Vapour phase composition and activities for the molten PbCl2 + NaCl system

1972 ◽  
Vol 25 (10) ◽  
pp. 2077 ◽  
Author(s):  
H Bloom ◽  
SR Richards ◽  
DJ Williams

Vapour pressures of molten PbCl2 + NaCl mixtures have been measured a.t 1071 K by a transpiration method. The vapours have also been investigated by mass spectrometry and the complex NaPbCl3 has been established. The enthalpy of formation of this complex from NaCl(g) and PbCl2(g) has been determined and the equilibrium constant for its formation has been estimated. Enthalpies of vaporization of NaCl and PbC12 and the enthalpy of dimerization of NaCl(g) agree with published results. The mass spectrometry results have enabled corrections to be made to measured activities of PbCl2 from the transpiration results, for errors due to the NaPbCl3 complexes. The activity values so determined are compared with those for other molten binary systems involving lead and alkali chlorides. The PbCl2 + NaCl system (like the other PbCl2 + alkali chloride systems except PbCl2 + LiCl) does not behave as regular solutions.

1968 ◽  
Vol 21 (3) ◽  
pp. 583 ◽  
Author(s):  
H Bloom ◽  
JW Hastie

Vapour pressures above molten PbBr2+KBr mixtures have been measured over a range of temperatures by a transpiration method. The vapours have been investigated also by mass spectrometry and the presence of the complex KPbBr3 has been established. The enthalpy and entropy of formation of this compound from PbBr2(g) and KBr(g) are similar to values obtained for the analogous chloride species. By combining the results of both methods, the true activities of lead bromide in the melt have been calculated as a function of composition, and the results have been interpreted to show that PbBr3 is the major complex ion present in the molten mixtures.


1979 ◽  
Vol 44 (4) ◽  
pp. 1187-1196 ◽  
Author(s):  
Ivona Malijevská

The relations were obtained between the thermodynamically consistent activity coefficient of associating component and the activity coefficient calculated irrespective of the association in the vapour phase. The analysis is limited to binary systems with one associating component and is given for the two cases: (a) the associating component dimerizes only, (b) the associating component forms, in addition to a dimer, one higher associate, too.


Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2335
Author(s):  
Gabriella Pinto ◽  
Sabrina De Pascale ◽  
Maria Aponte ◽  
Andrea Scaloni ◽  
Francesco Addeo ◽  
...  

Plant polyphenols have beneficial antioxidant effects on human health; practices aimed at preserving their content in foods and/or reusing food by-products are encouraged. The impact of the traditional practice of the water curing procedure of chestnuts, which prevents insect/mould damage during storage, was studied to assess the release of polyphenols from the fruit. Metabolites extracted from pericarp and integument tissues or released in the medium from the water curing process were analyzed by matrix-assisted laser desorption ionization-time of flight-mass spectrometry (MALDI-TOF-MS) and electrospray-quadrupole-time of flight-mass spectrometry (ESI-qTOF-MS). This identified: (i) condensed and hydrolyzable tannins made of (epi)catechin (procyanidins) and acid ellagic units in pericarp tissues; (ii) polyphenols made of gallocatechin and catechin units condensed with gallate (prodelphinidins) in integument counterparts; (iii) metabolites resembling those reported above in the wastewater from the chestnut curing process. Comparative experiments were also performed on aqueous media recovered from fruits treated with processes involving: (i) tap water; (ii) tap water containing an antifungal Lb. pentosus strain; (iii) wastewater from a previous curing treatment. These analyses indicated that the former treatment determines a 6–7-fold higher release of polyphenols in the curing water with respect to the other ones. This event has a negative impact on the luster of treated fruits but qualifies the corresponding wastes as a source of antioxidants. Such a phenomenon does not occur in wastewater from the other curing processes, where the release of polyphenols was reduced, thus preserving the chestnut’s appearance. Polyphenol profiling measurements demonstrated that bacterial presence in water hampered the release of pericarp metabolites. This study provides a rationale to traditional processing practices on fruit appearance and qualifies the corresponding wastes as a source of bioactive compounds for other nutraceutical applications.


