base, Precambrian-derived till, and the other was on a till of somewhat higher base status. Gross and net growth of the overstory tree layer were also determined. Total phytomass values for the two stands at the beginning of the study period were 245 000 and 210 000 kg•ha−1, respectively. Gross growth was largely offset by mortality in both stands, producing a rough equilibrium with regard to net increment. Growth before mortality was on the order of 2.4–2.5 m3•ha−1•year−1 in terms of gross total wood volume or 3700–3900 kg•ha−1•year−1 in terms of phytomass, and it was slightly greater in percent terms on the higher base site. In addition to that in the phytomass, organic matter in the forest floor and mineral soil to a depth of 1 m also contributed to the total organic matter content of 638 000–642 000 kg•ha−1 (equivalent to 34 8000–353 000 kg•ha−1 of C) on both sites and was distributed as follows: 29–34% in phytomass, 5% in the forest floor, and 61–66% in mineral soil. The order of abundance of elements in the phytomass was similar on both sites: Ca > N > K > Mg > S > Mn > P > Fe > Zn > Cu, with accumulation in the phytomass in rough proportion to occurrence in the soil. A more base-rich parent material would appear to be the origin of 1452 kg•ha−1 of Ca estimated to be in the phytomass and forest floor on the higher base soil, compared with 1250 kg•ha−1 in the phytomass and forest floor on the lower base soil.

scholarly journals CHEMICAL AND MINERALOGICAL PROPERTIES OF ULTISOLS OF SASAMBA AREA, EAST KALIMANTAN

2016 ◽  
Vol 2 (2) ◽  
pp. 37 ◽  
Author(s):  
B.H. Prasetyo ◽  
N. Suharta ◽  
Subagyo H. ◽  
Hikmatullah Hikmatullah
Keyword(s):  
Organic Matter ◽  
Organic Matter Content ◽  
Exchange Capacity ◽  
Matter Content ◽  
Point Of Zero Charge ◽  
East Kalimantan ◽  
Mineralogical Characteristics ◽  
Marginal Soils ◽  
Acid Reaction ◽  
Phosphate Fixation

Ultisols are a major group of marginal soils extensively found in the upland area of Indonesia. To better understand the potential of the Ultisols developed from claystone and sandstone in the Sasamba Integrated Economical Development Area in East Kalimantan, chemical and mineralogical characteristics of 27 Ultisols pedons consisting of 76 topsoil and 118 subsoil samples were investigated. Besides analysis and interpretation of data, relationships of several soil characteristics were constructed using simple regression. The results indicated that Ultisols showed acid to very acid reaction, had low content of organic matter and low base saturation. Soils generally exhibited net negative charge, and the point of zero charge was reached at pH 3.6. Both potential and available phosphates were low, and there was a trend that amorphous aluminum was responsible for phosphate fixation. The low content of exchangeable potassium in topsoil and subsoil indicated a positive correlation with potential potassium. Clay mineral was composed chiefly of kaolinite, with small amounts of illite, vermiculite, and quartz. The domination of kaolinite and low organic matter content causes the soils to have low cation exchange capacity. Soil management in this area should be focused on building up and maintaining soil fertility, and applying appropriate soil conservation techniques to minimize erosion. To obtain sustained productivity, various soil amendments including the use of farm and/or green manure, liming with agricultural lime, and application of rock phosphate and K fertilizers were highly recommended.

scholarly journals Yeşilırmak Nehir Teraslarında Toprakların Oluşumu ve Sınıflandırılması

2014 ◽  
Vol 2 (2) ◽  
pp. 98 ◽  
Author(s):  
Alper Durak ◽  
Mehmet Erdem Aydın
Keyword(s):  
Organic Matter ◽  
Research Result ◽  
Organic Matter Content ◽  
Matter Content ◽  
Parent Material ◽  
Carbonate Content ◽  
Soil Taxonomy ◽  
Material Particle ◽  
Wide Range ◽  
Research Profile

