scholarly journals Structural Transformations and Their Precursors

1983 ◽  
Vol 36 (4) ◽  
pp. 553 ◽  
Author(s):  
TR Finlayson
Keyword(s):  
Thermal Expansion ◽  
Electron Diffraction ◽  
Physical Properties ◽  
Elastic Constants ◽  
Direct Evidence ◽  
Indirect Evidence ◽  
Structural Transformations ◽  
X Ray ◽  
Kinetics Of

For a number of materials which exhibit a change of structure on being cooled below a certain temperature Tm, some physical properties display anomalous behaviour at temperatures above Tm. The particular structural transformations in mind have been broadly classified as 'martensitic' and the anomalous physical properties as 'precursive phenomena'. Some debate exists regarding the role of the precursive phenomenon in the kinetics of the structural transformation. The most direct evidence for 'martensite precursors' is obtained from electron diffraction, although various indirect evidence is contained in X-ray, neutron and y-ray diffraction and various physical properties, for example, elastic constants and thermal expansion. In this paper current understanding of 'martensite precursors' is reviewed and examples of data from the A15 structure compounds V 3Si and Nb3Sn,. In-TI and TiNi alloys are discussed.

Evidence for ordered Fe3Ni

1987 ◽  
Vol 45 ◽  
pp. 216-217
Author(s):  
K.B. Reuter ◽  
D.B. Williams ◽  
J.I. Goldstein
Keyword(s):  
Experimental Data ◽  
Martensitic Transformation ◽  
Electron Diffraction ◽  
Room Temperature ◽  
Direct Evidence ◽  
Transformation Product ◽  
Iron Meteorites ◽  
X Ray ◽  
Ni Content ◽  
Temperature Transformation

In the Fe-Ni system, although ordered FeNi and ordered Ni3Fe are experimentally well established, direct evidence for ordered Fe3Ni is unconvincing. Little experimental data for Fe3Ni exists because diffusion is sluggish at temperatures below 400°C and because alloys containing less than 29 wt% Ni undergo a martensitic transformation at room temperature. Fe-Ni phases in iron meteorites were examined in this study because iron meteorites have cooled at slow rates of about 10°C/106 years, allowing phase transformations below 400°C to occur. One low temperature transformation product, called clear taenite 2 (CT2), was of particular interest because it contains less than 30 wtZ Ni and is not martensitic. Because CT2 is only a few microns in size, the structure and Ni content were determined through electron diffraction and x-ray microanalysis. A Philips EM400T operated at 120 kV, equipped with a Tracor Northern 2000 multichannel analyzer, was used.

Structural evolution in lead substituted Bi–Sr–Ca–Cu–O superconductors

1991 ◽  
Vol 6 (2) ◽  
pp. 278-288 ◽  
Author(s):  
R. Ramesh ◽  
K. Remschnig ◽  
J.M. Tarascon ◽  
S.M. Green
Keyword(s):  
Structural Evolution ◽  
Homogeneous Sample ◽  
X Ray ◽  
Thermodynamics And Kinetics ◽  
Transmission Electron ◽  
Incommensurate Modulation ◽  
Kinetics Of ◽  
Pb Substitution ◽  
Microstructural Homogeneity

The structural evolution and cationic stoichiometry of Bi(Pb)–Sr–Ca–Cu–O superconductors have been studied using transmission electron microscopy and x-ray microanalysis. The nature of the incommensurate modulation changes systematically as increasing amounts of lead are added. X-ray microanalysis studies reveal that lead replaces Bi in the structure. Pb addition improves the microstructural homogeneity leading to the formation of a nearly homogeneous sample consisting of the “2223” phase. Based upon all the experimental results, it is inferred that the role of Pb substitution is related to the thermodynamics and kinetics of the formation of the n = 3 phase.

scholarly journals Role of Ti-Ru interaction in SrTi0.5Ru0.5O3 : Physical properties, x-ray spectroscopy, and cluster model calculations

2019 ◽  
Vol 100 (7) ◽  
Author(s):  
E. B. Guedes ◽  
F. Abud ◽  
H. P. Martins ◽  
M. Abbate ◽  
R. F. Jardim ◽  
...  
Keyword(s):  
Physical Properties ◽  
Cluster Model ◽  
Model Calculations ◽  
X Ray

scholarly journals The role of heat conduction to the formation of [WC]-type planetary nebulae

