Iron oxides in fractured quartz – development and evolution of iron sandstone layers in the Kinshasa area, DR Congo

Soil Research ◽  
2018 ◽  
Vol 56 (5) ◽  
pp. 518
Author(s):  
F. Mees ◽  
G. Phemba ◽  
P. Lahogue ◽  
E. De Grave ◽  
E. Van Ranst ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Iron Oxides ◽  
Crack Opening ◽  
Temperature Fluctuations ◽  
Cement Type ◽  
Dr Congo ◽  
Near Surface ◽  
Cemented Sand ◽  
Quartz Grains ◽  
Development And Evolution

Quartz grains in an iron sandstone layer in near-surface sandy deposits at Kasangulu, south of Kinshasa, DR Congo, are marked by the presence of iron oxides in subparallel horizontal cracks within the sand grains. This exceptional feature was investigated to understand its origin and paleoenvironmental significance. Based on thin section observations, supplemented by Mössbauer spectroscopy results and other data, the occurrence of filled subparallel cracks is attributed to iron oxide remobilisation following crack opening within an iron-oxide-cemented sand intercalation that became exposed through erosion, whereby crack opening is related to surface temperature fluctuations. The development of filled crack occurrences of this type requires a period of surface exposure, implying that their presence is indicative of the position of former surface levels. A macroscopically similar iron sandstone layer at another locality in the Kinshasa area, lacking filled cracks, provides indications for both surface exposure and cement type as factors in their development.

scholarly journals Morphological Analysis of Quartz Grains of Two Horizons in a Ultisol, Paraná – Brazil (Análise morfológica de grãos de quartzo de dois horizontes de Argissolos, Paraná – Brasil)

2017 ◽  
Vol 10 (4) ◽  
pp. 1059
Author(s):  
Fabiana Cristina Meira Zaparoli ◽  
Nelson Vicente Lovatto Gasparetto
Keyword(s):  
Iron Oxide ◽  
Surface Morphology ◽  
Iron Oxides ◽  
Morphological Analysis ◽  
Chemical Change ◽  
Subtropical Climate ◽  
Plasma Infusion ◽  
The City ◽  
Quartz Grains ◽  
Bt Horizon

This research aimed to compare the surface morphology of quartz grains of the E and Bt horizons of an Ultisol of the Aratu stream basin, in the city of Floraí, Paraná. The Ultisol is derived from sandstones of the Caiuá Formation and it is subjected to mesothermal humid subtropical climate. The materials from the E horizon showed abundant porosity compared to the Bt horizon ones, due to the filling of pores by coating of clay and iron oxides. On the surface of the quartz grains of the E horizon, several features were identified such as ";craters";, pyramidal microfeatures, gulfs of dissolution, elongated cavities, and silica reprecipitation, resulting from the chemical change, and fragmented grains resulting from a phenomenon called ";plasma infusion."; In the Bt horizon, nearly all the detrital grains were surrounded by clay and iron oxide. The detrital grains of the Bt horizon were better preserved, showing little corrosion features and rare fragmented grains, compared to the E horizon. These analyzes showed that the water flow accounts for the superficial alteration of detrital quartz grains when they are under the influence of humid subtropical climate.  R E S U M OA pesquisa teve como objetivo comparar a morfologia superficial de grãos de quartzo dos horizontes E e Bt de um Argissolo da bacia do córrego Aratu, no município de Floraí, PR. O Argissolo é derivado de arenitos da Formação Caiuá e submetido a clima subtropical úmido mesotérmico. Os materiais do horizonte E apresentam porosidade abundante quando comparados com os do horizonte Bt, em razão do preenchimento dos poros por revestimentos de argila e óxidos de ferro. Foram identificadas na superfície dos grãos de quartzo do horizonte E várias feições tipo “crateras”, microfeições piramidais, golfos de dissolução, cavidades alongadas, reprecipitação de sílica, oriundas da alteração química, e grãos fragmentados devido ao fenômeno denominado “plasma infusion”. No horizonte Bt, praticamente todos os grãos detritais estão envolvidos por argila e óxidos de ferro. Os grãos detritais do horizonte Bt estão mais preservados, exibindo poucas feições de corrosão e raros grãos fragmentados, se comparados com os do horizonte E. Essas análises demonstraram que o fluxo hídrico é o responsável pela alteração superficial dos grãos detritais de quartzo quando sob a influência de clima subtropical úmido. Palavras-chave: Argissolo, morfologia de grãos de quartzo, alteração geoquímica, fluxo hídrico 