In this study, the soils of which parent material is alluvial and formed Yeşilırmak river terraces were investigated. For this purposes four different profiles were excavated in the study area. Then twenty-seven soil samples were taken from horizons of four profiles and their physical and chemical analyses were done for soil taxonomy research. Profile of Kumocagi and Cakil were classified in subgroup as Typic Ustipsamments, Havaalanı and Mera profiles were classified Typic Haplustolls and Typic Argiustolls subgroups respectively. The pH values of soils varied between 7.38-8.41. These soils can be classified as low and highly basic. Most of the soil series had an irregular pH distribution in the profile. The range of carbonate content of the soils was 0.8-25.4%. Although carbonate content of soils showed a very wide range, majority of them can be classified as highly calcareous. In most of soils carbonate content was distributed irregulary in the profile. Organic matter content were between 0.14-6.11% in the soils. Although organic matter contents of the soils changed in a wide range most of them had low organic matter content. Organic matter content was over 4% in the surface horizon of only two profiles. Research result showed that, alluvial parent material, particle size, topograpy and time have different effect on investigation soils.

scholarly journals Potential impacts of climate change on soil properties

2018 ◽  
Vol 67 (1) ◽  
pp. 121-141 ◽  
Author(s):  
G. Gelybó ◽  
E. Tóth ◽  
C. Farkas ◽  
Á. Horel ◽  
I. Kása ◽  
...  
Keyword(s):  
Climate Change ◽  
Organic Matter ◽  
Soil Properties ◽  
Precipitation Amount ◽  
Organic Matter Content ◽  
Matter Content ◽  
Parent Material ◽  
Transport Processes ◽  
Anthropogenic Activity

Climate change is expected to have a vigorous impact on soils and ecosystems due to elevated temperature and changes in precipitation (amount and frequency), thereby altering biogeochemical and hydrological cycles. Several phenomena associated with climate change and anthropogenic activity affect soils indirectly via ecosystem functioning (such as higher atmospheric CO2 concentration and N deposition). Continuous interactions between climate and soils determine the transformation and transport processes. Long-term gradual changes in abiotic environmental factors alter naturally occurring soil forming processes by modifying the soil water regime, mineral composition evolution, and the rate of organic matter formation and degradation. The resulting physical and chemical soil properties play a fundamental role in the productivity and environmental quality of cultivated land, so it is crucial to evaluate the potential outcomes of climate change and soil interactions. This paper attempts to review the underlying long-term processes influenced by different aspects of climate change. When considering major soil forming factors (climate, parent material, living organisms, topography), especially climate, we put special attention to soil physical properties (soil structure and texture, and consequential changes in soil hydrothermal regime), soil chemical properties (e.g. cation exchange capacity, soil organic matter content as influenced by changes in environmental conditions) and soil degradation as a result of longterm soil physicochemical transformations. The temperate region, specifically the Carpathian Basin as a heterogeneous territory consisting of different climatic and soil zones from continental to mountainous, is used as an example to present potential changes and to assess the effect of climate change on soils. The altered physicochemical and biological properties of soils require accentuated scientific attention, particularly with respect to significant feedback processes to climate and soil services such as food security.

Structural stability, pore size distribution and surface charge properties of clay soils with varying mineralogy and organic matter content.

1969 ◽  
Vol 77 (1-2) ◽  
pp. 11-31
Author(s):  
Víctor A. Snyder ◽  
Rafael Pietri Oms ◽  
Milagros Miró ◽  
Héctor M. Lugo
Keyword(s):  
Organic Matter ◽  
Pore Size ◽  
Organic Matter Content ◽  
Clay Mineralogy ◽  
Matter Content ◽  
Clay Soils ◽  
Size Distributions ◽  
Moisture Retention ◽  
Variable Charge ◽  
Pore Size Distributions

