Reactions of aryl diazonium salts and arylazo alkyl ethers. VI. A comparison of the available methods for the measurement of the rate of ionization of (Z)-arylazo alkyl ethers in alcoholic solvents

1982 ◽  
Vol 35 (2) ◽  
pp. 319 ◽  
Author(s):  
TJ Broxton ◽  
MJ Mcleish
Keyword(s):  
Substituent Effects ◽  
Ionization Rate ◽  
New Method ◽  
Diazonium Salts ◽  
Advantages And Disadvantages ◽  
Diazonium Ions ◽  
Alkyl Ethers ◽  
Trapping Agent ◽  
Ionization Rates

Two previously reported methods for the determination of the ionization rate of (Z)-arylazo alkyl ethers by using x-naphtholate ions as a trapping agent are compared. A new method, which uses thiophenolate ions to trap the free diazonium ions formed in this ionization, is reported. This method is recommended in preference to the earlier methods because it includes a correction for the effect of the ionic strength of the solution on the rate of ionization. Rates measured by the thiophenolate method are consequently lower than those measured by either of the two previous methods. The advantages and disadvantages of the new method are discussed. The magnitude of salt effects and substituent effects on the ionization of (Z)- and (E)-arylazo alkyl ethers are compared.

Lattice-constant and stress measurement in single crystals: a new method

2005 ◽  
Vol 38 (4) ◽  
pp. 678-684 ◽  
Author(s):  
Balder Ortner
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Lattice Constant ◽  
Stress Measurement ◽  
New Method ◽  
Lattice Plane ◽  
X Ray ◽  
Advantages And Disadvantages

A method for the X-ray determination of lattice-plane distances is given. Similar to Bond's method, it is based on the measurement of rocking curves, with some advantages and disadvantages compared with the former method. The new method is especially designed for single-crystal stress measurement. Its usefulness is demonstrated in two examples of lattice-constant and stress measurement.

scholarly journals On the Cosmic Ray-Induced Ionization Rate in Molecular Clouds

2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Ararat G. Yeghikyan
Keyword(s):  
Molecular Clouds ◽  
Column Density ◽  
Cosmic Ray ◽  
Ionization Rate ◽  
Electronic Interaction ◽  
Absorbing Medium ◽  
Be Star ◽  
Good Agreement ◽  
Ionization Rates

The transformation of the energy dependence of the cosmic ray proton flux in the keV to GeV region is investigated theoretically when penetrating inside molecular clouds ( mag). The computations suggest that energy losses of the cosmic ray particles by interaction with the matter of the molecular cloud are principally caused by the inelastic (electronic) interaction potential; the transformed energy distribution of energetic protons is determined mainly by the column density of the absorbing medium. A cutoff of the cosmic ray spectrum inside clouds by their magnetic fields is also phenomenologically taken into account. This procedure allows a determination of environment-dependent ionization rates of molecular clouds. The theoretically predicted ionization rates are in good agreement with those derived from astronomical observations of absorption lines in the spectrum of the cloud connected with the Herbig Be star LkH 101.

Reactions of aryl diazonium salts and arylazo alkyl ethers. III. Substituent effects in the ionization of anti-arylazo ethyl ethers in ethanol

1978 ◽  
Vol 31 (7) ◽  
pp. 1519 ◽  
Author(s):  
TJ Broxton
Keyword(s):  
Substituent Effects ◽  
Parameter Analysis ◽  
Diazonium Salts ◽  
Resonance Effects ◽  
Inductive Effects ◽  
Alkyl Ethers

A dual substituent parameter analysis of substituent effects on the ionization of anti-arylazo ethyl ethers in ethanol shows that the reaction is affected primarily by inductive effects. The reaction is insensitive to resonance effects and an explanation for this behaviour is offered.

Reactions of Aryl Diazonium Salts and Arylazo Alkyl Ethers. IV. Substituent Effects on the Rates of Some Reactions of syn-Arylazo Ethyl Ethers in Ethanol

1979 ◽  
Vol 32 (5) ◽  
pp. 1031 ◽  
Author(s):  
TJ Broxton
Keyword(s):  
Substituent Effects ◽  
Diazonium Salts ◽  
Recombination Mechanism ◽  
Alkyl Ethers

Substituent effects on the rates of ionization (kIS), decomposition (kD) and syn-anti interconversion (kp) for a number of syn-arylazo ethyl ethers have been measured. The rates of ionization and syn-anti interconversion correlate well with sigma while the rates of decomposition correlate with σ+. Substituent effects on the ionization of the syn-ethers are compared to those for ionization of the anti-ethers. Substituent effects on the rate of syn-anti interconversion support the proposed ionization-recombination mechanism.

scholarly journals New Method for Determination of Drain Saturation Voltage in Short Channel MOS Devices Between Liquid Helium to Room Temperature

2001 ◽  
Vol 24 (2) ◽  
pp. 129-134
Author(s):  
Y. Amhouche ◽  
A. El Abbassi ◽  
K. Raïs ◽  
E. Bendada ◽  
R. Rmaily
Keyword(s):  
Room Temperature ◽  
Impact Ionization ◽  
Ionization Rate ◽  
Channel Length ◽  
New Method ◽  
Short Channel ◽  
Mos Devices ◽  
Impact Ionization Rate ◽  
The Impact

A new method for drain saturation voltage extraction in submicron MOSFETs is presented. It is based on measurements of the partial derivative of the impact ionization rate. The method has been tested using main of channel length MOSFET devices and compared with others methods.

SUBSTITUENT EFFECTS ON13C CHEMICAL SHIFTS OF KETENIMINES A NEW METHOD FOR DETERMINATION OF σp−CONSTANTS

1979 ◽  
Vol 8 (7) ◽  
pp. 851-854 ◽  
Author(s):  
Joachim Firl ◽  
Karl Schink ◽  
Horst Schaschke
Keyword(s):  
Chemical Shifts ◽  
Substituent Effects ◽  
New Method

A new method for the determination of nitrates

1960 ◽  
Vol 23 ◽  
pp. 227-232 ◽  
Author(s):  
P WEST ◽  
G LYLES
Keyword(s):  
New Method

A New Method for the Determination of Plasma Activators of Fibrinolysis

1977 ◽  
Vol 37 (02) ◽  
pp. 210-215 ◽  
Author(s):  
R Margalit ◽  
E Gidron ◽  
Y Shalitin
Keyword(s):  
New Method ◽  
Effective Activator

SummaryThe term “effective activator” of plasminogen is proposed, to denote the resultant of activator-antiactivator interaction, and a method for the determination of the level of these activators is described. By adding axcess plasminogen to the euglobulin fraction of plasma the influence of the level of endogenous plasminogen and of the antiplasmin is eliminated. It is shown that the level of fibrinogen has very little bearing on the results. An effective activator unit is defined as equal to 1 CTA unit of urokinase activity on a fibrinogen-plasminogen substrate.

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