scholarly journals The reaction between aluminium metal and aqueous solutions of the nitrite ion

1980 ◽  
Vol 33 (1) ◽  
pp. 169 ◽  
Author(s):  
PJ Hyde ◽  
IM Ritchie
Keyword(s):  
Aqueous Solutions ◽  
Induction Period ◽  
Sodium Nitrite ◽  
Room Temperature ◽  
Nitrite Ion ◽  
Aluminium Metal ◽  
Mechanism Of The Reaction

The reaction between aluminium metal and a 0.1 wt % solution of sodium nitrite at room temperature is described. Initially the reaction is slow, but after an induction period the aluminium corrodes catastrophically. The products of the reaction were identified as ammonia, hydrogen and bayerite. A possible mechanism of the reaction is suggested.

scholarly journals Supramolecular Frameworks Based on Rhenium Clusters Using the Synthons Approach

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2662
Author(s):  
Nathalie Audebrand ◽  
Antoine Demont ◽  
Racha El Osta ◽  
Yuri V. Mironov ◽  
Nikolay G. Naumov ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Crystal Structures ◽  
Ligand Exchange ◽  
Alkaline Earth ◽  
Room Temperature ◽  
Hydration Rate ◽  
Rhenium Cluster ◽  
New Compounds ◽  
Cluster Unit

The reaction of the K4[{Re6Si8}(OH)a6]·8H2O rhenium cluster salt with pyrazine (Pz) in aqueous solutions of alkaline or alkaline earth salts at 4 °C or at room temperature leads to apical ligand exchange and to the formation of five new compounds: [trans-{Re6Si8}(Pz)a2(OH)a2(H2O)a2] (1), [cis-{Re6Si8}(Pz)a2(OH)a2(H2O)a2] (2), (NO3)[cis-{Re6Si8}(Pz)a2(OH)a(H2O)a3](Pz)·3H2O (3), [Mg(H2O)6]0.5[cis-{Re6Si8}(Pz)a2(OH)a3(H2O)a]·8.5H2O (4), and K[cis-{Re6Si8}(Pz)a2(OH)a3(H2O)a]·8H2O (5). Their crystal structures are built up from trans- or cis-[{Re6Si8}(Pz)a2(OH)a4−x(H2O)ax]x−2 cluster units. The cohesions of the 3D supramolecular frameworks are based on stacking and H bonding, as well as on H3O2−bridges in the cases of (1), (2), (4), and (5) compounds, while (3) is built from stacking and H bonding only. This evidences that the nature of the synthons governing the cluster unit assembly is dependent on the hydration rate of the unit.

scholarly journals Ein Wasserstoffisotopieeffekt im CuSO4 * 5H2O

1969 ◽  
Vol 24 (10) ◽  
pp. 1502-1511
Author(s):  
Karl Heinzinger
Keyword(s):  
Water Vapor ◽  
Aqueous Solutions ◽  
Separation Factor ◽  
Room Temperature ◽  
Copper Ion ◽  
Hydrogen Isotopes ◽  
Bulk Water ◽  
Water Molecules ◽  
Hydration Water ◽  
Sulfate Solutions

Abstract There are two kinds of water in CuSO4·5H2O differing by their binding in the crystal. The oxygen of four water molecules is bonded to the copper ion, that of the fifth molecule is hydrogen bonded. It is shown that the D/H ratios of these two kinds of water differ by 5.7%, the light isotope being enriched in the water molecules coordinated with the copper ion. The results show that there is no exchange of the hydrogen isotopes during the time needed for dehydration at room temperature which takes several days. The assumption has been confirmed that the water coordinated with the copper ion leaves the crystal first on dehydration at temperatures below 50 °C. Additional measurements of the separation factor for the hydrogen isotopes between water vapor and copper sulfate solutions allow conclusions on the fractionation of the hydrogen isotopes between bulk water and hydration water in aqueous solutions.

scholarly journals Evaluation of temporal, seasonal and geographic stability of the molluscicidal property of Euphorbia splendens latex

1992 ◽  
Vol 34 (3) ◽  
pp. 183-191 ◽  
Author(s):  
Virginia Torres Schall ◽  
Mauricio Carvalho de Vasconcellos ◽  
Ana Luiza Villaça-Coelho ◽  
Fátima Eliana Ferreira-Lopes ◽  
Ivonise Paz da Silva
Keyword(s):  
Aqueous Solutions ◽  
Laboratory Tests ◽  
Large Scale ◽  
Room Temperature ◽  
Tropical Climate ◽  
Wide Distribution ◽  
Promising Material ◽  
Active Principle ◽  
Reference Substance ◽  
Belo Horizonte

