Carboxylato-Modified New Oxo-Centred Triruthenium Cluster Compounds with CO and Solvent Ligands: The X-ray Structure of [Ru3O(C2H5CO2)6(CO)(THF)2]

Atsushi Inatomi; Masaaki Abe; Yoshio Hisaeda

doi:10.1002/ejic.200900701

Carboxylato-Modified New Oxo-Centred Triruthenium Cluster Compounds with CO and Solvent Ligands: The X-ray Structure of [Ru3O(C2H5CO2)6(CO)(THF)2]

European Journal of Inorganic Chemistry ◽

10.1002/ejic.200900701 ◽

2009 ◽

Vol 2009 (32) ◽

pp. 4830-4836 ◽

Cited By ~ 13

Author(s):

Atsushi Inatomi ◽

Masaaki Abe ◽

Yoshio Hisaeda

Keyword(s):

Cluster Compounds ◽

X Ray

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ChemInform Abstract: SYNTHESIS AND X-RAY STRUCTURAL STUDIES ON THE RHODIUM-RUTHENIUM CLUSTER COMPOUNDS (RURH3(μ3-CO)2(CO)3(η-C5ME5)3) AND (RURH2(μ-CO)(μ3-CO)(CO)2(η4-C8H10)(η-C5ME5)2)

Chemischer Informationsdienst ◽

10.1002/chin.198532321 ◽

1985 ◽

Vol 16 (32) ◽

Author(s):

L. J. FARRUGIA ◽

J. C. JEFFERY ◽

C. MARSDEN ◽

F. G. A. STONE

Keyword(s):

Cluster Compounds ◽

Structural Studies ◽

Ruthenium Cluster ◽

X Ray

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X-ray emission and X-ray photoelectron studies of the electronic structure of the polymeric cubane cluster compounds Mo4S4Cl4, GaMo4S8, and GaMo4S4Te4

Journal of Structural Chemistry ◽

10.1007/bf02578553 ◽

1995 ◽

Vol 36 (6) ◽

pp. 948-955 ◽

Cited By ~ 1

Author(s):

G. F. Khudorozhko ◽

I. P. Asanov ◽

L. N. Mazalov ◽

É. A. Kravtsova ◽

G. K. Parygina ◽

...

Keyword(s):

Electronic Structure ◽

Cluster Compounds ◽

X Ray ◽

Cubane Cluster

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Reactions of gold–phosphine cluster compounds. Preparation and X-ray structure determination of octakis(triphenylphosphine)octa-gold bis(hexafluorophosphate)

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39790000387 ◽

1979 ◽

pp. 387-388 ◽

Cited By ~ 50

Author(s):

Frans A. Vollenbroek ◽

Wil P. Bosman ◽

Jan J. Bour ◽

Jan H. Noordik ◽

Paul T. Beurskens

Keyword(s):

Structure Determination ◽

Cluster Compounds ◽

X Ray

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Synthesis of new titanium–oxo cluster compounds: X-ray structure of the tetranuclear oxide [Ti4Cl6(µ2-O2CPh)6(µ3-O)2]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39920000846 ◽

1992 ◽

pp. 846-848 ◽

Cited By ~ 7

Author(s):

Nathaniel W. Alcock ◽

David A. Brown ◽

S. Mark Roe ◽

Malcolm G. H. Wallbridge

Keyword(s):

Cluster Compounds ◽

X Ray

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The heteronuclear cluster chemistry of the Group 1B metals. Part 6. Synthesis, structures, and dynamic behaviour of the bimetallic hexanuclear Group 1B metal cluster compounds [M2Ru4(µ3-H)2{µ-Ph2P(CH2)nPPh2}(CO)12](M = Cu or Ag, n= 1–6). X-Ray crystal structures of [Cu2Ru4(µ3-H)2{µ-Ph2P(CH2)nPPh2}(CO)12](n= 2, 3, or 5)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9880000757 ◽

1988 ◽

pp. 757-767 ◽

Cited By ~ 24

Author(s):

Scott S. D. Brown ◽

Ian D. Salter ◽

Loïc Toupet

Keyword(s):

Crystal Structures ◽

Dynamic Behaviour ◽

Metal Cluster ◽

Cluster Compounds ◽

Cluster Chemistry ◽

X Ray ◽

Heteronuclear Cluster

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X-ray attenuation coefficients of high-atomic-number, hexanuclear transition metal cluster compounds: A new paradigm for radiographic contrast agents

