The Reaction of Alkali Metal Derivatives of Group IV Metal Alkyls with Bis(cyclopentadienyl)titanium(IV) Dichloride

1961 ◽  
Vol 14 (4) ◽  
pp. 555 ◽  
Author(s):  
RS Dickson ◽  
BO West

The reactions of bis(cyclopentadienyl)titanium(IV) dichloride with sodium lead triethyl and with lithium tin triethyl have been investigated. Unstable solid products are formed. The reaction of liquid ammonia with bis(cyclopentadienyl)titanium(IV) dichloride has also been studied.

1972 ◽  
Vol 38 (1) ◽  
pp. 121-124 ◽  
Author(s):  
R.B. King ◽  
A. Efraty ◽  
W.C. Zipperer

1981 ◽  
Vol 34 (6) ◽  
pp. 1337 ◽  
Author(s):  
WR Bullard ◽  
MJ Taylor

Ionic compounds R+SnPh3-, where R = Me4N, (Ph3P)2N, Na(15-crown-5) or K(18-crown-6), are prepared from alkali metal derivatives, Ph3SnM, by reactions in liquid ammonia which yield the products as yellow crystalline solids, soluble in a weakly basic solvent. N.m.r. and vibrational spectra of the Ph3Sn- anion, a pyramidal species with C3V symmetry, and the cationic complexes [M(crown)]+, are reported and assigned.


2008 ◽  
Vol 112 (33) ◽  
pp. 7682-7688 ◽  
Author(s):  
Fernando Blanco ◽  
Ibon Alkorta ◽  
Jose Elguero

2014 ◽  
Vol 43 (11) ◽  
pp. 4351-4360 ◽  
Author(s):  
Sarah Robinson ◽  
E. Stephen Davies ◽  
William Lewis ◽  
Alexander J. Blake ◽  
Stephen T. Liddle

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