Molten potassium pyrosulfate: the reactions of alkali metal oxides, peroxides, nitrites and nitrates

1981 ◽  
Vol 34 (4) ◽  
pp. 885 ◽  
Author(s):  
AN Ford ◽  
SA Tariq
Keyword(s):  
Nitric Oxide ◽  
Alkali Metal ◽  
Nitrogen Dioxide ◽  
Metal Oxides ◽  
Lithium Oxide ◽  
Sodium Peroxide ◽  
Gaseous Products ◽  
Sodium And Potassium ◽  
Oxide Ion

The reactions of lithium oxide, sodium peroxide, the nitrites of sodium and potassium, and the nitrates of lithium, sodium and potassium with molten potassium pyrosulfate were investigated. It was found that gaseous products of reactions of peroxide, nitrites and nitrates consisted of, respectively, oxygen, nitrogen dioxide plus nitric oxide, and nitrogen dioxide plus oxygen. Pyrosulfate, after accepting an oxide ion from each of the above oxyanions, was converted into sulfate. The range of temperatures and stoichiometries of these reactions have been established.

Molten potassium pyrosulfate: the reactions of alkali metal hydroxides, hydrogen carbonates and carbonates

1981 ◽  
Vol 34 (3) ◽  
pp. 647 ◽  
Author(s):  
AN Ford ◽  
SA Tariq
Keyword(s):  
Carbon Dioxide ◽  
Alkali Metal ◽  
Acid Base ◽  
Metal Hydroxides ◽  
Produce Water ◽  
Gaseous Products ◽  
Potassium Hydrogen ◽  
Hydrogen Carbonates ◽  
Oxide Ions ◽  
Sodium And Potassium

The reactions of hydroxides of lithium, sodium and potassium; hydrogen carbonates of sodium and potassium and carbonates of lithium, sodium and potassium with molten potassium pyrosulfate were studied. It was found that during these Lux-Flood acid-base reactions, hydroxides, hydrogen carbonates and carbonates reacted with pyrosulfate to produce water, water plus carbon dioxide and carbon dioxide alone respectively, as the gaseous products. Pyrosulfate, after accepting oxide ions from these bases, was found in each case to be converted into sulfate. The temperatures and stoichiometries of these reactions have been established.

scholarly journals Alkali metal doping of black phosphorus monolayer for ultrasensitive capture and detection of nitrogen dioxide

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Azam Marjani ◽  
Mehdi Ghambarian ◽  
Mohammad Ghashghaee
Keyword(s):  
Alkali Metal ◽  
Nitrogen Dioxide ◽  
Work Function ◽  
Black Phosphorus ◽  
Research Interest ◽  
Metal Doping ◽  
Li Doping ◽  
Rational Development ◽  
Parallel Configuration ◽  
First Time

AbstractBlack phosphorus nanostructures have recently sparked substantial research interest for the rational development of novel chemosensors and nanodevices. For the first time, the influence of alkali metal doping of black phosphorus monolayer (BP) on its capabilities for nitrogen dioxide (NO2) capture and monitoring is discussed. Four different nanostructures including BP, Li-BP, Na-BP, and K-BP were evaluated; it was found that the adsorption configuration on Li-BP was different from others such that the NO2 molecule preferred a vertical stabilization rather than a parallel configuration with respect to the surface. The efficiency for the detection increased in the sequence of Na-BP < BP < K-BP < Li-BP, with the most significant improvement of + 95.2% in the case of Li doping. The Na-BP demonstrated the most compelling capacity (54 times higher than BP) for NO2 capture and catalysis (− 24.36 kcal/mol at HSE06/TZVP). Furthermore, the K-doped device was appropriate for both nitrogen dioxide adsorption and sensing while also providing the highest work function sensitivity (55.4%), which was much higher than that of BP (10.4%).

Heats of Formation of Alkali Metal and Alkaline Earth Metal Oxides and Hydroxides:  Surprisingly Demanding Targets for High-Level ab Initio Procedures

2003 ◽  
Vol 107 (29) ◽  
pp. 5617-5630 ◽  
Author(s):  
Michael B. Sullivan ◽  
Mark A. Iron ◽  
Paul C. Redfern ◽  
Jan M. L. Martin ◽  
Larry A. Curtiss ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Oxides ◽  
Ab Initio ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Heats Of Formation ◽  
Alkaline Earth Metal ◽  
Alkaline Earth Metal Oxides ◽  
High Level

Reactions of nitric oxide and nitrogen dioxide with coenzyme Q: involvement of the isoprenic chain

2013 ◽  
Vol 11 (8) ◽  
pp. 1399 ◽  
Author(s):  
Paola Astolfi ◽  
Laurence Charles ◽  
Didier Gigmes ◽  
Lucedio Greci ◽  
Corrado Rizzoli ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Nitrogen Dioxide ◽  
Coenzyme Q

Alkali metal-resistant mechanism for selective catalytic reduction of nitric oxide over V2O5/HWO catalysts

Fuel ◽  
2021 ◽  
Vol 304 ◽  
pp. 121445
Author(s):  
Running Kang ◽  
Junyao He ◽  
Feng Bin ◽  
Baojuan Dou ◽  
Qinglan Hao ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Alkali Metal ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction
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