Chemistry of the Group 1B metals. X. Reactions between silver arylacetylides and some rhodium(I) and iridium(I) complexes

OMA Salah; MI Bruce

doi:10.1071/ch9772639

Chemistry of the Group 1B metals. X. Reactions between silver arylacetylides and some rhodium(I) and iridium(I) complexes

Australian Journal of Chemistry ◽

10.1071/ch9772639 ◽

1977 ◽

Vol 30 (12) ◽

pp. 2639 ◽

Cited By ~ 18

Author(s):

OMA Salah ◽

MI Bruce

Keyword(s):

Cluster Compounds ◽

Zwitterionic Complexes

Reactions between AgC2Ar (Ar = Ph or C6F5) and RhCl(PPh3)3 or IrCl(CO)(PPh3)2 have given hexanuclear heteroatom cluster compounds M2Ag4(C2Ar)8(PPh3)2 (M = Rh or Ir), and the zwitterionic complexes {[Ag(PPh3)]+ [M(C2C6F5)4(PPh3)2]-} and {[Ag(PPh3)]2+ [Rh(C2C6F5)5(PPh3)] 2-}.The structures of these complexes are described and discussed, together with possible reactions by which they may be formed.

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Semibridging Phenyl Ligands in Iridium–Copper and Iridium–Silver Cluster Compounds: Synthesis, Structures, and Bonding

Organometallics ◽

10.1021/om400133w ◽

2013 ◽

Vol 32 (8) ◽

pp. 2416-2426 ◽

Cited By ~ 9

Author(s):

Richard D. Adams ◽

Mingwei Chen ◽

Gaya Elpitiya ◽

Xinzheng Yang ◽

Qiang Zhang

Keyword(s):

Silver Cluster ◽

Cluster Compounds

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ChemInform Abstract: HETERONUCLEAR CLUSTER SYSTEMS, XI. PREPARATION, PROPERTIES, AND MOLECULAR STRUCTURES OF TITANIUM-, ZIRCONIUM-, AND HAFNIUM-SUBSTITUTED OXYMETHYLIDYNE-TRICOBALTNONCARBONYL CLUSTER COMPOUNDS

Chemischer Informationsdienst ◽

10.1002/chin.197826284 ◽

1978 ◽

Vol 9 (26) ◽

Author(s):

B. STUTTE ◽

V. BAETZEL ◽

R. BOESE ◽

G. SCHMID

Keyword(s):

Molecular Structures ◽

Cluster Compounds ◽

Cluster Systems ◽

Titanium Zirconium ◽

Heteronuclear Cluster

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Bimetallic Zwitterionic Complexes with an Ambident Stanna-closo-dodecaborate Ligand: [1-{M(CO)5}-2,7,8-(μ-H)3-{Fe(triphos)}-SnB11H11] (M = Cr, Mo, W)

Organometallics ◽

10.1021/om060328m ◽

2006 ◽

Vol 25 (16) ◽

pp. 3904-3911 ◽

Cited By ~ 23

Author(s):

Torben Gädt ◽

Klaus Eichele ◽

Lars Wesemann

Keyword(s):

Zwitterionic Complexes

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Reactions of donor-acceptor cyclopropanes or benzylidenemalonate with benzyl azide by generating gallium trichloride 1,2-zwitterionic complexes

Russian Chemical Bulletin ◽

10.1007/s11172-019-2584-2 ◽

2019 ◽

Vol 68 (8) ◽

pp. 1504-1509 ◽

Cited By ~ 1

Author(s):

I. A. Borisova ◽

A. V. Tarasova ◽

K. V. Potapov ◽

R. A. Novikov ◽

Yu. V. Tomilov

Keyword(s):

Donor Acceptor ◽

Gallium Trichloride ◽

Zwitterionic Complexes

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On the reaction of GeCl2·dioxane with KFeCp(CO)2: isolation and characterization of novel bimetallic clusters

Dalton Transactions ◽

10.1039/c9dt00097f ◽

2019 ◽

Vol 48 (12) ◽

pp. 3831-3834 ◽

Cited By ~ 2

Author(s):

Lars Preißing ◽

Claudio Schrenk ◽

Andreas Schnepf

Keyword(s):

Cluster Compounds ◽

Bimetallic Clusters ◽

Complex Reaction ◽

Reaction Route ◽

Isolation And Characterization

The reaction of GeCl2·dioxane with KFeCp(CO)2 leads to polyhedral cluster compounds with six germanium atoms like Ge6[FeCp(CO)2]6 or Ge6Cl2[FeCp(CO)2]6via a complex reaction route.

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