Potentiometric Sensors Based on Macrocyclic Ligands: 1,8-Naphthyridine and 1,10-Phenanthroline Derivatives

1992 ◽  
Vol 45 (6) ◽  
pp. 983 ◽  
Author(s):  
TJ Cardwell ◽  
RW Cattrall ◽  
LW Deady ◽  
KA Murphy ◽  
SS Tan
Keyword(s):  
Vinyl Chloride ◽  
Divalent Cations ◽  
Potassium Ion ◽  
Macrocyclic Ligands ◽  
Potentiometric Sensors ◽  
Macrocyclic Compounds ◽  
Cation Selectivity ◽  
Poly Vinyl Chloride ◽  
High Preference ◽  
Oxygen Atoms

The synthesis of some macrocyclic compounds based on 1,8-naphthyridine and 1,10-phenanthroline with rings containing four and five oxygen atoms is reported. These compounds were tested for cation selectivity in poly(vinyl chloride)-based potentiometric sensors. Nernstian esponse was observed towards the potassium ion but with low discrimination for potassium in the presence of other cations. Dimethyl 4-octyloxy-1,10-phenanthroline-2,9-dicarboxylate, a precursor to one of the macrocyclic series, showed a high preference for divalent cations such as Zn2+, Ba2+, Cu2+ and Co2+. .

scholarly journals Potentiometric Sensors for Iodide and Bromide Based on Pt(II)-Porphyrin

Sensors ◽  
2018 ◽  
Vol 18 (7) ◽  
pp. 2297 ◽  
Author(s):  
Dana Vlascici ◽  
Nicoleta Plesu ◽  
Gheorghe Fagadar-Cosma ◽  
Anca Lascu ◽  
Mihaela Petric ◽  
...  
Keyword(s):  
Diffusion Coefficient ◽  
Water Absorption ◽  
Vinyl Chloride ◽  
Potentiometric Sensors ◽  
Iodide Ions ◽  
Response Characteristics ◽  
Potentiometric Response ◽  
Poly Vinyl Chloride

Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) was used in the construction of new ion-selective sensors. The potentiometric response characteristics (slope and selectivity) of iodide and bromide-selective electrodes based on (PtTMeOPP) metalloporphyrin in o-nitrophenyloctylether (NPOE), dioctylphtalate (DOP) and dioctylsebacate (DOS) plasticized poly(vinyl chloride) membranes are compared. The best results were obtained for the membranes plasticized with DOP and NPOE. The sensors have linear responses with near-Nernstian slopes toward bromide and iodide ions and good selectivity. The membrane plasticized with NPOE was electrochemically characterized using the EIS method to determine its water absorption and the diffusion coefficient into the membrane.

Fiber-optic potassium ion sensor using alkyl-acridine orange in plasticized poly(vinyl chloride) membrane

1990 ◽  
Vol 62 (14) ◽  
pp. 1528-1531 ◽  
Author(s):  
Yuji. Kawabata ◽  
Ryuichi. Tahara ◽  
Toshito. Kamichika ◽  
Totaro. Imasaka ◽  
Nobuhiko. Ishibashi
Keyword(s):  
Acridine Orange ◽  
Vinyl Chloride ◽  
Fiber Optic ◽  
Potassium Ion ◽  
Ion Sensor ◽  
Poly Vinyl Chloride

Highly Sensitive and Selective Poly(vinyl chloride)-Membrane Potentiometric Sensors Based on a Calix[4]arene Derivative for 2-Furaldehyde

2009 ◽  
Vol 81 (16) ◽  
pp. 6789-6796 ◽  
Author(s):  
Mojtaba Shamsipur ◽  
Ali Akbar Miran Beigi ◽  
Mohammad Teymouri ◽  
Solmaz Rasoolipour ◽  
Zouhair Asfari
Keyword(s):  
Vinyl Chloride ◽  
Potentiometric Sensors ◽  
Arene Derivative ◽  
Poly Vinyl Chloride ◽  
Highly Sensitive