Author(s):  
Xing Wang ◽  
Henk G. Jansen ◽  
Haico Duin ◽  
Harro A. J. Meijer

AbstractThere are two officially approved methods for stable isotope analysis for wine authentication. One describes δ18O measurements of the wine water using Isotope Ratio Mass Spectrometry (IRMS), and the other one uses Deuterium-Nuclear Magnetic Resonance (2H-NMR) to measure the deuterium of the wine ethanol. Recently, off-axis integrated cavity output (laser) spectroscopy (OA-ICOS) has become an easier alternative to quantify wine water isotopes, thanks to the spectral contaminant identifier (SCI). We utilized an OA-ICOS analyser with SCI to measure the δ18O and δ2H of water in 27 wine samples without any pre-treatment. The OA-ICOS results reveal a wealth of information about the growth conditions of the wines, which shows the advantages to extend the official δ18O wine water method by δ2H that is obtained easily from OA-ICOS. We also performed high-temperature pyrolysis and chromium reduction combined with IRMS measurements to illustrate the “whole wine” isotope ratios. The δ18O results of OA-ICOS and IRMS show non-significant differences, but the δ2H results of both methods differ much more. As the δ2H difference between these two methods is mainly caused by ethanol, we investigated the possibility to deduce deuterium of wine ethanol from this difference. The results present large uncertainties and deviate from the obtained 2H-NMR results. The deviation is caused by the other constituents in the wine, and the uncertainty is due to the limited precision of the SCI-based correction, which need to improve to obtain the 2H values of ethanol as alternative for the 2H-NMR method.


2000 ◽  
Vol 6 (1) ◽  
pp. 53-64 ◽  
Author(s):  
V.V. Takhistov ◽  
I.N. Domnin ◽  
D.A. Ponomarev

Ionization and appearance energies of some fragment ions from 1,2,3-trimethy1-3-phenyl-, 3-methyl-1,2,3-triphenyl-, 1,2-diphenyl-3-methoxycarbonyl-, 1,2,3-triphenyl-3-methoxycarbonyl- and 1,3,3-triphenyl-2-methoxycarbonyl-cyclopropenes were measured by photoionization mass spectrometry. It was shown that in none of these compounds did the fragment ions possess the expected stable substituted cyclopropenium ion structure. Accordingly, possible schemes of molecular ion isomerization are given. The enthalpies of formation of nearly 50 substituted cyclopropenium ions, and ions of related structure, were estimated using series of isodesmic reactions. This publication, together with the previous works of the authors in this Journal, demonstrates the general methodology for estimation of the enthalpy of formation for even-electron ions. It is suggested that the present methodology can provide a good alternative to other estimation or computation procedures applied to the thermochemistry of ions.


2021 ◽  
Vol 21 (7) ◽  
pp. 4081-4084
Author(s):  
Seul-Bee Lee ◽  
Young-Min Kim ◽  
Ji-Hui Park ◽  
Young-Kwon Park

This study examined the thermal and catalytic pyrolysis of waste Achyranthes Root (AR) using pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). The non-catalytic pyrolysis of waste AR produced various kinds of oxygenates, such as acetic acid, hydroxy propanone, furfural, phenol, cresol, guaiacols, syringols, and so on. By applying nanoporous Al-MCM-41 with acidic properties and mesopores to the pyrolysis of waste AR, the levels of furan and aromatic hydrocarbons production increased with a concomitant decrease in the other oxygenates. The formation efficiency of furans was improved further by increasing the amount of Al-MCM-41 applied to the catalytic pyrolysis of waste AR.