scholarly journals IV.—Woodwardian Laboratory Notes—N. Wales Rocks IV

1883 ◽  
Vol 10 (1) ◽  
pp. 17-21
Author(s):  
E. B. Tawney
Keyword(s):  
Iron Oxide ◽  
Iron Oxides ◽  
Dark Colour ◽  
Grey Colour ◽  
Quartz Grains ◽  
Amorphous Matter

[C1. 41], Sedgwick Collection, from near the top of Bwlch Mawr, is a rock of greenish-grey colour, with rather fewer felspars than the last. In the microscope the ground is seen to be largely occupied by squarish crystals of felspar, between which is some crypto-crystal-line matter. The larger felspars seem all plagioclase, but they are all much decomposed, some of the smaller ones are perhaps ortho-clase. There is no pyroxenic mineral preserved; calcite aggregations result, and also viridite extinguishing in no position. There are many minute quartz grains in the ground, which have the appearance of being secondary. Apatite is abundant; there are also black and brown crystals of iron oxides (ilmenite). A few crystals of epidote have been formed. No hornblende is to be found, and amorphous matter in the ground is uncertain, yet the rock may most conveniently be placed among the porphyrites. It has not, however, the andesitic structure of the Carn Boduan rock. The dark colour would be due to the chloritic matter and iron oxide scattered through the ground.

scholarly journals Discovery of Fe7O9: a new iron oxide with a complex monoclinic structure

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Ryosuke Sinmyo ◽  
Elena Bykova ◽  
Sergey V. Ovsyannikov ◽  
Catherine McCammon ◽  
Ilya Kupenko ◽  
...  
Keyword(s):  
Applied Sciences ◽  
Crystal Structure ◽  
Iron Oxide ◽  
Iron Oxides ◽  
Industrial Applications ◽  
Ambient Conditions ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Pressure High Temperature ◽  
Insight Into

Abstract Iron oxides are fundamentally important compounds for basic and applied sciences as well as in numerous industrial applications. In this work we report the synthesis and investigation of a new binary iron oxide with the hitherto unknown stoichiometry of Fe7O9. This new oxide was synthesized at high-pressure high-temperature (HP-HT) conditions, and its black single crystals were successfully recovered at ambient conditions. By means of single crystal X-ray diffraction we determined that Fe7O9 adopts a monoclinic C2/m lattice with the most distorted crystal structure among the binary iron oxides known to date. The synthesis of Fe7O9 opens a new portal to exotic iron-rich (M,Fe)7O9 oxides with unusual stoichiometry and distorted crystal structures. Moreover, the crystal structure and phase relations of such new iron oxide groups may provide new insight into the cycling of volatiles in the Earth’s interior.

scholarly journals Large Temperature Fluctuations due to Cold-Air Pool Displacement along the Lee Slope of a Desert Mountain

2017 ◽  
Vol 56 (4) ◽  
pp. 1083-1098 ◽  
Author(s):  
Matthew E. Jeglum ◽  
Sebastian W. Hoch ◽  
Derek D. Jensen ◽  
Reneta Dimitrova ◽  
Zachariah Silver
Keyword(s):  
Low Frequency ◽  
Temperature Fluctuations ◽  
Atmospheric Modeling ◽  
Large Temperature ◽  
Complex Flow ◽  
Near Surface ◽  
Cold Air ◽  
Flow Interactions ◽  
Initial Drop ◽  
Program Temperature