2011 ◽  
Vol 7 (S283) ◽  
pp. 494-495
Author(s):  
Christer Sandin ◽  
Matthias Steffen ◽  
Ralf Jacob ◽  
Detlef Schönberner ◽  
Ute Rühling ◽  
...  
Keyword(s):  
Heat Conduction ◽  
Chemical Composition ◽  
Physical Properties ◽  
Planetary Nebulae ◽  
Time Dependent ◽  
Diffuse Emission ◽  
Hydrodynamic Models ◽  
X Ray ◽  
Central Stars

AbstractX-ray observations of young Planetary Nebulæ (PNe) have revealed diffuse emission in extended regions around both H-rich and H-deficient central stars. In order to also reproduce physical properties of H-deficient objects, we have, at first, extended our time-dependent radiation-hydrodynamic models with heat conduction for such conditions. Here we present some of the important physical concepts, which determine how and when a hot wind-blown bubble forms. In this study we have had to consider the, largely unknown, evolution of the CSPN, the slow (AGB) wind, the fast hot-CSPN wind, and the chemical composition. The main conclusion of our work is that heat conduction is needed to explain X-ray properties of wind-blown bubbles also in H-deficient objects.

scholarly journals Investigating Possible Gastroliths in a Referred Specimen of Bohaiornis guoi (Aves: Enantiornithes)

2021 ◽  
Vol 9 ◽  
Author(s):  
Shumin Liu ◽  
Zhiheng Li ◽  
Alida M. Bailleul ◽  
Min Wang ◽  
Jingmai O’Connor
Keyword(s):  
Digestive System ◽  
Multidisciplinary Approach ◽  
Direct Evidence ◽  
Soft Tissues ◽  
Indirect Evidence ◽  
Stomach Contents ◽  
Gastric Mill ◽  
Limited Evidence ◽  
X Ray ◽  
Two Samples

Gastroliths, where preserved, can provide indirect evidence regarding diet in extinct avian and non-avian dinosaurs. Masses of gastroliths consistent with the presence of a gastric mill are preserved in many Early Cretaceous Jehol birds mostly belonging to the Ornithuromorpha. Gastroliths are also present in basal birds Sapeornis and Jeholornis in which herbivory is supported by direct evidence these taxa consumed seeds in the form of crop or stomach contents. Although gastroliths have been correlated with herbivory in non-avian dinosaurs, the presence of gastroliths and bone together in Ambopteryx calls this association in to question. Despite being known from greater numbers of specimens than other avian lineages, no unequivocal direct or indirect evidence of diet has been recovered from Jehol deposits for the Enantiornithes. A referred specimen of Bohaiornis guoi IVPP V17963 was described as preserving a small number of gastroliths interpreted as rangle, gastroliths whose function is cleaning the stomach in extant raptorial birds. However, based on comparison with gastroliths in other Jehol birds, it has alternatively been suggested that the identified structures are not ingested stones at all but some unusual mineral precipitate. Considering the limited evidence regarding diet in Enantiornithes and the importance of accurately identifying the traces in Bohaiornis in order to understand the enantiornithine digestive system, we extracted two samples of these purported gastroliths and explored these traces using computerized laminography scanning, scanning electron microscopy, energy dispersive x-ray spectroscopy, ground sections, and body size to gastral mass regressions. Similar analyses were conducted on gastroliths extracted from undisputed gastral masses of two Jehol ornithuromorphs and the non-avian pennaraptoran Caudipteryx. The combined results contradict the hypothesis that these traces are gastroliths and supports the interpretation they are mineral precipitate, most likely authigenic quartz (chalcedony). Although authigenesis is commonly responsible for the preservation of soft tissues, it is unclear if these traces record part of the tissues of this Bohaiornis. This study highlights the importance of a multidisciplinary approach in understanding unusual traces in the fossil record and reveal a previously unidentified taphonomic phenomenon in fossils from Jehol deposits.

