CO Oxidation Activity at Room Temperature over Au/CeO2 Catalysts: Disclosure of Induction Period and Humidity Effect

ACS Catalysis ◽  
2014 ◽  
Vol 4 (10) ◽  
pp. 3481-3489 ◽  
Author(s):  
Shuo Zhang ◽  
Xiao-Song Li ◽  
Bingbing Chen ◽  
Xiaobing Zhu ◽  
Chuan Shi ◽  
...  
Nanoscale ◽  
2019 ◽  
Vol 11 (24) ◽  
pp. 11755-11764 ◽  
Author(s):  
Kamel Eid ◽  
Mostafa H. Sliem ◽  
Aboubakr M. Abdullah

PtPd/CN nanorods synthesized via the rolling up mechanism enhanced the electrochemical and photoelectrochemical CO oxidation activity substantially at room temperature.


2021 ◽  
Vol 536 ◽  
pp. 147809
Author(s):  
Mingming Luo ◽  
Zhao Liang ◽  
Chao Liu ◽  
Xiaopeng Qi ◽  
Mingwei Chen ◽  
...  

2015 ◽  
Vol 345 ◽  
pp. 319-328 ◽  
Author(s):  
V. Johánek ◽  
M. Václavů ◽  
I. Matolínová ◽  
I. Khalakhan ◽  
S. Haviar ◽  
...  

2012 ◽  
Vol 116 (24) ◽  
pp. 13127-13132 ◽  
Author(s):  
Sheng-Liang Zhong ◽  
Lin-Fei Zhang ◽  
Lei Wang ◽  
Wei-Xin Huang ◽  
Cong-Min Fan ◽  
...  

2020 ◽  
Vol 71 (1) ◽  
pp. 337 ◽  
Author(s):  
B. M. Berto ◽  
R. K.A. Garcia ◽  
G. D. Fernandes ◽  
D. Barrera-Arellano ◽  
G. G. Pereira

This paper proposes to characterize and monitor the degradation of linseed oil under two oxidation conditions using some traditional oxidative and quality parameters. The experimental section of this study was divided into 2 stages. In the first one, three commercial linseed oil samples (OL1, OL2, and OL3) were characterized according to oxidative stability (90 °C) and fatty acid composition. In the second stage, the OL1 sample, selected due to its availability, was subjected to the following oxidation procedures: storage at room temperature conditions with exposure to light and air (temperature ranging from 7 to 35 °C) for 140 days and accelerated oxidation at 100 °C for 7h. Samples were collected at different time intervals and analyzed for oxidative stability (90 °C), peroxide value, and acid value. The results showed that all the samples presented a similar fatty acid profile and that the OL3 sample showed a higher induction period (p < 0.05). Regarding the oxidative degradation, the induction period of the OL1 sample reduced from 9.7 to 5.7 and 9.7 to 6.3 during 140 days of storage under room temperature and 7 h of accelerated oxidation, respectively. The end of induction period of the OL1 sample is expected to occur within 229 days according to an exponential mathematical model fitted to the induction period values at different temperatures. In addition, the OL1 sample met the limits proposed by Codex and Brazilian regulations for peroxide and acid values during the oxidation time intervals.


Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3077
Author(s):  
Rima D. Alharthy ◽  
Ahmed Saleh

In this study, we developed a new chemi-resistive, flexible and selective ammonia (NH3) gas sensor. The sensor was prepared by depositing thin film of polyaniline-cobalt ferrite (PAni-CoFe2O4) nanocomposite on flexible polyethylene terephthalate (PET) through an in situ chemical oxidative polymerization method. The prepared PAni-CoFe2O4 nanocomposite and flexible PET-PAni-CoFe2O4 sensor were evaluated for their thermal stability, surface morphology and materials composition. The response to NH3 gas of the developed sensor was examined thoroughly in the range of 1–50 ppm at room temperature. The sensor with 50 wt% CoFe2O4 NPs content showed an optimum selectivity to NH3 molecules, with a 118.3% response towards 50 ppm in 24.3 s response time. Furthermore, the sensor showed good reproducibility, ultra-low detection limit (25 ppb) and excellent flexibility. In addition, the relative humidity effect on the sensor performance was investigated. Consequently, the flexible PET-PAni-CoFe2O4 sensor is a promising candidate for trace-level on-site sensing of NH3 in wearable electronic or portable devices.


2008 ◽  
Vol 47 (26) ◽  
pp. 4762-4762
Author(s):  
Hanne Falsig ◽  
Britt Hvolbæk ◽  
Iben S. Kristensen ◽  
Tao Jiang ◽  
Thomas Bligaard ◽  
...  

2016 ◽  
Vol 6 (22) ◽  
pp. 8104-8116 ◽  
Author(s):  
Thandanani Cwele ◽  
N. Mahadevaiah ◽  
Sooboo Singh ◽  
Holger B. Friedrich ◽  
A. K. Yadav ◽  
...  

Synergism between Pd2+, Cu2+ and cerium ions in Ce0.93Pd0.02Cu0.05O2−δ gives improved reducibility and superior performance for CO oxidation.


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