AbstractLarge temperature fluctuations (LTFs), defined as a drop of the near-surface temperature of at least 3°C in less than 30 min followed by a recovery of at least half of the initial drop, were frequently observed during the Mountain Terrain Atmospheric Modeling and Observations (MATERHORN) program. Temperature time series at over 100 surface stations were examined in an automated fashion to identify and characterize LTFs. LTFs occur almost exclusively at night and at locations elevated 50–100 m above the basin floors, such as the east slope of the isolated Granite Mountain (GM). Temperature drops associated with LTFs were as large as 13°C and were typically greatest at heights of 4–10 m AGL. Observations and numerical simulations suggest that LTFs are the result of complex flow interactions of stably stratified flow with a mountain barrier and a leeside cold-air pool (CAP). An orographic wake forms over GM when stably stratified southwesterly nocturnal flow impinges on GM and is blocked at low levels. Warm crest-level air descends in the lee of the barrier, and the generation of baroclinic vorticity leads to periodic development of a vertically oriented vortex. Changes in the strength or location of the wake and vortex cause a displacement of the horizontal temperature gradient along the slope associated with the CAP edge, resulting in LTFs. This mechanism explains the low frequency of LTFs on the west slope of GM as well as the preference for LTFs to occur at higher elevations later at night, as the CAP depth increases.

Waste Plastic Sachet as Alternative Anti-Corrosion Filler for Iron Oxide in Resin Coatings

2021 ◽  
Vol 877 ◽  
pp. 9-14
Author(s):  
Francis Darwin T. Eugenio ◽  
Bryan B. Pajarito
Keyword(s):  
Corrosion Resistance ◽  
Iron Oxide ◽  
Film Thickness ◽  
Iron Oxides ◽  
Water Resistance ◽  
Inorganic Compounds ◽  
Environmental Issues ◽  
Metal Coatings ◽  
Waste Plastic ◽  
Coating Mixture

Iron oxides and similar inorganic compounds have served as anti-corrosion fillers for metal coatings. Environmental issues related to the mining of metallic fillers have stimulated interest in alternative fillers such as organic fillers. This paper explores the use of comminuted waste plastic sachets (WPS) as an anti-corrosion filler to resin-based metal coating. Mixture design of experiment was used to study the effect of iron oxide-WPS blends on the film thickness, viscosity, corrosion behavior, and water resistance of the coating. Results show that the film thickness was affected by the presence of iron oxide while the viscosity of the coating was affected by high loads of WPS. Among all coatings, the blend containing 25% iron oxide and 75% WPS produced the highest corrosion resistance. In conclusion, comminuted WPS provided additional corrosion resistance and could serve as an alternative anti-corrosion filler.

scholarly journals Iron Oxide Contents in Relation to the Colour of Asnawa Soils

2017 ◽  
Vol 1 (1) ◽  
pp. 89-94
Author(s):  
Sherwan Kafoor
Keyword(s):  
Iron Oxide ◽  
Soil Properties ◽  
Iron Oxides ◽  
Soil Samples ◽  
Visual Methods ◽  
Colour Intensity ◽  
Fe Oxide ◽  
Fe Oxides ◽  
New Formula

Asnawa soils contain high amounts of iron oxides. These minerals apply much influence on different soil properties, of which the most observable is colour. The objective of this study was to conclude if colour of soils measured by visual methods can be parameterized to quantify soil Fe oxides. The examined area was divided to three zones (zone A, zone B and zone C) according to their colour intensity. Forty soil samples were examined for their colour and iron oxide contents. Their colour were ranged between 5YR (H) 2.5 (V/C) to 5YR (H) 5/8 (V/C). The average values of free Fe oxide in the soils of the three zones were 52.1%, 36.8% and 15.9% respectively. A new formula was derived to measure colour intensity. A highly significant correlation was found between colour intensity and concentrations of Fe oxides in the examined soils.

Facilitated Heterogeneous Photodegradation of Dissolved Organic Matter by Particulate Iron

2004 ◽  
Vol 1 (3) ◽  
pp. 197 ◽  
Author(s):  
Julia A. Howitt ◽  
Darren S. Baldwin ◽  
Gavin N. Rees ◽  
Barry T. Hart
Keyword(s):  
Organic Matter ◽  
Iron Oxide ◽  
Dissolved Organic Matter ◽  
Iron Oxides ◽  
Aquatic Ecosystems ◽  
Photochemical Reactions ◽  
Freshwater Systems ◽  
Particulate Iron ◽  
Presence And Absence ◽  
Australian Freshwater

