scholarly journals Liquid Structures and Transport Properties of Lithium Bis(fluorosulfonyl)amide/Glyme Solvate Ionic Liquids for Lithium Batteries

2019 ◽  
Vol 72 (2) ◽  
pp. 70 ◽  
Author(s):  
Shoshi Terada ◽  
Kohei Ikeda ◽  
Kazuhide Ueno ◽  
Kaoru Dokko ◽  
Masayoshi Watanabe
Keyword(s):  
Ionic Liquids ◽  
Transport Properties ◽  
Lithium Batteries ◽  
Diffusion Coefficients ◽  
The Self ◽  
Metal Anode ◽  
Self Diffusion ◽  
Molar Ratios ◽  
Li Metal Anode ◽  
A Current

The liquid structures and transport properties of electrolytes composed of lithium bis(fluorosulfonyl)amide (Li[FSA]) and glyme (triglyme (G3) or tetraglyme (G4)) were investigated. Raman spectroscopy indicated that the 1:1 mixtures of Li[FSA] and glyme (G3 or G4) are solvate ionic liquids (SILs) comprising a cationic [Li(glyme)]+ complex and the [FSA]− anion. In Li[FSA]-excess liquids with Li[FSA]/glyme molar ratios greater than 1, anionic Lix[FSA]y(y–x)– complexes were formed in addition to the cationic [Li(glyme)]+ complex. Pulsed field gradient NMR measurements revealed that the self-diffusion coefficients of Li+ (DLi) and glyme (Dglyme) are identical in the Li[FSA]/glyme=1 liquid, suggesting that Li+ and glyme diffuse together and that a long-lived cationic [Li(glyme)]+ complex is formed in the SIL. The ratio of the self-diffusion coefficients of [FSA]− and Li+, DFSA/DLi, was essentially constant at ~1.1–1.3 in the Li[FSA]/glyme<1 liquid. However, DFSA/DLi increased rapidly as the amount of Li[FSA] increased in the Li[FSA]/glyme>1 liquid, indicating that the ion transport mechanism in the electrolyte changed at the composition of Li[FSA]/glyme=1. The oxidative stability of the electrolytes was enhanced as the Li[FSA] concentration increased. Furthermore, Al corrosion was suppressed in the electrolytes for which Li[FSA]/glyme>1. A battery consisting of a Li metal anode, a LiNi1/3Mn1/3Co1/3O2 cathode, and Li[FSA]/G3=2 electrolyte exhibited a discharge capacity of 105mAhg−1 at a current density of 1.3mAcm−2, regardless of its low ionic conductivity of 0.2mScm−1.

Solvate Ionic Liquids and Their Application to Lithium Batteries: Glyme-Lithium Bis(fluorosulfonyl)amide Equimolar Complexes

2012 ◽  
Vol 1473 ◽  
Author(s):  
Kazuki Yoshida ◽  
Mizuho Tsuchiya ◽  
Naoki Tachikawa ◽  
Kaoru Dokko ◽  
Masayoshi Watanabe
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Lithium Batteries ◽  
Diffusion Coefficients ◽  
Room Temperature ◽  
Spin Echo ◽  
The Self ◽  
Resonance Spectroscopy ◽  
Lithium Secondary Battery ◽  
Self Diffusion ◽  
Secondary Battery

ABSTRACTThe physicochemical properties of glyme-Li[FSA] (FSA: bis(fluorosulfonyl)amide) equimolar complexes were investigated. The self-diffusion coefficients of glymes and Li+ as determined by pulsed-field gradient spin-echo nuclear magnetic resonance spectroscopy in equimolar complexes were almost identical, suggesting that all of the glyme molecules coordinated with Li+. Electrochemical characterization revealed that the oxidative stability of glyme molecules was enhanced by complexing with Li+. Using [Li(glyme)1][FSA] electrolytes and a LiFePO4cathode, a lithium secondary battery could be stably operated for more than 100 cycles at room temperature.

scholarly journals Self-Diffusion Coefficients, Aggregation Numbers and the Range of Existence of Spherical Micelles of Oxyethylated Alkylphenols

2021 ◽  
Author(s):  
Victor P. Arkhipov ◽  
Natalia A. Kuzina ◽  
Andrei Filippov
Keyword(s):  
Aqueous Solutions ◽  
Diffusion Coefficients ◽  
The Self ◽  
Self Diffusion ◽  
Aggregation Numbers ◽  
Temperature Ranges ◽  
Spherical Micelles ◽  
Limiting Values

AbstractAggregation numbers were calculated based on measurements of the self-diffusion coefficients, the effective hydrodynamic radii of micelles and aggregates of oxyethylated alkylphenols in aqueous solutions. On the assumption that the radii of spherical micelles are equal to the lengths of fully extended neonol molecules, the limiting values of aggregation numbers corresponding to spherically shaped neonol micelles were calculated. The concentration and temperature ranges under which spherical micelles of neonols are formed were determined.