Academic Radiology ◽

10.1016/s1076-6332(00)80475-4 ◽

2000 ◽

Vol 7 (4) ◽

pp. 254-259 ◽

Cited By ~ 19

Author(s):

Brian F. Mullan ◽

Mark T. Madsen ◽

Louis Messerle ◽

Vladimir Kolesnichenko ◽

Jason Kruger

Keyword(s):

Transition Metal ◽

Contrast Agents ◽

Atomic Number ◽

Metal Cluster ◽

Cluster Compounds ◽

New Paradigm ◽

Attenuation Coefficients ◽

X Ray ◽

Transition Metal Cluster ◽

Radiographic Contrast

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Dynamic NMR studies on hydride and carbonyl fluxionality in triosmium-platinum cluster compounds. X-ray crystal structure of [Os3Pt(.mu.-H)3(CO)10(PCy3)]+BF4- (Cy = cyclohexyl)

Organometallics ◽

10.1021/om00094a012 ◽

1988 ◽

Vol 7 (4) ◽

pp. 859-870 ◽

Cited By ~ 14

Author(s):

Paul. Ewing ◽

Louis J. Farrugia ◽

David S. Rycroft

Keyword(s):

Crystal Structure ◽

Cluster Compounds ◽

Dynamic Nmr ◽

Nmr Studies ◽

X Ray ◽

Platinum Cluster

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Effect of the phosphine ligand cone angle on the metal frameworks of heteronuclear cluster compounds containing Cu(PR3)(R = alkyl or aryl) groups: X-ray structure analyses of [Cu2Ru4(µ3-H)2(CO)12(PR3)2](R = cyclo-C6H11or CHMe2)

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39880001106 ◽

1988 ◽

Vol 0 (16) ◽

pp. 1106-1108 ◽

Cited By ~ 8

Author(s):

Trushar Adatia ◽

Paul J. McCarthy ◽

Mary McPartlin ◽

Mine Rizza ◽

Ian D. Salter

Keyword(s):

Cone Angle ◽

Phosphine Ligand ◽

Cluster Compounds ◽

X Ray ◽

Heteronuclear Cluster

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ChemInform Abstract: Heteronuclear Cluster Chemistry of the Group 1B Metals. Part 1. Structural Similarities and Differences Among Mixed-metal Cluster Compounds Containing Copper, Silver, or Gold Atoms Ligated by Phosphines. X-Ray Crystal Structures of (C

ChemInform ◽

10.1002/chin.198709275 ◽

1987 ◽

Vol 18 (9) ◽

Author(s):

R. A. BRICE ◽

S. C. PEARSE ◽

I. D. SALTER ◽

K. HENRICK

Keyword(s):

Crystal Structures ◽

Metal Cluster ◽

Cluster Compounds ◽

Cluster Chemistry ◽

X Ray ◽

Mixed Metal ◽

Mixed Metal Cluster ◽

Similarities And Differences ◽

Heteronuclear Cluster

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η3- Allymetall-Schwefel-Cluster des Nickels, Palladiums und Platins / η3-Allyl Metal Sulfur Cluster Compounds of Nickel, Palladium, and Platinum

Zeitschrift für Naturforschung B ◽

10.1515/znb-1979-0416 ◽

1979 ◽

Vol 34 (4) ◽

pp. 609-613 ◽

Cited By ~ 11

Author(s):

Borislav Bogdanović ◽

Richard Goddard ◽

Peter Göttsch ◽

Carl Krüger ◽

Klaus Schlichte ◽

...

Keyword(s):

Molecular Structure ◽

Structural Similarity ◽

Molecular Data ◽

Cluster Compounds ◽

Sulfur Cluster ◽

Space Group ◽

X Ray ◽

Coordination Sites ◽

Cell Data ◽

Ray Methods

AbstractNovel cluster compounds of the composition [(η3-C3H5)2M2S]x, wherein M represents nickel, palladium or platinum are obtained by reaction of 2,5-disubstituted-1,6,6a-trithiopentalenes or H2S with (η3-C3H5)2M in THF solution. The molecular structure of one of these new cluster types [(η3-C3H5Ni)2S]3 has been established by X-ray methods. It is best described as being a fraction of a NiS-framework in which peripheral coordination sites are occupied by partial disordered η3-allyl groups. Molecular data (cell data: a = 19.868(4), b = 8.988(2), c = 14.501(3) Å, β = 115.30(2)°, space group C2/c, Z = 4, R = 0.106) are compared with the parent Bs-NiS lattice. Spectroscopic evidence for the structural similarity of the related Pd- and Pt-compounds is given.

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