Laboratory tests with aqueous solutions of Euphorbia splendens var. hislopii latex have demonstrated seasonal stability of the molluscicidal principle, with LD90 values of 1.14 ppm (spring), 1.02 ppm (fall), 1.09 ppm (winter), and 1.07 ppm (summer) that have been determined against Biomphalaria tenagophila in the field. Assays on latex collected in Belo Horizonte and Recife yielded LD90 values similar to those obtained with the reference substance collected in Rio de Janeiro (Ilha do Governador), demonstrating geographic stability of the molluscicidal effect. The molluscicidal action of aqueous dilutions of the latex in natura, centrifuged (precipitate) and lyophilized, was stable for up to 124 days at room temperature (in natura) and for up to 736 days in a common refrigerator at 10 to 12ºC (lyophilized product). A 5.0 ppm solution is 100% lethal for snails up to 13 days after preparation, the effect being gradually lost to almost total inactivity by the 30th day. This observation indicated that the active principle is instable. These properties together with the wide distribution of the plant, its resistance and adaptation to the tropical climate, its easy cultivation and the easy obtention of latex and preparation of the molluscicidal solution, make this a promising material for large-scale use in the control of schistosomiasis

scholarly journals Formation of Cyanide Ion by the Reaction of Amines and Nitrite Ion. III. Formation of Cyanide Ion by the Reaction of Glycine and Nitrite Ion at Various pH and Room Temperature

Eisei kagaku ◽  
1975 ◽  
Vol 21 (6) ◽  
pp. 326-329 ◽  
Author(s):  
TOSHIKO KOSHIMIZU ◽  
KAZUYUKI TAKAMATSU ◽  
MIKIHIRO KANEKO ◽  
SHOZO FUKUI ◽  
SABURO KANNO
Keyword(s):  
Room Temperature ◽  
Cyanide Ion ◽  
Nitrite Ion

CO Oxidation Activity at Room Temperature over Au/CeO2 Catalysts: Disclosure of Induction Period and Humidity Effect

ACS Catalysis ◽  
2014 ◽  
Vol 4 (10) ◽  
pp. 3481-3489 ◽  
Author(s):  
Shuo Zhang ◽  
Xiao-Song Li ◽  
Bingbing Chen ◽  
Xiaobing Zhu ◽  
Chuan Shi ◽  
...  
Keyword(s):  
Co Oxidation ◽  
Induction Period ◽  
Room Temperature ◽  
Humidity Effect ◽  
Oxidation Activity

scholarly journals Linseed oil: Characterization and study of its oxidative degradation

2020 ◽  
Vol 71 (1) ◽  
pp. 337 ◽  
Author(s):  
B. M. Berto ◽  
R. K.A. Garcia ◽  
G. D. Fernandes ◽  
D. Barrera-Arellano ◽  
G. G. Pereira
Keyword(s):  
Fatty Acid ◽  
Oxidative Stability ◽  
Induction Period ◽  
Room Temperature ◽  
Linseed Oil ◽  
Oxidative Degradation ◽  
Acid Value ◽  
Quality Parameters ◽  
Time Intervals ◽  
Accelerated Oxidation

This paper proposes to characterize and monitor the degradation of linseed oil under two oxidation conditions using some traditional oxidative and quality parameters. The experimental section of this study was divided into 2 stages. In the first one, three commercial linseed oil samples (OL1, OL2, and OL3) were characterized according to oxidative stability (90 °C) and fatty acid composition. In the second stage, the OL1 sample, selected due to its availability, was subjected to the following oxidation procedures: storage at room temperature conditions with exposure to light and air (temperature ranging from 7 to 35 °C) for 140 days and accelerated oxidation at 100 °C for 7h. Samples were collected at different time intervals and analyzed for oxidative stability (90 °C), peroxide value, and acid value. The results showed that all the samples presented a similar fatty acid profile and that the OL3 sample showed a higher induction period (p < 0.05). Regarding the oxidative degradation, the induction period of the OL1 sample reduced from 9.7 to 5.7 and 9.7 to 6.3 during 140 days of storage under room temperature and 7 h of accelerated oxidation, respectively. The end of induction period of the OL1 sample is expected to occur within 229 days according to an exponential mathematical model fitted to the induction period values at different temperatures. In addition, the OL1 sample met the limits proposed by Codex and Brazilian regulations for peroxide and acid values during the oxidation time intervals.

Precipitation and densification of magnetic iron compounds from aqueous solutions at room temperature

1998 ◽  
Vol 50 (3) ◽  
pp. 223-242 ◽  
Author(s):  
Oscar Perales Perez ◽  
Yoshiaki Umetsu ◽  
Hiroshi Sasaki
Keyword(s):  
Aqueous Solutions ◽  
Room Temperature ◽  
Iron Compounds
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