Organophosphorus compounds. XXI. Solvolysis and C3-substitution reactions of some 2,3-Dihydro-1H-1,2-benzazaphosphole 2-oxides and 2-sulfides

DJ Collins; PF Drygala; JM Swan

doi:10.1071/ch9841349

Organophosphorus compounds. XXI. Solvolysis and C3-substitution reactions of some 2,3-Dihydro-1H-1,2-benzazaphosphole 2-oxides and 2-sulfides

Australian Journal of Chemistry ◽

10.1071/ch9841349 ◽

1984 ◽

Vol 37 (6) ◽

pp. 1349 ◽

Cited By ~ 1

Author(s):

DJ Collins ◽

PF Drygala ◽

JM Swan

Keyword(s):

Ring Opening ◽

Organophosphorus Compounds ◽

Substitution Reactions ◽

Ring Opening Reactions ◽

Benzylidene Derivative ◽

Methyl Derivatives

The solvolysis in D2O/CD3SOCD3 of the 2-phenyl-2,3-dihydro-1H-1,2-benzazaphosphole 2-oxides (5a-c), the analogous 2-methyl derivatives (6a-c), and of the 2-methyl-2,3-dihydro-lH-1,2-benzaza-phosphole 2-sulfides (6d) and (6e) was examined semi-quantitatively by n.m.r. spectroscopy. 1-Methyl-2-phenyl-2,3-dihydro-1 H-1,2-benzazaphosphole 2-oxide (5b) was subjected to reductive ring-opening reactions, base-catalysed C3-alkylation, and base-catalysed formation of a 3-benzylidene derivative.

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Ring-opening reactions. 3. Mechanistic path vs. ring-strain control in elimination and substitution reactions of 1,1-dimethyl cyclic ammonium ions and their .alpha.,.alpha.'-dimethyl-substituted derivatives

The Journal of Organic Chemistry ◽

10.1021/jo00327a021 ◽

1981 ◽

Vol 46 (14) ◽

pp. 2944-2947 ◽

Cited By ~ 25

Author(s):

Gabriella Cospito ◽

Gabriello Illuminati ◽

Claudio Lillocci ◽

Horia Petride

Keyword(s):

Ring Opening ◽

Ammonium Ions ◽

Substitution Reactions ◽

Strain Control ◽

Ring Strain ◽

Ring Opening Reactions

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Ring-opening reactions. Part 4. The role of strain and stereochemical effects on the elimination and substitution reactions of small rings; the reactivity of 1,1-dimethylaziridinium systems

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29850001943 ◽

1985 ◽

pp. 1943 ◽

Cited By ~ 4

Author(s):

Maria Luisa Di Vona ◽

Gabriello Illuminati ◽

Claudio Lillocci

Keyword(s):

Ring Opening ◽

Substitution Reactions ◽

Ring Opening Reactions

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ChemInform Abstract: RING-OPENING REACTIONS. 3. MECHANISTIC PATH VS. RING-STRAIN CONTROL IN ELIMINATION AND SUBSTITUTION REACTIONS OF 1,1-DIMETHYL CYCLIC AMMONIUM IONS AND THEIR α,α′-DIMETHYL-SUBSTITUTED DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.198151110 ◽

1981 ◽

Vol 12 (51) ◽

Author(s):

G. COSPITO ◽

G. ILLUMINATI ◽

C. LILLOCCI ◽

H. PETRIDE

Keyword(s):

Ring Opening ◽

Ammonium Ions ◽

Substitution Reactions ◽

Strain Control ◽

Ring Strain ◽

Ring Opening Reactions

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ChemInform Abstract: Ring-opening Reactions. Part 4. The Role of Strain and stereochemical Effects on the Elimination and Substitution Reactions of Small Rings.

Chemischer Informationsdienst ◽

10.1002/chin.198617103 ◽

1986 ◽

Vol 17 (17) ◽

Author(s):

M. L. DI VONA ◽

G. ILLUMINATI ◽

C. LILLOCCI

Keyword(s):

Ring Opening ◽

Substitution Reactions ◽

Ring Opening Reactions

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ChemInform Abstract: Ring-Opening Reactions of Difluoro(methylene)cyclopropanes with Halogens and Amines.

ChemInform ◽

10.1002/chin.200912060 ◽

2009 ◽

Vol 40 (12) ◽

Author(s):

Xiao-Chun Hang ◽

Qing-Yun Chen ◽

Ji-Chang Xiao

Keyword(s):

Ring Opening ◽

Ring Opening Reactions

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Substituent Effects in Mechanochemical Allowed and Forbidden Cyclobutene Ring-Opening Reactions

Journal of the American Chemical Society ◽

10.1021/jacs.0c12088 ◽

2021 ◽

Author(s):

Cameron L. Brown ◽

Brandon H. Bowser ◽

Jan Meisner ◽

Tatiana B. Kouznetsova ◽

Stefan Seritan ◽

...

Keyword(s):

Ring Opening ◽

Substituent Effects ◽

Ring Opening Reactions

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ChemInform Abstract: Discovery of μ-Opioid Selective Ligands Derived from 1-Aminotetralin Scaffolds Made via Metal-Catalyzed Ring-Opening Reactions.

ChemInform ◽

10.1002/chin.200929090 ◽

2009 ◽

Vol 40 (29) ◽

Author(s):

Chris Dockendorff ◽

Shujuan Jin ◽

Madeline Olsen ◽

Mark Lautens ◽

Martin Coupal ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Reactions ◽

Selective Ligands ◽

Metal Catalyzed

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Stereoselective Synthesis of Tetraalkyl Cyclobutene-1,2,3,4-tetracarboxylates. Synthesis of Tetraalkyl (Z,Z)-Buta-1,3-diene-1,2,3,4-tetracarboxylates

Journal of Chemical Research ◽

10.1177/174751989902300829 ◽

1999 ◽

Vol 23 (8) ◽

pp. 512-513

Author(s):

Issa Yavari ◽

Farahnaz Nourmohammadian

Keyword(s):

Ring Opening ◽

Wittig Reaction ◽

Stereoselective Synthesis ◽

Intramolecular Wittig Reaction ◽

Ring Opening Reactions ◽

Boiling Toluene

Tetraalkyl cyclobutene-1,2,3,4-tetracarboxylates, prepared by intramolecular Wittig reaction between a vinylphosphonium salt and diethyl 2-oxobutanedioate, undergo electrocyclic ring-opening reactions, in boiling toluene, to produce highly electron-deficient 1,3-dienes.

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