Spin-Spin Coupling in Binuclear Complexes. II. The Magnetic Properties of Schiff's Base Complexes of Copper(II)

1966 ◽  
Vol 5 (7) ◽  
pp. 1161-1167 ◽  
Author(s):  
William E. Hatfield ◽  
Fred L. Bunger
Keyword(s):  
Magnetic Properties ◽  
Spin Coupling ◽  
Binuclear Complexes ◽  
Schiff’S Base ◽  
Spin Spin Coupling

N-Substituted salicylaldimine complexes of iron(III). II. Magnetic properties

1968 ◽  
Vol 21 (6) ◽  
pp. 1517 ◽  
Author(s):  
den Bergen A van ◽  
KS Murray ◽  
BO West
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Spin Coupling ◽  
Coupling Mechanism ◽  
Ferric Ion ◽  
Binuclear Complexes ◽  
Magnetic Susceptibilities ◽  
Mononuclear Complexes ◽  
Bulk Susceptibility ◽  
Spin Spin Coupling

The magnetic susceptibilities of iron(111) N-substituted salicylaldimine complexes of types Fe(sal-XR)3, Fe(sal-NR)2X, [Fe(salH-KR)2X]X, (X = Cl, Br), and [Fe(sal-NR)2]2O have been measured over the temperature range 90-300�K.? The mononuclear complexes exhibit normal high-spin (S = 5/2), Curie-Weiss behaviour. The binuclear oxygen-bridged complexes show antiferromagnetic behaviour and the results have been analysed using the spin-spin coupling mechanism. The exchange interaction is found to be independent of the nature of the N-substituent on the Schiff base. It appears that bulk susceptibility measurements alone cannot unambiguously specify the formal spin state of the ferric ion in these binuclear complexes.

Binuclear and mononuclear nickel(II) and zinc(II) complexes of the tetradentate ligand 1,4-di(2′-pyridyl)aminophthalazine

1980 ◽  
Vol 58 (3) ◽  
pp. 221-228 ◽  
Author(s):  
James Alfred Doull ◽  
Laurence Kenneth Thompson
Keyword(s):  
Nickel Complexes ◽  
Zinc Complexes ◽  
Spin Coupling ◽  
Binuclear Complexes ◽  
Antiferromagnetic Exchange ◽  
Tetradentate Ligand ◽  
Metal Ratio ◽  
Spin Spin Coupling ◽  
Hydroxy Groups

Previous studies with the title ligand, PAP, have shown a predominance of binuclear complexes with cobalt and copper in which the ligand-to-metal ratio is 1:2. The nickel complexes produced are more varied in composition; e.g., 1:2 binuclear systems [PAPNi2X(OH)(H2O)4]X2 (X = Cl, Br); 1:1 binuclear systems [PAP2Ni2(H2O)4]X4 (X = Cl, Br), [PAP2Ni2(NCS)3]NCS, [PAP2Ni2(OH)I2]I•2H2O, [PAP2Ni2(OH)(H2O)2]X3 (X = ClO4, BF4, I); and 2:1 mononuclear systems [(PAPH)2Ni(H2O)2]X4 (X = I, BF4). Zinc forms both mononuclear, [PAPZnX2]•H2O (X = Br, I), and a 1:1 binuclear system, [PAP2Zn2Cl4]. Triple bridges are suggested between the nickel atoms in all binuclear systems involving bridging hydroxy groups. Weak antiferromagnetic exchange is observed (−J < 10 cm−1) in two binuclear nickel complexes, which is enhanced in the presence of a hydroxy bridge. Spin–spin coupling is assumed to occur via a superexchange mechanism. In all cases nickel appears to be six-coordinate while for the zinc complexes both four- and six-coordination are observed.

57Fe-15N Spin-Spin Coupling at Natural Abundance of the Isotopes in Binuclear Complexes Fe2(CO)6(μ-RNS) Containing a Sulfimide Bridge

1991 ◽  
Vol 46 (12) ◽  
pp. 1679-1683 ◽  
Author(s):  
Bernd Wrackmeyer ◽  
Ēriks Kupče ◽  
Berthold Distler ◽  
Klaus Dirnberger ◽  
Max Herberhold
Keyword(s):  
Magnetic Resonance ◽  
Polarization Transfer ◽  
Natural Abundance ◽  
Spin Coupling ◽  
Binuclear Complexes ◽  
Spin Spin Coupling ◽  
First Time ◽  
Multinuclear Magnetic Resonance

Complexes of the type Fe2(CO)6(μ-RNS) [R = H (la), tBu (lb), SiMe3 (lc), Si'BuMe2 (1d), SnMe3 (le)] have been studied by multinuclear magnetic resonance (1H13C, 14C, 14N, 15N, 17O, 29Si, 119Sn) with emphasis on natural abundance 15N NMR measurements. By application of various polarization transfer techniques 1J(57Fe15N) (6.1 Hz) in la has been determined for the first time, together with the isotope-induced shift 1Δ34/32S (-36 ppb). Compound ld has been prepared via the reaction between Me2tBuSiCl and Fe2(CO)6(μ-NaNS) (lf), available from la and sodium.

Spin-spin coupling in copper(II) complexes of Pentane-2,4-dione

1974 ◽  
Vol 27 (9) ◽  
pp. 1843 ◽  
Author(s):  
CG Barraclough ◽  
RW Brookes ◽  
RL Martin
Keyword(s):  
Magnetic Properties ◽  
Liquid Nitrogen ◽  
Spin Coupling ◽  
Spin Spin Coupling ◽  
Binuclear Unit

A number of complexes in the series Cu(acac)(X), where X = OMe-, OEt-, OCH2Ph-, N3- and pz- (the pyrazolate anion), have been prepared and their magnetic properties determined down to liquid nitrogen temperatures. Also reported is the complex Cu2(acac)2(OH)(pz). In each case, the magnetism is interpreted in terms of spin coupling within a binuclear unit. All coupling is antiferromagnetic in nature, except for X = N3- which appears to be weakly ferromagnetic.

Spin-Spin Coupling in Binuclear Complexes

1964 ◽  
Vol 86 (18) ◽  
pp. 3888-3889 ◽  
Author(s):  
William E. Hatfield ◽  
John S. Paschal
Keyword(s):  
Spin Coupling ◽  
Binuclear Complexes ◽  
Spin Spin Coupling
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