scholarly journals Aluminium chloride catalysed reaction of phosphorus(III) halides and carbonyl compounds. II. Scope of the reaction

1968 ◽  
Vol 21 (9) ◽  
pp. 2297 ◽  
Author(s):  
KL Freeman ◽  
MJ Gallagher
Keyword(s):  
Carbonyl Compounds ◽  
Aluminium Chloride ◽  
Catalysed Reaction

No abstract available.

The aluminium chloride catalysed reaction of phosphorus(III) halides and carbonyl compounds. I. Reaction with benzophenone

1966 ◽  
Vol 19 (11) ◽  
pp. 2025 ◽  
Author(s):  
KL Freeman ◽  
MJ Gallagher
Keyword(s):  
Carbonyl Compounds ◽  
Phosphorus Trichloride ◽  
Aluminium Chloride ◽  
Factors Affecting ◽  
Anhydrous Aluminium Chloride ◽  
Catalysed Reaction ◽  
Hydrated Aluminium

In the presence of partially hydrated aluminium chloride, phenylphosphonous dichloride and diphenylphosphinous chloride add smoothly to benzophenone to give chlorodiphenylmethylphenylphosphinic chloride and benzhydryldiphenylphosphine oxide respectively. Little reaction occurs with anhydrous aluminium chloride, and phosphorus trichloride does not react under any conditions. The factors affecting these reactions are described and possible mechanisms discussed. It is suggested that the intermediacy of species of the type [PhPCl3]+[PhPCl,AlCl3]- best explains the observed results.

The mechanism of 1,3-dioxolane formation from the BF3 -catalysed reaction of epoxides with carbonyl compounds

Tetrahedron ◽  
1970 ◽  
Vol 26 (6) ◽  
pp. 1311-1313 ◽  
Author(s):  
B.N. Blackett ◽  
J.M. Coxon ◽  
M.P. Hartshorn ◽  
A.J. Lewis ◽  
G.R. Little ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Catalysed Reaction

The BF3-Catalysed Reaction between 2-Methylfuran and Some a,b-Unsaturated Carbonyl Compounds.

Heterocycles ◽  
1981 ◽  
Vol 15 (2) ◽  
pp. 1079 ◽  
Author(s):  
John W. ApSimon ◽  
V. Seenu Srinivasan ◽  
M. R. L’Abbé ◽  
R. Seguin
Keyword(s):  
Carbonyl Compounds ◽  
Catalysed Reaction
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