Kinetics of Lamellar Decomposition Reactions in U-Nb Alloys

2011 ◽  
Vol 172-174 ◽  
pp. 555-560 ◽  
Author(s):  
Robert E. Hackenberg ◽  
Heather M. Volz ◽  
Pallas A. Papin ◽  
Ann M. Kelly ◽  
Robert T. Forsyth ◽  
...  
Keyword(s):  
Direct Evidence ◽  
Practical Interest ◽  
Two Phase ◽  
X Ray ◽  
Decomposition Reactions ◽  
Nb Content ◽  
System 2 ◽  
Discontinuous Phase ◽  
Kinetics Of ◽  
Prolonged Holding

Discontinuous precipitation (DP) and discontinuous coarsening (DC) reactions have been observed in numerous alloy systems [1]. DP has been observed in the U-Nb system [2, 3, 4, 5]. The U-Nb phase diagram (Fig. 1) exhibits a continuous γ-BCC solid solution at high temperatures and a two-phase mixture of a-orthorhombic and γ-BCC below the 647°C monotectoid isotherm. The DP reaction occurs during continuous cooling and isothermal aging over 300-647°C. No metallographic evidence of a DC reaction in U-Nb has been published, although this is suggested from x-ray observations of distinct changes in the Nb content of the γ phase upon prolonged holding after the DP reaction [2, 3, 6]. This study will provide direct evidence for a DC reaction. Discontinuous and other aging reactions [7] are undesirable in U-Nb alloys, since they degrade corrosion resistance [5], ductility [8], and the shape-memory effect [9]. Hence, an improved understanding of the kinetics of these discontinuous phase transformations in U-Nb alloys is of practical interest.

scholarly journals Changes in Expression Level of OsHKT1;5 Alters Activity of Membrane Transporters Involved in K+ and Ca2+ Acquisition and Homeostasis in Salinized Rice Roots

2020 ◽  
Vol 21 (14) ◽  
pp. 4882
Author(s):  
Mohammad Alnayef ◽  
Celymar Solis ◽  
Lana Shabala ◽  
Takaaki Ogura ◽  
Zhonghua Chen ◽  
...  
Keyword(s):  
Direct Evidence ◽  
Xylem Sap ◽  
Feedback Regulation ◽  
Membrane Transporters ◽  
Expression Level ◽  
Xylem Parenchyma ◽  
Critical Determinant ◽  
Kinetics Of ◽  
Na Uptake

In rice, the OsHKT1;5 gene has been reported to be a critical determinant of salt tolerance. This gene is harbored by the SKC1 locus, and its role was attributed to Na+ unloading from the xylem. No direct evidence, however, was provided in previous studies. Also, the reported function of SKC1 on the loading and delivery of K+ to the shoot remains to be explained. In this work, we used an electrophysiological approach to compare the kinetics of Na+ uptake by root xylem parenchyma cells using wild type (WT) and NIL(SKC1) plants. Our data showed that Na+ reabsorption was observed in WT, but not NIL(SKC1) plants, thus questioning the functional role of HKT1;5 as a transporter operating in the direct Na+ removal from the xylem. Instead, changes in the expression level of HKT1;5 altered the activity of membrane transporters involved in K+ and Ca2+ acquisition and homeostasis in the rice epidermis and stele, explaining the observed phenotype. We conclude that the role of HKT1;5 in plant salinity tolerance cannot be attributed to merely reducing Na+ concentration in the xylem sap but triggers a complex feedback regulation of activities of other transporters involved in the maintenance of plant ionic homeostasis and signaling under stress conditions.

Dehydroxylation of Fe3+ , Mg-rich dioctahedral micas: (I) structural transformation

Clay Minerals ◽  
2000 ◽  
Vol 35 (3) ◽  
pp. 491-504 ◽  
Author(s):  
F. Muller ◽  
V. A. Drits ◽  
A. Plançon ◽  
G. Besson
Keyword(s):  
Crystal Structure ◽  
Electron Diffraction ◽  
Structural Models ◽  
Structural Transformations ◽  
X Ray ◽  
Plane Component ◽  
Unit Cells ◽  
Different Temperatures ◽  
Xrd Patterns ◽  
Octahedral Cations

AbstractCeladonite and glauconite samples heated at different temperatures were studied by X-ray and electron diffraction. For dioctahedral micas the in-plane component of the translation between layers (ccosβ/a), which is strongly dependent on the position of the vacant octahedral site, significantly decreases at temperatures greater than the temperature of maximum dehydroxylation. The simulation of XRD patterns from different structural models reveals the actual crystal structure of dehydroxylated samples as well as the dynamics of the structural transformations. In the nonheated state the samples consist of tv (trans-vacant) 2:1 layers. During dehydroxylation, cations migrate from cis- into trans-octahedra and have 5-fold coordination. In the averaged unit-cell the ‘residual’ anions formed after the dehydroxylation reaction occupy the former OH sites with probability equal to 0.5. The migration of octahedral cations is accompanied by the transformation of the C-centred layer unit-cells into primitive ones. In contrast to Fe, Al and Mg cations have a greater ability to migrate.

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