scholarly journals Activation of saturated hydrocarbons by homogeneous metal catalysts : Deuterium exchange in iridium(III) solution

1974 ◽  
Vol 27 (8) ◽  
pp. 1823 ◽  
Author(s):  
JL Garnett ◽  
MA Long ◽  
KB Peterson
Keyword(s):  
Hydrogen Exchange ◽  
Metal Catalysts ◽  
Deuterium Exchange ◽  
Saturated Hydrocarbons ◽  
Isotopic Hydrogen

Isotopic hydrogen exchange between simple alkanes and D2O is homogeneously catalysed by sodium chloroiridite at 160�C. Initial isotope orientation favours hydrogen on the primary carbon atoms.High M values for the exchange are typical.

Catalytic deuterium exchange reactions with organics. XIII. Characteristic reactions of the Group VIII transition metals

1965 ◽  
Vol 18 (7) ◽  
pp. 1003 ◽  
Author(s):  
JL Garnett ◽  
WA Sollich
Keyword(s):  
Transition Metal ◽  
Hydrogen Exchange ◽  
Deuterium Oxide ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Group Viii ◽  
Exchange Reactions ◽  
Substitution Mechanism ◽  
Π Complex ◽  
Complex Adsorption

Activation procedures and hydrogen exchange reactions with six Group VIII transition metal catalysts (Pt, Pd, Ru, Rh, Ir, Ni) are reported for three characteristic reaction systems: (i) deuterium oxide/benzene, (ii) deuterium oxide/naphthalene, and (iii) deuterium oxide/n-octane. Results of these exchange reactions indicate that both π-complex adsorption and the dissociative π-complex substitution mechanism previously established for platinum are applicable to other Group VIII transition metal catalysts. For general catalytic labelling with isotopic hydrogen, platinum was found to be the most efficient of the catalysts investigated.

Isotopic hydrogen exchange in ?-ylide of group VIB metal complexes

1976 ◽  
Vol 25 (8) ◽  
pp. 1664-1666
Author(s):  
V. N. Setkina ◽  
A. Zh. Zhakaeva ◽  
V. I. Zdanovich ◽  
D. N. Kursanov
Keyword(s):  
Metal Complexes ◽  
Hydrogen Exchange ◽  
Isotopic Hydrogen

Isotopic hydrogen exchange in ?-bonded ligand of ?-C6H5CH2MO(CO)3C5H5-? and ?-C6H5CH2W(CO)3C5H5-? complexes

1973 ◽  
Vol 22 (7) ◽  
pp. 1602-1604
Author(s):  
T. Yu. Orlova ◽  
S. S. Churanov ◽  
L. A. Fedorov ◽  
V. N. Setkina ◽  
D. N. Kursanov
Keyword(s):  
Hydrogen Exchange ◽  
Isotopic Hydrogen

Isotopic hydrogen exchange in bisarenechromium complexes

1972 ◽  
Vol 37 (2) ◽  
pp. C35-C36 ◽  
Author(s):  
D.N. Kursanov ◽  
V.N. Setkina ◽  
B.G. Gribov
Keyword(s):  
Hydrogen Exchange ◽  
Isotopic Hydrogen
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