scholarly journals Photoionisation Cross Sections of Chlorine Atoms and Molecules at 584 Å

1986 ◽  
Vol 39 (5) ◽  
pp. 779 ◽  
Author(s):  
WJ van der Meer ◽  
RJ Butselaar ◽  
CA de Lange

A recently developed modulation method is used to obtain cross sections for the photoionisation of ground state neutral to ground state ionic, atomic and molecular chlorine relative to that of the HCl + (X2n 1IZ,3IZ) +-- HCl(XI ~ +) transition at the He Ia wavelength. With the known absolute cross section of the latter process, determined by (e,2e) coincidence spectroscopy, the present ell,periments provide absolute photoionisation cross sections of the CI + epz,l,o) +-- Clep) and Cli (XZ n g, 1IZ,3 IZ) +-- Clz (X I ~ t) transitions. Relative cross sections, previously determined for the transitions to the additional Cl and Clz ionic states accessible with He Ia radiation, are used to obtain absolute cross sections for the Cl+(IDz, ISO) +-- Clep) and Cli(AZnu,1IZ,3IZ, BZ~t) +-- Clz(XI~t) ionisation processes.

Author(s):  
P.A. Crozier

Absolute inelastic scattering cross sections or mean free paths are often used in EELS analysis for determining elemental concentrations and specimen thickness. In most instances, theoretical values must be used because there have been few attempts to determine experimental scattering cross sections from solids under the conditions of interest to electron microscopist. In addition to providing data for spectral quantitation, absolute cross section measurements yields useful information on many of the approximations which are frequently involved in EELS analysis procedures. In this paper, experimental cross sections are presented for some inner-shell edges of Al, Cu, Ag and Au.Uniform thin films of the previously mentioned materials were prepared by vacuum evaporation onto microscope cover slips. The cover slips were weighed before and after evaporation to determine the mass thickness of the films. The estimated error in this method of determining mass thickness was ±7 x 107g/cm2. The films were floated off in water and mounted on Cu grids.


1987 ◽  
Vol 40 (3) ◽  
pp. 383 ◽  
Author(s):  
J Fletcher ◽  
PH Purdie

Low current, low pressure, steady state Townsend discharges in helium and neon gas have been investigated using the photon flux technique. Such discharges have been found to exhibit spatial non-uniformity resulting in luminous layers throughout the discharge. The separation and structure of these layers has been investigated experimentally in both gases along with the wavelength distribution of the photon flux. A Monte Carlo simulation of the discharge in neon has been used to gain information on the cross sections necessary to describe these discharges. It is found that direct excitaton of ground state atoms to the resonance level of each gas is less than indicated by some published cross section data.


Atoms ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 29 ◽  
Author(s):  
Sultana N. Nahar ◽  
Bobby Antony

A review on the positron scattering from atoms and molecules is presented in this article. The focus on positron scattering studies is on the rise due to their presence in various fields and application of cross section data in such environments. Positron scattering is usually investigated using theoretical approaches that are similar to those for electron scattering, being its anti-particle. However, most experimental or theoretical studies are limited to the investigation of electron and positron scattering from inert gases, single electron systems and simple or symmetric molecules. Optical potential and polarized orbital approaches are the widely used methods for investigating positron scattering from atoms. Close coupling approach has also been used for scattering from atoms, but for lighter targets with low energy projectiles. The theoretical approaches have been quite successful in predicting cross sections and agree reasonably well with experimental measurements. The comparison is generally good for electrons for both elastic and inelastic scatterings cross sections, while spin polarization has been critical due to its sensitive perturbing interaction. Positron scattering cross sections show relatively less features than that of electron scattering. The features of positron impact elastic scattering have been consistent with experiment, while total cross section requires significant improvement. For scattering from molecules, utilization of both spherical complex optical potential and R-matrix methods have proved to be efficient in predicting cross sections in their respective energy ranges. The results obtained shows reasonable comparison with most of the existing data, wherever available. In the present article we illustrate these findings with a list of comprehensive references to data sources, albeit not exhaustive.


2019 ◽  
Vol 211 ◽  
pp. 03009
Author(s):  
Paula Salvador-Castiñeira ◽  
Franz-Josef Hambsch ◽  
Alf Göök ◽  
Marzio Vidali ◽  
Nigel P. Hawkes ◽  
...  

