Spin-spin coupling in copper(II) complexes of Pentane-2,4-dione

CG Barraclough; RW Brookes; RL Martin

doi:10.1071/ch9741843

Spin-spin coupling in copper(II) complexes of Pentane-2,4-dione

Australian Journal of Chemistry ◽

10.1071/ch9741843 ◽

1974 ◽

Vol 27 (9) ◽

pp. 1843 ◽

Cited By ~ 22

Author(s):

CG Barraclough ◽

RW Brookes ◽

RL Martin

Keyword(s):

Magnetic Properties ◽

Liquid Nitrogen ◽

Spin Coupling ◽

Spin Spin Coupling ◽

Binuclear Unit

A number of complexes in the series Cu(acac)(X), where X = OMe-, OEt-, OCH2Ph-, N3- and pz- (the pyrazolate anion), have been prepared and their magnetic properties determined down to liquid nitrogen temperatures. Also reported is the complex Cu2(acac)2(OH)(pz). In each case, the magnetism is interpreted in terms of spin coupling within a binuclear unit. All coupling is antiferromagnetic in nature, except for X = N3- which appears to be weakly ferromagnetic.

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Spin-Spin Coupling in Binuclear Complexes. II. The Magnetic Properties of Schiff's Base Complexes of Copper(II)

Inorganic Chemistry ◽

10.1021/ic50041a019 ◽

1966 ◽

Vol 5 (7) ◽

pp. 1161-1167 ◽

Cited By ~ 25

Author(s):

William E. Hatfield ◽

Fred L. Bunger

Keyword(s):

Magnetic Properties ◽

Spin Coupling ◽

Binuclear Complexes ◽

Schiff’S Base ◽

Spin Spin Coupling

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Spin-Spin Coupling in Binuclear Complexes. III. The Magnetic Properties of Copper Salts of Substituted Benzoic Acids

Inorganic Chemistry ◽

10.1021/ic50045a004 ◽

1966 ◽

Vol 5 (11) ◽

pp. 1855-1858 ◽

Cited By ~ 35

Author(s):

William E. Hatfield ◽

Carol S. Fountain ◽

Robin Whyman

Keyword(s):

Magnetic Properties ◽

Spin Coupling ◽

Binuclear Complexes ◽

Benzoic Acids ◽

Copper Salts ◽

Substituted Benzoic Acids ◽

Spin Spin Coupling

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N-Substituted salicylaldimine complexes of iron(III). II. Magnetic properties

Australian Journal of Chemistry ◽

10.1071/ch9681517 ◽

1968 ◽

Vol 21 (6) ◽

pp. 1517 ◽

Cited By ~ 16

Author(s):

den Bergen A van ◽

KS Murray ◽

BO West

Keyword(s):

Magnetic Properties ◽

Schiff Base ◽

Spin Coupling ◽

Coupling Mechanism ◽

Ferric Ion ◽

Binuclear Complexes ◽

Magnetic Susceptibilities ◽

Mononuclear Complexes ◽

Bulk Susceptibility ◽

Spin Spin Coupling

The magnetic susceptibilities of iron(111) N-substituted salicylaldimine complexes of types Fe(sal-XR)3, Fe(sal-NR)2X, [Fe(salH-KR)2X]X, (X = Cl, Br), and [Fe(sal-NR)2]2O have been measured over the temperature range 90-300�K.? The mononuclear complexes exhibit normal high-spin (S = 5/2), Curie-Weiss behaviour. The binuclear oxygen-bridged complexes show antiferromagnetic behaviour and the results have been analysed using the spin-spin coupling mechanism. The exchange interaction is found to be independent of the nature of the N-substituent on the Schiff base. It appears that bulk susceptibility measurements alone cannot unambiguously specify the formal spin state of the ferric ion in these binuclear complexes.

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Vibrational and thermal averaging of the indirect nuclear spin-spin coupling constants of CH4, SiH4, GeH4 and SnH4

Molecular Physics ◽

10.1080/00268979709482780 ◽

1997 ◽

Vol 91 (5) ◽

pp. 897-907 ◽

Cited By ~ 5

Author(s):

SHEELA KIRPEKAR ◽

THOMAS ENEVOLDSEN ◽

JENS ODDERSHEDE ◽

WILLIAM RAYNES

Keyword(s):

Nuclear Spin ◽

Coupling Constants ◽

Spin Coupling ◽

Spin Coupling Constants ◽

Spin Spin Coupling

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Recent advances in computational 31 P NMR: Part 2. Spin-spin coupling constants

Magnetic Resonance in Chemistry ◽

10.1002/mrc.4973 ◽

2019 ◽

Vol 58 (6) ◽

pp. 500-511

Author(s):

Leonid B. Krivdin

Keyword(s):

Coupling Constants ◽

Spin Coupling ◽

Recent Advances ◽

Spin Coupling Constants ◽

Spin Spin Coupling

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Anisotropies in spin—spin coupling constants and chemical shifts as determined from the NMR spectra of molecules oriented by liquid crystal solvents

Progress in Nuclear Magnetic Resonance Spectroscopy ◽

10.1016/0079-6565(82)80004-6 ◽

1982 ◽

Vol 15 (3) ◽

pp. 249-290 ◽

Cited By ~ 93

Author(s):

J. Lounila ◽

J. Jokisaari

Keyword(s):

Liquid Crystal ◽

Nmr Spectra ◽

Chemical Shifts ◽

Coupling Constants ◽

Spin Coupling ◽

Spin Coupling Constants ◽

Spin Spin Coupling

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Basis set dependence of 1H–X spin–spin coupling constants in non-empirical pure DFT framework, X = 1H, 13C, 19F, 35Cl: Case of CHCl=CH–CF3 stereoisomers

AIP Advances ◽

10.1063/5.0043005 ◽

2021 ◽

Vol 11 (3) ◽

pp. 035113

Author(s):

Olivier Holtomo ◽

Mama Nsangou ◽

Ousmanou Motapon

Keyword(s):

Coupling Constants ◽

Spin Coupling ◽

Basis Set ◽

Spin Coupling Constants ◽

Spin Spin Coupling

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Structural Characterization of Natural Products By Means of Quantum Chemical Calculations of NMR Parameters: New insights

Organic Chemistry Frontiers ◽

10.1039/d1qo00034a ◽

2021 ◽

Author(s):

Fabio Luiz Paranhos Costa ◽

Ana Carolina Ferreira de Albuquerque ◽

Rodolfo Goetze Fiorot ◽

Luciano Morais Lião ◽

Lucas Haidar Martorano ◽

...

Keyword(s):

Natural Products ◽

Structural Characterization ◽

Quantum Chemical ◽

Chemical Shifts ◽

Coupling Constants ◽

Spin Coupling ◽

Nmr Parameters ◽

Spin Coupling Constants ◽

Spin Spin Coupling

The calculation of NMR parameters for natural products was pioneered by Bifulco and coworkers in 2002. Since then, modelling 1H and 13C chemical shifts and spin-spin coupling constants for this...

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