Environmental Context. Iron oxides, as suspended minerals or as a colloidal phase, are common in Australian freshwater systems. Freshwater systems are also loaded with carbon-based substances, ‘dissolved organic matter’, but not all is biologically available as food to freshwater organisms. However, photochemical interactions between these iron oxides and dissolved organic matter provide a mechanism for biologically resistant carbon to re-enter the food web. Suspended iron oxides thus need to be considered in carbon cycles in aquatic ecosystems. Abstract. The photochemical degradation of dissolved organic matter (DOM) derived from the leaves of River Red Gum (Eucalyptus camaldulensis) was examined, with a particular focus on the photochemical generation of CO2, consumption of O2, and the effect of particulate iron minerals on these photochemical reactions. Solutions of leaf leachate were irradiated with ultraviolet and visible light in the presence and absence of amorphous iron oxides. Addition of fresh iron oxide was found to increase the rate of photodegradation of the organic matter by up to an order of magnitude compared to the reactions without added iron oxide. The ratio of CO2 produced to O2 consumed was ~1:1 in both the presence and absence of iron oxyhydroxide. The reactivity of the iron oxides was dependent on the preparation method and decreased with increased storage time. These results suggest that photochemical reactions on particle surfaces should be considered when examining carbon transformation in aquatic ecosystems, especially at sites with potential for the production of iron oxyhydroxides.

Microstructure, Stiffness and Corrosion of Bare and Phosphated Specimens Made by Sintering of Structured Iron-Iron Oxide Spheres

2020 ◽  
Vol 405 ◽  
pp. 411-416
Author(s):  
Miriam Kupková ◽  
Martin Kupka ◽  
Renáta Oriňáková ◽  
Radka Gorejová
Keyword(s):  
Iron Oxide ◽  
Iron Oxides ◽  
Metallic Iron ◽  
Galvanic Corrosion ◽  
Iron Phosphate ◽  
Reduction Reaction ◽  
Diffusion Control ◽  
Iron Oxide Particles ◽  
Flow Through ◽  
Iron Iron

Granulated iron oxide particles were incompletely reduced to structured particles comprised metallic iron and residual iron oxides. Structured particles were pressed into prismatic compacts and sintered. Some of sintered specimens were subsequently phosphatized and calcined. Specimens with an iron phosphate coating were found stiffer than specimens without coating. In Hanks' solution, a galvanic corrosion was induced by more noble iron oxides coupled to a less noble metallic iron. This could explain higher corrosion potentials and higher rates of iron dissolution in comparison with a pure iron. The coating of specimens with iron phosphates shifted corrosion potentials towards more negative values and slowed down the dissolution of iron. This was most likely caused by a reduction in oxygen flow through the coating to iron-oxide cathodes, which has enhanced the influence of diffusion control on the kinetics of reduction reaction.

scholarly journals Air-temperature control on diurnal variations in microseismicity at Laohugou Glacier No. 12, Qilian Mountains

2019 ◽  
Vol 60 (79) ◽  
pp. 125-136 ◽  
Author(s):  
Tao Zhang ◽  
Yuqiao Chen ◽  
Min Ding ◽  
Zhongyan Shen ◽  
Yuande Yang ◽  
...  
Keyword(s):  
Short Duration ◽  
Crack Opening ◽  
Low Frequency ◽  
Local Stress ◽  
Stress Concentrations ◽  
Night Time ◽  
Strong Negative Correlation ◽  
Near Surface ◽  
Temperature Change Rate ◽  
Trigger Algorithm

ABSTRACTWe conducted a 9-d seismic experiment in October 2015 at Laohugou Glacier No. 12. We identified microseismic signals using the short-term/long-term average trigger algorithm at four stations and classified them as long and short-duration events based on waveform, frequency, duration and magnitude characteristics. Both categories show systematical diurnal trends. The long-duration events are low-frequency tremor-like events that mainly occurred during the daytime with only several events per day. These events lasted tens of seconds to tens of minutes and are likely related to resonance of daytime meltwater. The dominant short-duration events mostly occurred during the night time with a peak occurrence frequency of ~360 h−1. Their short-duration (<0.2 s), high frequency (20–100 Hz) and dominance of Rayleigh waves are typical of events for near-surface crack opening. A strong negative correlation between the hourly event number and temperature change rate suggests that the occurrence of night-time events is controlled by the rate of night-time cooling. We estimated the near-surface tensile stress due to thermal contraction at night to be tens of kilopascals, which is enough to induce opening of surface cracks with pre-existing local stress concentrations, although we cannot exclude the effect of refreezing of meltwater produced during the day.

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