pH-Controlled Supramolecular Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate with Capped ?-Cyclodextrins

2008 ◽  
Vol 61 (8) ◽  
pp. 565 ◽  
Author(s):  
Cheng Yang ◽  
Chenfeng Ke ◽  
Fujita Kahee ◽  
De-Qi Yuan ◽  
Tadashi Mori ◽  
...  

γ-Cyclodextrins capped with p-cresolbisbenzimidazole at the primary rim were synthesized and used as chiral hosts for mediating the enantiodifferentiating [4 + 4] photocyclodimerization of 2-anthracenecarboxylate. The use of 6A,6E-capped γ-cyclodextrin led to the formation of the anti-head-to-head photodimer in –5% enantiomeric excesses (ee) at pH 11 but in 28% ee at pH 6 with accompanying switching of product chirality, for which a pH-responsive conformational change of the capping moiety is likely to be responsible.

2018 ◽  
Vol 9 (4) ◽  
pp. 463-471 ◽  
Author(s):  
Qingwei Li ◽  
Ziquan Cao ◽  
Guojie Wang

A multiple-stimuli-responsive polymer nanocarrier has been self-assembled for NIR/UV light- and pH-controlled cargo release.


2016 ◽  
Vol 4 (26) ◽  
pp. 6287-6294 ◽  
Author(s):  
G. Panzarasa ◽  
M. Dübner ◽  
V. Pifferi ◽  
G. Soliveri ◽  
C. Padeste

Grafting-from of poly(methacrylic acid) brushes enables pH-controlled switching of silicon wafer electrochemistry, making possible the design of new electrochemical hybrid devices.


Author(s):  
Zihang Shen ◽  
Kaiyue Liu ◽  
Zheng Zhou ◽  
Qifang Li

This study proposes a simple method to prepare a pH-responsive and shape memory hydrogel based on cooperative hydrophobic interaction and hydrogen bonding.


Nanoscale ◽  
2017 ◽  
Vol 9 (29) ◽  
pp. 10404-10419 ◽  
Author(s):  
Y. Chen ◽  
O. Tezcan ◽  
D. Li ◽  
N. Beztsinna ◽  
B. Lou ◽  
...  

Polymeric nanogels with folate receptor-based active targeting and pH-controlled drug release are developed to overcome multidrug resistance.


2017 ◽  
Vol 41 (3) ◽  
pp. 916-919 ◽  
Author(s):  
Yujuan Zhou ◽  
Kecheng Jie ◽  
Yong Yao

A novel pH-responsive molecular recognition motif was built between an anionic carboxylate group modified resorcin[4]arene and paraquat in water. We then employed it to fabricate a supra-amphiphile for controllable self-assembly.


RSC Advances ◽  
2015 ◽  
Vol 5 (128) ◽  
pp. 105678-105691 ◽  
Author(s):  
Fatemeh Bazmi zeynabad ◽  
Roya Salehi ◽  
Effat Alizadeh ◽  
Hossein Samadi Kafil ◽  
Azad Mohammad Hassanzadeh ◽  
...  

The modified cationic silica based stimuli responsive polymer–clay nanocomposite with pH responsive release manner could improve the targeting performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 50985-50992 ◽  
Author(s):  
Ruo-Mei Wang ◽  
Qian Liu ◽  
Yu Zhang ◽  
Zhangyong Hong ◽  
He-Fang Wang

A novel multifunctional poly(N-isopropylacrylamide)–Mn–ZnS (PMZS) nanocomposite was developed as a smart drug carrier for thermo- and pH-controlled release of doxorubicin (Dox) and real-time photoluminescence tracking of the released Dox.


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