Kinetically Stable Anode Interface for Li3YCl6-Based All-Solid-State Lithium Batteries

2021 ◽  
Author(s):  
Weixiao Ji ◽  
Dong Zheng ◽  
Xiaoxiao Zhang ◽  
Tianyao Ding ◽  
Deyang Qu
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Oxidative Stability ◽  
Lithium Batteries ◽  
Solid Electrolytes ◽  
Metal Anode ◽  
Li Metal Anode

Despite excellent ionic conductivity and electrochemical oxidative stability, the emerging halide-based solid electrolytes suffer from inherent instability toward Li metal anode. A thick and resistive interface can be formed by...

Concentration dependence of the self-diffusion coefficients of water in electrolyte solutions

1974 ◽  
Vol 14 (6) ◽  
pp. 915-918
Author(s):  
A. M. Sazonov ◽  
V. M. Olevskii ◽  
A. B. Porai-Koshits ◽  
V. N. Skobolev ◽  
G. A. Shmuilovich
Keyword(s):  
Concentration Dependence ◽  
Diffusion Coefficients ◽  
Electrolyte Solutions ◽  
The Self ◽  
Self Diffusion

scholarly journals Investigation of the Self-Diffusion Coefficients of Trivalent Gd3+ in aqueous solutions: The Effect of Hydrolysis and nitrate ion association

2012 ◽  
Vol 1 (6) ◽  
pp. 334-346 ◽  
Author(s):  
Rafik Besbes ◽  
Noureddine Ouerfelli ◽  
Manef Abderabba ◽  
Patric Lindqvist-Reis ◽  
Habib Latrous
Keyword(s):  
Aqueous Solutions ◽  
Diffusion Coefficients ◽  
Ion Association ◽  
The Self ◽  
Nitrate Ion ◽  
Self Diffusion

Self-Diffusion of Sodium, Chloride and Iodide Ions in Methanol-Water Mixture

1986 ◽  
Vol 41 (7) ◽  
pp. 939-943 ◽  
Author(s):  
E. Hawlicka
Keyword(s):  
Sodium Chloride ◽  
Diffusion Coefficients ◽  
Solvent Composition ◽  
The Self ◽  
Water Mixture ◽  
Preferential Hydration ◽  
Water Solutions ◽  
Iodide Ions ◽  
Self Diffusion

The self-diffusion coefficients of Na+, Cl- and I- in methanol-water solutions at 35 ± 0.01 °C have been measured in their dependence on the salt molarity in the range 1 · 10-4- 1 · 10-2 mol dm -3. The ionic self-diffusion coefficients in infinitely diluted solutions have been computed. The influence of the solvent composition on the solvation of the ions is discussed. A preferential hydration of Na+, Cl- and I- ions in water-methanol mixtures has been found.

c , T-Dependence of the Self Diffusion in Concentrated Aqueous Sucrose Solutions

1994 ◽  
Vol 49 (3-4) ◽  
pp. 258-264 ◽  
Author(s):  
D. Girlich ◽  
H.-D. Lüdemann ◽  
C. Buttersack ◽  
K. Buchholz
Keyword(s):  
Field Gradient ◽  
Concentration Dependence ◽  
Diffusion Coefficients ◽  
The Self ◽  
Water Molecules ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Self Diffusion ◽  
Sucrose Solutions ◽  
Wide Range

The self diffusion coefficients D of the water molecules and of sucrose have been determined by the pulsed field gradient NMR technique over a wide range of temperatures and concentrations (cmax: 70% w/w suc.). All temperature dependencies can be fitted to a Vogel- Tammann-Fulcher equation. The isothermic concentration dependence of D for the sucrose is given by a simple exponential concentration dependence

Self-Diffusion in Molten Lithium Nitrate

1992 ◽  
Vol 47 (10) ◽  
pp. 1047-1050 ◽  
Author(s):  
C. Herdlicka ◽  
J. Richter ◽  
M. D. Zeidler
Keyword(s):  
Diffusion Coefficient ◽  
Diffusion Coefficients ◽  
Spin Echo ◽  
The Self ◽  
Lithium Nitrate ◽  
Equimolar Ratio ◽  
Self Diffusion ◽  
Field Gradients ◽  
Molten Lithium ◽  
Self Diffusion Coefficient

AbstractSelf-diffusion coefficients of 7Li+ ions have been measured in molten LiNO3 with several compositions of 6Li+ and 7Li+ over a temperature range from 537 to 615 K. The NMR spin-echo method with pulsed field gradients was applied. It was found that the self-diffusion coefficient depends on the isotopic composition and shows a maximum at equimolar ratio. At temperatures above 600 K this behaviour disappears.

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