Photochemical studies of a sulphonated derivative of 1,3-Diphenyl-2-pyrazoline

1975 ◽  
Vol 28 (9) ◽  
pp. 2083 ◽  
Author(s):  
IH Leaver ◽  
GC Ramsay ◽  
LJ Stephens

The photochemistry of the sulphonated pyrazoline fluorescent whitening agent sodium 4-(3?-phenyl-2?-pyrazolin-1?-yl)benzenesulphonate has been examined in aqueous solution, in films of poly(vinyl alcohol) and in the wool fibre. Photooxidation to give the pyrazole occurs almost quantitatively in solution, but accounts for only half of the photoproducts formed in the polymer. In the wool fibre, pyrazole formation accounts for more than half of the pyrazoline whitener destroyed during exposure to simulated sunlight.

RSC Advances ◽  
2016 ◽  
Vol 6 (9) ◽  
pp. 7653-7660 ◽  
Author(s):  
Bai Xue ◽  
Jianguo Deng ◽  
Junhua Zhang

A series of multiporous open-cell poly(vinyl formal) (PVF) foams were obtained by crosslinking poly(vinyl alcohol) (PVA) with different contents of formaldehyde in aqueous solution.


2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.


2013 ◽  
Vol 54 (9) ◽  
pp. 1969-1975 ◽  
Author(s):  
Tongsai Jamnongkan ◽  
Ryo Shirota ◽  
Sathish K. Sukumaran ◽  
Masataka Sugimoto ◽  
Kiyohito Koyama

1984 ◽  
Vol 40 (4-5) ◽  
pp. T158-T160
Author(s):  
Motoko Komatsu ◽  
Takashi Inoue ◽  
Keizo Miyasaka

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