Cotton-Mouton and Kerr constants of twelve non-dipolar tri- and hexa-substituted benzenes

1982 ◽  
Vol 35 (5) ◽  
pp. 869 ◽  
Author(s):  
GLD Ritchie ◽  
J Vrbancich
Keyword(s):  
Carbon Tetrachloride ◽  
High Frequency ◽  
Infinite Dilution ◽  
Experimental Results ◽  
Lower Sensitivity ◽  
Polarizability Anisotropy ◽  
Substituted Benzenes ◽  
Significant Temperature ◽  
Predicted Values ◽  
Kerr Constants

Measurements of the infinite-dilution molar Cotton-Mouton and Kerr constants of 12 non-dipolar 1,3,5-tri- and hexa-substituted benzenes as solutes in carbon tetrachloride at 298 K are reported. Some of the experimental results are in notable disagreement with earlier determinations made on equipment of much lower sensitivity. Although the magnetic anisotropies derived for the tri-substituted benzenes are concordant with other observed or predicted values, those for the hexa-substituted benzenes are generally very much larger than expected. It is suggested, in explanation, that relatively large and strongly anisotropic atomic polarizabilities may cause the ratio of the static to the high-frequency polarizability anisotropy to be considerably smaller in the hexa-substituted benzenes than in benzene; in addition, there may be significant temperature independent contributions to the magnetic birefringences of these molecules.

Dipole Moments, Kerr Constants and Solute Conformations of the Aryl Methyl Sulfones p-XC6H4S(02)CH3 (X = H, Cl, BR or NO2)

1987 ◽  
Vol 40 (3) ◽  
pp. 619 ◽  
Author(s):  
MJ Aroney ◽  
RJW LeFevre ◽  
RK Pierens ◽  
HJ Stootman ◽  
MGM Yong
Keyword(s):  
Experimental Data ◽  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Dipole Moments ◽  
Solution State ◽  
Dimethyl Sulfone ◽  
Kerr Constants ◽  
Aryl Methyl

Measurements are reported of the infinite-dilution dipole moments and molar Kerr constants of dimethyl sulfone and of the four aryl methyl sulfones p-XC6H4S(02)CH3 (X = H, Cl, Br or NO2) dissolved in carbon tetrachloride or dioxan at 298 K and under light of 589 nm. The experimental data are analysed to obtain information on the solution-state conformations in relation to steric and electromeric effects operative between the aryl and methanesulfonyl groups.

Kerr constants and conformations of some p-substituted benzaldehydes

1982 ◽  
Vol 35 (3) ◽  
pp. 663
Author(s):  
D Mirarchi ◽  
GLD Ritchie ◽  
AJ Williams
Keyword(s):  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Molecular Conformations ◽  
Substituted Benzaldehydes ◽  
Kerr Constants

Analysis of the experimental infinite-dilution molar Kerr constants of five p-substituted benzaldehydes (X-C6H4-CHO; X = NO2, CN, F, Cl, Br) as solutes in carbon tetrachloride at 298 K confirms that uniplanar molecular conformations are preferred.

Partial molal volumes of some halobenzenes in carbon tetrachloride

1983 ◽  
Vol 61 (7) ◽  
pp. 1414-1416 ◽  
Author(s):  
Fereidoon Shahidi
Keyword(s):  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Van Der Waals ◽  
Alkyl Halides ◽  
Substituted Benzenes ◽  
Halogen Atoms ◽  
Partial Molal Volumes ◽  
Molal Volumes

The partial molal volumes at infinite dilution [Formula: see text] for a number of halobenzenes are measured and related to their van der Waals volumes. Results indicate larger volume increments for halogen atoms in halobenzenes than those in alkyl halides. Possible explanations are forwarded. The effect of steric overcrowding in ortho-substituted benzenes on the [Formula: see text] values are evaluated.

Effects of p-substituents on the conformation of acetophenone

1981 ◽  
Vol 34 (7) ◽  
pp. 1443 ◽  
Author(s):  
D Mirarchi ◽  
GLD Ritchie
Keyword(s):  
Carbon Tetrachloride ◽  
Dihedral Angle ◽  
Infinite Dilution ◽  
Dipole Moments ◽  
Reported Data ◽  
Kerr Constants

Experimental dipole moments and infinite-dilution molar Kerr constants are reported for six p-substituted acetophenones (CH3COC6H4X; X = Me, But, NO2, CN, F, Br) as solutes in carbon tetrachloride at 298 K. Analysis of these results and reconsideration of previously reported data for acetophenone and p-chloroacetophenone yields the dihedral angle, Φ, between the planes of the carbonyl and aryl groups in the effective conformation of each molecule (X = H, Φ = 0°; Me, 0°; But, 10�10°; NO2, 20�15°; NO2, 20�20°; F, 27�5°; Cl, 32�5°; Br, 30�10°).

Dipole moments, Kerr constants and solution-state conformations of 1- and 2-pivaloylnaphthalene

1982 ◽  
Vol 35 (11) ◽  
pp. 2341 ◽  
Author(s):  
D Mirarchi ◽  
GLD Ritchie
Keyword(s):  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Dipole Moments ◽  
Dihedral Angles ◽  
Solution State ◽  
Kerr Constants

Infinite-dilution dipole moments (1030p/Cm) and molar Kerr constants (1027mK/m5 V-2 mol-1) for 1-pivaloylnaphthalene (8.83,-490) and 2-pivaloylnaphthalene (9.24, 218) as solutes in carbon tetrachloride at 25�C are reported and analysed to yield the dihedral angles between the Car-CO-C and naphthyl planes as 90 � 10� and 53 � 8�, respectively.

