scholarly journals Host-Tailored Sensors for Leucomalachite Green Potentiometric Measurements

2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
F. T. C. Moreira ◽  
R. B. Queirós ◽  
L. A. A. Truta ◽  
T. I. Silva ◽  
R. M. Castro ◽  
...  

A new biomimetic sensor for leucomalachite green host-guest interactions and potentiometric transduction is presented. The artificial host was imprinted in methacrylic acid or acrylamido-2-methyl-1-propanesulfonic acid-based polymers. Molecularly imprinted particles were dispersed in 2-nitrophenyloctyl ether and trapped in poly(vinyl chloride). The potentiometric sensors exhibited a near-Nernstianresponse in steady state evaluations, with slopes and detection limits ranging from 45.8 to 81.2 mVdecade-1and 0.28 to 1.01 μg mL-1, respectively. They were independent from the pH of test solutions within 3 to 5. Good selectivity was observed towards drugs that may contaminate water near fish cultures, such as oxycycline, doxycycline, enrofloxacin, trimethoprim, creatinine, chloramphenicol, and dopamine. The sensors were successfully applied to field monitoring of leucomalachite green in river samples. The method offered the advantages of simplicity, accuracy, applicability to colored and turbid samples, and automation feasibility.

Sensors ◽  
2018 ◽  
Vol 18 (7) ◽  
pp. 2297 ◽  
Author(s):  
Dana Vlascici ◽  
Nicoleta Plesu ◽  
Gheorghe Fagadar-Cosma ◽  
Anca Lascu ◽  
Mihaela Petric ◽  
...  

Pt(II) 5,10,15,20-tetra(4-methoxy-phenyl)-porphyrin (PtTMeOPP) was used in the construction of new ion-selective sensors. The potentiometric response characteristics (slope and selectivity) of iodide and bromide-selective electrodes based on (PtTMeOPP) metalloporphyrin in o-nitrophenyloctylether (NPOE), dioctylphtalate (DOP) and dioctylsebacate (DOS) plasticized poly(vinyl chloride) membranes are compared. The best results were obtained for the membranes plasticized with DOP and NPOE. The sensors have linear responses with near-Nernstian slopes toward bromide and iodide ions and good selectivity. The membrane plasticized with NPOE was electrochemically characterized using the EIS method to determine its water absorption and the diffusion coefficient into the membrane.


2009 ◽  
Vol 81 (16) ◽  
pp. 6789-6796 ◽  
Author(s):  
Mojtaba Shamsipur ◽  
Ali Akbar Miran Beigi ◽  
Mohammad Teymouri ◽  
Solmaz Rasoolipour ◽  
Zouhair Asfari

1990 ◽  
Vol 22 (2) ◽  
pp. 89-95 ◽  
Author(s):  
Jagbir Singh ◽  
Alok R. Ray ◽  
Harpal Singh

2018 ◽  
Vol 142 ◽  
pp. 107-114 ◽  
Author(s):  
Ivette Zuñiga-Zamorano ◽  
H. Iván Meléndez-Ortiz ◽  
Alejandro Costoya ◽  
Carmen Alvarez-Lorenzo ◽  
Angel Concheiro ◽  
...  

2015 ◽  
Vol 55 (10) ◽  
pp. 892-900 ◽  
Author(s):  
E. G. Kulapina ◽  
N. M. Makarova ◽  
O. I. Kulapina ◽  
I. A. Utc ◽  
V. V. Baraguzina

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