Studies on Cation Selectivities of Some Pyridine-Based Ionophores for Use in Polymer Membrane Chemical Sensors

1991 ◽  
Vol 44 (11) ◽  
pp. 1603 ◽  
Author(s):  
MRM Bates ◽  
TJ Cardwell ◽  
RW Cattrall ◽  
LW Deady ◽  
K Murphy
Keyword(s):  
Dicarboxylic Acid ◽  
Related Compound ◽  
Chemical Sensors ◽  
Membrane Electrodes ◽  
Macrocyclic Compounds ◽  
Cation Selectivity ◽  
Poly Vinyl Chloride ◽  
Class B ◽  
Sulfur Containing ◽  
Sulfur Containing Compounds

The synthesis of some macrocyclic compounds based on 4-octyloxypyridine-2,6-dicarboxylic acid, containing sulfur and/or oxygen atoms in the 2 to 6-bridging unit, along with some non-cyclic analogues is reported. These were tested for cation selectivity in poly(vinyl chloride)-based membrane electrodes. Little selectivity was found for any ion with the oxygen-containing compounds, and none approached the selectivity for potassium reported previously for a related compound. High bonding affinities for class b acceptors, particularly Ag+ and Hg2+, were found for sulfur-containing compounds. The complexation with Hg2+ was so strong that the electrodes showed behaviour characteristic of an anion response.

Potentiometric sensors with plastized poly(vinyl chloride) membranes selective to penicillin antibiotics: Properties and applications

2015 ◽  
Vol 55 (10) ◽  
pp. 892-900 ◽  
Author(s):  
E. G. Kulapina ◽  
N. M. Makarova ◽  
O. I. Kulapina ◽  
I. A. Utc ◽  
V. V. Baraguzina
Keyword(s):  
Vinyl Chloride ◽  
Potentiometric Sensors ◽  
Poly Vinyl Chloride

Porphyrins as carriers in poly(vinyl chloride)-based membrane potentiometric sensors for histamine

The Analyst ◽  
1999 ◽  
Vol 124 (9) ◽  
pp. 1319-1322 ◽  
Author(s):  
Mohammad K. Amini ◽  
Said Shahrokhian ◽  
Shahram Tangestaninejad
Keyword(s):  
Vinyl Chloride ◽  
Potentiometric Sensors ◽  
Poly Vinyl Chloride

scholarly journals Host-Tailored Sensors for Leucomalachite Green Potentiometric Measurements

2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
F. T. C. Moreira ◽  
R. B. Queirós ◽  
L. A. A. Truta ◽  
T. I. Silva ◽  
R. M. Castro ◽  
...  
Keyword(s):  
Steady State ◽  
Vinyl Chloride ◽  
Methacrylic Acid ◽  
Detection Limits ◽  
Potentiometric Sensors ◽  
Molecularly Imprinted ◽  
Poly Vinyl Chloride ◽  
Potentiometric Measurements ◽  
Leucomalachite Green ◽  
Biomimetic Sensor

A new biomimetic sensor for leucomalachite green host-guest interactions and potentiometric transduction is presented. The artificial host was imprinted in methacrylic acid or acrylamido-2-methyl-1-propanesulfonic acid-based polymers. Molecularly imprinted particles were dispersed in 2-nitrophenyloctyl ether and trapped in poly(vinyl chloride). The potentiometric sensors exhibited a near-Nernstianresponse in steady state evaluations, with slopes and detection limits ranging from 45.8 to 81.2 mVdecade-1and 0.28 to 1.01 μg mL-1, respectively. They were independent from the pH of test solutions within 3 to 5. Good selectivity was observed towards drugs that may contaminate water near fish cultures, such as oxycycline, doxycycline, enrofloxacin, trimethoprim, creatinine, chloramphenicol, and dopamine. The sensors were successfully applied to field monitoring of leucomalachite green in river samples. The method offered the advantages of simplicity, accuracy, applicability to colored and turbid samples, and automation feasibility.

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