Dipole moment, Kerr constant, Cotton-Mouton constant and conformation of 1,4-dithiin

1982 ◽  
Vol 35 (11) ◽  
pp. 2335 ◽  
Author(s):  
D Mirarchi ◽  
L Phillips ◽  
GLD Ritchie
Keyword(s):  
Dipole Moment ◽  
Carbon Tetrachloride ◽  
Magnetic Anisotropy ◽  
Infinite Dilution ◽  
Kerr Constant ◽  
Polarizability Anisotropy ◽  
Solution State

Measurements of the infinite-dilution dipole moment, molar Kerr constant and molar Cotton-Mouton constant of 1,4-dithiin dissolved in cyclohexane and carbon tetrachloride at 25�C are reported and analysed to provide information concerning the solution-state conformation, the polarizability anisotropy and the magnetic anisotropy of this molecule.

The molar kerr constants, dipole moments, and relaxation times of Methyl and Ethyl Maleates and fumarates, Ethyl Formate, Diethyl Oxalate, and of Ethyl and Propyl Azodiformates

1957 ◽  
Vol 10 (3) ◽  
pp. 218 ◽  
Author(s):  
CG Le Fevre ◽  
RJW Le Fevre ◽  
WT Oh
Keyword(s):  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Dipole Moments ◽  
Azimuthal Angle ◽  
Relaxation Times ◽  
Ethyl Formate ◽  
The Other ◽  
Diethyl Oxalate ◽  
Negative Results ◽  
Kerr Constants

Values for the properties and compounds named in the title are recorded at infinite dilution in carbon tetrachloride at 25 �C. Dipole moments of the seven diesters lie between 2 2 and 2.8 D ; the molar Kerr constants of the two azodiformates however differ from those of the maleates, fumarates, and oxalate in being negative. Results with ethyl oxalate are consistent with a structure in which the two ?CO2Et groups are in planes making an azimuthal angle c. 90�. Indications of configurations for the other esters are discussed, but conclusions are indefinite.

scholarly journals Synchronous Machine Winding Modeling Method Based on Broadband Characteristics

2021 ◽  
Vol 11 (10) ◽  
pp. 4631
Author(s):  
Yu Chen ◽  
Xiaoqing Ji ◽  
Zhongyong Zhao
Keyword(s):  
Equivalent Circuit ◽  
High Frequency ◽  
Equivalent Circuit Model ◽  
Black Box ◽  
Synchronous Machine ◽  
Circuit Model ◽  
Modeling Method ◽  
Experimental Results ◽  
Box Model ◽  
Impedance Curve

The accurate establishment of the equivalent circuit model of the synchronous machine windings’ broadband characteristics is the basis for the study of high-frequency machine problems, such as winding fault diagnosis and electromagnetic interference prediction. Therefore, this paper proposes a modeling method for synchronous machine winding based on broadband characteristics. Firstly, the single-phase high-frequency lumped parameter circuit model of synchronous machine winding is introduced, then the broadband characteristics of the port are analyzed by using the state space model, and then the equivalent circuit parameters are identified by using an optimization algorithm combined with the measured broadband impedance characteristics of port. Finally, experimental verification and comparison experiments are carried out on a 5-kW synchronous machine. The experimental results show that the proposed modeling method identifies the impedance curve of the circuit parameters with a high degree of agreement with the measured impedance curve, which indicates that the modeling method is feasible. In addition, the comparative experimental results show that, compared with the engineering exploratory calculation method, the proposed parameter identification method has stronger adaptability to the measured data and a certain robustness. Compared with the black box model, the parameters of the proposed model have a certain physical meaning, and the agreement with the actual impedance characteristic curve is higher than that of the black box model.

scholarly journals PCDRN: Progressive Cascade Deep Residual Network for Pansharpening

2020 ◽  
Vol 12 (4) ◽  
pp. 676 ◽  
Author(s):  
Yong Yang ◽  
Wei Tu ◽  
Shuying Huang ◽  
Hangyuan Lu
Keyword(s):  
High Resolution ◽  
Loss Function ◽  
High Frequency ◽  
Experimental Results ◽  
Superior Performance ◽  
Residual Network ◽  
High Quality ◽  
Convolution Approach ◽  
Visual Assessments ◽  
Coarse To Fine

Pansharpening is the process of fusing a low-resolution multispectral (LRMS) image with a high-resolution panchromatic (PAN) image. In the process of pansharpening, the LRMS image is often directly upsampled by a scale of 4, which may result in the loss of high-frequency details in the fused high-resolution multispectral (HRMS) image. To solve this problem, we put forward a novel progressive cascade deep residual network (PCDRN) with two residual subnetworks for pansharpening. The network adjusts the size of an MS image to the size of a PAN image twice and gradually fuses the LRMS image with the PAN image in a coarse-to-fine manner. To prevent an overly-smooth phenomenon and achieve high-quality fusion results, a multitask loss function is defined to train our network. Furthermore, to eliminate checkerboard artifacts in the fusion results, we employ a resize-convolution approach instead of transposed convolution for upsampling LRMS images. Experimental results on the Pléiades and WorldView-3 datasets prove that PCDRN exhibits superior performance compared to other popular pansharpening methods in terms of quantitative and visual assessments.

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