New standard (n,f) cross sections other than 235U are important to study the relevant cross sections for Generation-IV power plants. A specific need for such standards is for performing new experiments with quasimonoenergetic neutron beams, such as those produced by Van de Graaf accelerators. Neutrons down-scattered to low energies in the experimental environment, so called room-return, become relevant for this type of measurements. Hence, a standard (n,f) cross section with a fission threshold is of great interest, in order to suppress the contribution from room-return background. For this reason we have performed two experiments at the VDG of the National Physical Laboratory to measure absolutely the (n,f) cross sections of 235U, 238U and 237Np in the fast neutron energy region. Our preliminary results are in agreement with the most up-to-date evaluations.


1979 ◽  
Vol 57 (8) ◽  
pp. 1174-1177
Author(s):  
S. P. Ojha ◽  
P. Tiwari

Cross sections for the singlet excitation of helium by proton impact have been computed using the Vainshtein, Presnyakov, and Sobelman (VPS) method with peaking approximation. Transitions from the ground state to the n1P(n = 2, 3, and 4) states have been taken into account. The results are compared with other theoretical and experimental findings.


1968 ◽  
Vol 46 (19) ◽  
pp. 2127-2131 ◽  
Author(s):  
M. Stupavsky ◽  
L. Krause

3 2P1/2 ↔ 3 2P3/2 excitation transfer in sodium, induced in inelastic collisions with ground-state N2, H2, HD, and D2 molecules, has been investigated in a series of sensitized fluorescence experiments. Mixtures of sodium vapor at a pressure of 5 × 10−7 Torr, and the gases, were irradiated with each NaD component in turn, and the fluorescence which contained both D components was monitored at right angles to the direction of the exciting beam. Measurements of the relative intensities of the NaD fluorescent components yielded the following collision cross sections for excitation transfer. For Na–N2 collisions: Q12(2P1/2 → P3/2) = 144 Å2, Q21(2P1,2 ← 2P3/2) = 76 Å2 for Na–H2 collisions: Q12 = 80 Å2, Q21 = 42 Å2. For Na–HD collisions: Q12 = 84 Å2, Q21 = 44 Å2. For Na–D2 collisions: Q12 = 98 Å2, Q21 = 52 Å2. The cross sections Q21 exhibit a slight resonance effect between the atomic and molecular rotational transitions.


2013 ◽  
Vol 12 (01) ◽  
pp. 1250093 ◽  
Author(s):  
YULIANG WANG ◽  
JINCHUN ZHANG ◽  
BAOGUO TIAN ◽  
KUN WANG ◽  
XIAORUI LIANG ◽  
...  

Based on the new accurate potential energy surface of the ground state of LiH2 system. Quasi-classical trajectory (QCT) calculations were carried out for the reaction LiH + H . The reaction probability of the title reaction for J = 0 has been calculated. The reaction cross sections were calculated as functions of the collision energy in the range 0.1–2.5 eV. The results were found to be well consistent with the previous real wave packet (RWP) and QCT results.


1991 ◽  
Vol 244 ◽  
Author(s):  
Jau-Sheng Wang ◽  
Elias Snitzer ◽  
George H. Sigel

ABSTRACTThe results to be presented focus on the optimization of tellurite glass compositions which are suitable both for doping with erbium oxide as well as subsequent for fiber drawing. The laser related properties, such as fluorescence spectrum, lifetime, and optical transition cross sections will be presented. Judd-Ofelt parameters for erbium in the glasses have been exploited to predict fluorescence lifetime, excited state absorption(ESA), ground state absorption(GSA) and ground state fluorescence(GSF). For comparison, the absorption cross section, emission cross section, excited state absorption(ESA)/ground state absorption(GSA)(0.8μm pumping) and fluorescence terminating in the ground state(GSF)/excited state absorption(ESA) ratios are calculated for both Al2O3-SiO2 and tellurite glasses.


Author(s):  
Manel Hariz Belgacem ◽  
Elhabib Guedda ◽  
Haikel Jelassi

<sub></sub> In this paper we present our calculation of the cross section ionization by electron impact of C V, N VI and O VII. Using the Flexible Atomic Code (FAC), we obtain the cross sections for the ionization of these ions from the ground state 1<sup>1</sup>S, and from the unstable states 2<sup>1</sup>S and 2<sup>3</sup>S. Our results are in good agreement with those based on the Coulomb Born (CB) approximation and the available measurements.


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