2018 ◽  
Vol 11 (9) ◽  
pp. 770-780 ◽  
Author(s):  
Guang Liu ◽  
Limei Wang ◽  
Junmin Pan

Abstract The motility of cilia or eukaryotic flagella is powered by the axonemal dyneins, which are preassembled in the cytoplasm by proteins termed dynein arm assembly factors (DNAAFs) before being transported to and assembled on the ciliary axoneme. Here, we characterize the function of WDR92 in Chlamydomonas. Loss of WDR92, a cytoplasmic protein, in a mutant wdr92 generated by DNA insertional mutagenesis resulted in aflagellate cells or cells with stumpy or short flagella, disappearance of axonemal dynein arms, and diminishment of dynein arm heavy chains in the cytoplasm, suggesting that WDR92 is a DNAAF. Immunoprecipitation of WDR92 followed by mass spectrometry identified inner dynein arm heavy chains and multiple DNAAFs including RuvBL1, RPAP3, MOT48, ODA7, and DYX1C. The PIH1 domain-containing protein MOT48 formed a R2TP-like complex with RuvBL1/2 and RPAP3, while PF13, another PIH1 domain-containing protein with function in dynein preassembly, did not. Interestingly, the third PIH1 domain-containing protein TWI1 was not related to flagellar motility. WDR92 physically interacted with the R2TP-like complex and the other identified DNNAFs. Our data suggest that WDR92 functions in association with the HSP90 co-chaperone R2TP-like complex as well as linking other DNAAFs in dynein preassembly.


2018 ◽  
Vol 615 ◽  
pp. A62 ◽  
Author(s):  
G. Valle ◽  
M. Dell’Omodarme ◽  
P. G. Prada Moroni ◽  
S. Degl’Innocenti

Aims. The capability of grid-based techniques to estimate the age together with the convective core overshooting efficiency of stars in detached eclipsing binary systems for main sequence stars has previously been investigated. We have extended this investigation to later evolutionary stages and have evaluated the bias and variability on the recovered age and convective core overshooting parameter accounting for both observational and internal uncertainties. Methods. We considered synthetic binary systems, whose age and overshooting efficiency should be recovered by applying the SCEPtER pipeline to the same grid of models used to build the mock stars. We focus our attention on a binary system composed of a 2.50 M⊙ primary star coupled with a 2.38 M⊙ secondary. To explore different evolutionary scenarios, we performed the estimation at three different times: when the primary is at the end of the central helium burning, when it is at the bottom of the RGB, and when it is in the helium core burning phase. The Monte Carlo simulations have been carried out for two typical values of accuracy on the mass determination, that is, 1% and 0.1%. Results. Adopting typical observational uncertainties, we found that the recovered age and overshooting efficiency are biased towards low values in all three scenarios. For an uncertainty on the masses of 1%, the underestimation is particularly relevant for a primary in the central helium burning stage, reaching − 8.5% in age and − 0.04 (− 25% relative error) in the overshooting parameter β. In the other scenarios, an undervaluation of the age by about 4% occurs. A large variability in the fitted values between Monte Carlo simulations was found: for an individual system calibration, the value of the overshooting parameter can vary from β = 0.0 to β = 0.26. When adopting a 0.1% error on the masses, the biases remain nearly unchanged but the global variability is suppressed by a factor of about two. We also explored the effect of a systematic discrepancy between the artificial systems and the model grid by accounting for an offset in the effective temperature of the stars by ± 150 K. For a mass error of 1% the overshooting parameter is largely biased towards the edges of the explored range, while for the lower mass uncertainty it is basically unconstrained from 0.0 to 0.2. We also evaluate the possibility of individually recovering the β value for both binary stars. We found that this is impossible for a primary near to central hydrogen exhaustion owing to huge biases for the primary star of + 0.14 (90% relative error), while in the other cases the fitted β are consistent, but always biased by about − 0.04 (− 25% relative error). Finally, the possibility to distinguish between models computed with mild overshooting from models with no overshooting was evaluated, resulting in a reassuring power of distinction greater than 80%. However, the scenario with a primary in the central helium burning was a notable exception, showing a power of distinction lower than 5%.


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