This study evaluated interactive effects of mineralogy and organic matter content on chemical and physical properties of clay soils. Measurements were taken at different depths in four soil profiles characterized by oxidic, kaolinitic, mixed and montmorillonitic clay mineralogies, respectively. Within a given profile, organic carbon content varied more or less continuously with depth, whereas texture and mineralogy remained relatively constant. Thus in this study the combined effects of organic matter content and clay mineralogy could be evaluated in various combinations while texture remained constant. Resistance of soil aggregates to slaking by water was related primarily to soil organic matter content, with relatively minor differences attributable to mineralogy except in the oxidic soil where oxides seemed to exert an important stabilizing effect. Organic matter was associated with an increase in water-holding capacity both in the interaggregate pore space (0 to -0.33 bar moisture retention range) and intraaggregate porosity (-0.33 to -0.8 bar retention range). The enhancing effect of organic matter on intra-aggregate porosity seemed most prominent in the soils with oxidic and kaolinitic mineralogies, suggesting the importance of organic matter for maximizing plant-available water retention in these soils. For all soils and depths, pore-size distributions within the 0 to -0.33 bar moisture retention range were log-normally distributed, with the geometric mean pore diameter and log standard deviation practically constant. These results implied that although the total 0 to -0.33 bar porosity varied strongly (primarily with organic matter content), the relative pore size distributions were all similar. In agreement with other studies in the literature, effective cation exchange capacity (ECEC) increased and the zero point of charge (ZPC) of the variable charge complex decreased as organic matter increased, and as clay mineralogy varied in the order oxidic -> kaofinitic -> mixed -> montmorillonitic. Results of this study highlight the importance of managing organic matter for optimizing physical and chemical properties in soils, particularly those dominated by variable charge minerals.

scholarly journals The influence of pH on the forms of cadmium in four West Australian soils

Soil Research ◽  
1993 ◽  
Vol 31 (3) ◽  
pp. 255 ◽  
Author(s):  
SS Mann ◽  
GSP Ritchie
Keyword(s):  
Organic Matter ◽  
Ammonium Oxalate ◽  
Organic Matter Content ◽  
Matter Content ◽  
Residual Fraction ◽  
Soluble Form ◽  
Solution Ph ◽  
Ph Values ◽  
Adsorption Surface ◽  
Exchangeable Form

The forms of cadmium in soils affect its uptake by plants and hence its potential toxicity to animals and humans. We studied the effect of pH on the forms of native and added Cd in four West Australian soils which differed in their clay, hydrous oxide and organic matter content. The forms of Cd were extracted sequentially by KCl, BaCl2, NaOCl, ammonium oxalate and concentrated acids. The majority of Cd applied to a sandy soil was found in the soluble (KCl) and the exchangeable (BaCl2) forms at all pH values. In the siliceous sand, the proportion of the Cd present in the exchangeable form increased as the soil solution pH increased. However, in the peaty sand, the opposite trend was observed; at pH 5, approximately 50% of the Cd was found in the exchangeable form, while at higher pH values, < 60% was bound to organic matter and 20% was in the soluble form. In soils in which the main adsorption surface was dominated by hydrous oxides (mainly goethite), 50-70% of the Cd was extracted as bound to oxides and as the residual fraction at pH < 5. At pH values > 5, the majority (90%) of it was extracted in these forms. Soils, containing clay (mainly kaolinite) as the major adsorbent, retained Cd mainly in exchangeable form at all pH values and at all the rates of Cd application. At pH > 5, however, some of the Cd was also found in the residual form and bound to organic matter. This work has shown that the form of added Cd in a soil cannot be elucidated by considering the major adsorbing component alone. It is also necessary to know the pH, the presence of other adsorbing surfaces and the rates of applied Cd.

HEAVY METAL SPECIATION IN BOTTOM SEDIMENTS OF THE VYSHNEVOLOTSKY RESERVOIR

2018 ◽  
pp. 46-54
Author(s):  
O. A. Lipatnikova
Keyword(s):  
Heavy Metal ◽  
Organic Matter ◽  
Bottom Sediments ◽  
Metal Speciation ◽  
Organic Matter Content ◽  
Water Reservoir ◽  
Matter Content ◽  
Heavy Metal Speciation ◽  
Mobile Forms ◽  
Manganese Hydroxides

The study of heavy metal speciation in bottom sediments of the Vyshnevolotsky water reservoir is presented in this paper. Sequential selective procedure was used to determine the heavy metal speciation in bottom sediments and thermodynamic calculation — to determine ones in interstitial water. It has been shown that Mn are mainly presented in exchangeable and carbonate forms; for Fe, Zn, Pb и Co the forms are related to iron and manganese hydroxides is played an important role; and Cu and Ni are mainly associated with organic matter. In interstitial waters the main forms of heavy metal speciation are free ions for Zn, Ni, Co and Cd, carbonate complexes for Pb, fulvate complexes for Cu. Effects of particle size and organic matter content in sediments on distribution of mobile and potentially mobile forms of toxic elements have been revealed.

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