Acidification with sulfur of the separated solid fraction of raw and co-digested pig slurry: effect on greenhouse gas and ammonia emissions during storage

2016 ◽  
Vol 56 (3) ◽  
pp. 343 ◽  
Author(s):  
F. Gioelli ◽  
E. Dinuccio ◽  
D. Cuk ◽  
L. Rollè ◽  
P. Balsari
Keyword(s):  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Solid Fraction ◽  
Greenhouse Gas Emission ◽  
Ammonia Emission ◽  
Pig Slurry ◽  
Ammonia Emissions ◽  
Gaseous Emissions ◽  
Photoacoustic Detection ◽  
Sulfur Powder

A study was performed to assess: (1) the feasibility to acidify the separated solid fraction of raw and co-digested pig slurry by using a powdery sulfur-based product; and (2) the effect of this acidification method on greenhouse gases and ammonia emissions during manure storage. Samples of raw and co-digested pig slurry were collected at two commercial farms and mechanically separated by a laboratory-scale screw press device. The sulfur powder (80% concentration) was added to the obtained separated solid fractions at three application rates: 0.5%, 1% and 2% (w/w). Carbon dioxide, methane, nitrous oxide and ammonia emissions were afterwards measured during storage of the acidified samples and compared with those measured from untreated samples (Control). Gaseous emissions were determined with dynamic chamber method by Infrared Photoacoustic Detection. Gaseous losses were monitored along 30 and 60 days of storage time for raw solid fraction and digested solid fraction, respectively. The addition of the tested sulfur powder to solid fractions showed to be a reliable and effective method to acidify raw and co-digested solid fractions. Results showed a significant reduction of both greenhouse gases and ammonia emission regardless of the separated solid fraction type. The highest sulfur application rate (2% w/w) led to a reduction of up to 78% of greenhouse gas emission and 65% of ammonia losses from raw separated solid fraction when compared with the Control. Similar results were achieved from the co-digested solid fraction, with emission reduction of up to 67% for ammonia and 61% for greenhouse gas.

scholarly journals Meta-Analysis of Strategies to Reduce NH3 Emissions from Slurries in European Agriculture and Consequences for Greenhouse Gas Emissions

Agronomy ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1633
Author(s):  
Christoph Emmerling ◽  
Andreas Krein ◽  
Jürgen Junk
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Management Practices ◽  
Meta Analysis ◽  
Management Strategies ◽  
Ammonia Emission ◽  
Ammonia Emissions ◽  
The Impact

The intensification of livestock production, to accommodate rising human population, has led to a higher emission of ammonia into the environment. For the reduction of ammonia emissions, different management steps have been reported in most EU countries. Some authors, however, have criticized such individual measures, because attempts to abate the emission of ammonia may lead to significant increases in either methane, nitrous oxide, or carbon dioxide. In this study, we carried out a meta-analysis of experimental European data published in peer-reviewed journals to evaluate the impact of major agricultural management practices on ammonia emissions, including the pollution swapping effect. The result of our meta-analysis showed that for the treatment, storage, and application stages, only slurry acidification was effective for the reduction of ammonia emissions (−69%), and had no pollution swapping effect with other greenhouse gases, like nitrous oxide (−21%), methane (−86%), and carbon dioxide (−15%). All other management strategies, like biological treatment, separation strategies, different storage types, the concealing of the liquid slurry with different materials, and variable field applications were effective to varying degrees for the abatement of ammonia emission, but also resulted in the increased emission of at least one other greenhouse gas. The strategies focusing on the decrease of ammonia emissions neglected the consequences of the emissions of other greenhouse gases. We recommend a combination of treatment technologies, like acidification and soil incorporation, and/or embracing emerging technologies, such as microbial inhibitors and slow release fertilizers.

Effects of winter storage conditions and subsequent agitation on gaseous emissions from liquid dairy manure

2010 ◽  
Vol 90 (1) ◽  
pp. 229-239 ◽  
Author(s):  
A C VanderZaag ◽  
R J Gordon ◽  
R C Jamieson ◽  
D L Burton ◽  
G W Stratton
Keyword(s):  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
Storage Period ◽  
Flux Measurement ◽  
Pilot Scale ◽  
Storage Conditions ◽  
Dairy Manure ◽  
Ammonia Emission ◽  
Gaseous Emissions ◽  
Dissolved Gas

An understanding of emissions from liquid manure facilities during winter, spring thaw and agitation is needed to improve national emissions inventories in Canada. In this study, liquid dairy manure was stored in six pilot-scale tanks (1.8 m deep × 6.6 m2 surface area) covered by steady-state chambers that enabled greenhouse gas (GHG) and ammonia (NH3) flux measurement. After 158 d of undisturbed storage, three tanks were agitated for 5 d (8 h per day) consecutively. During storage, methane (CH4) flux was correlated with manure temperature at 30 cm depth (P < 0.05). Nitrous oxide (N2O) fluxes occurred only during spring thaw - at rates comparable with agricultural soil during spring thaw. On a carbon dioxide (CO2) equivalent basis, however, cumulative N2O fluxes were negligible compared with CH4 fluxes. Flux of NH3 was correlated positively with manure temperature near the surface and negatively with the presence of ice or a surface crust (P < 0.01). Agitation did not affect N2O and NH3 fluxes, whereas CO2 and CH4 fluxes increased significantly (P < 0.01) as dissolved gas and bubbles were released. Trapped CH4 released during agitation was estimated to be 6.3 g CH4 m-3 manure, and was depleted in 2 d. Considering the entire storage period, agitated tanks (158 d + 5 d agitation) had 6% higher GHG fluxes due to higher CH4 losses than undisturbed tanks (163 d). This CH4 release is small in context of annual fluxes, but may partially explain discrepancies between predicted and measured winter fluxes.Key words: Manure storage, agitation, greenhouse gas emission, ammonia emission, dissolved gas

GHG emissions during the storage of rough pig slurry and the fractions obtained by mechanical separation

2008 ◽  
Vol 48 (2) ◽  
pp. 93 ◽  
Author(s):  
E. Dinuccio ◽  
P. Balsari ◽  
W. Berg
Keyword(s):  
Carbon Dioxide ◽  
Solid Fraction ◽  
Ghg Emissions ◽  
Pig Slurry ◽  
Gaseous Emissions ◽  
Ghg Emission ◽  
Photoacoustic Detection ◽  
Dynamic Chamber ◽  
Mechanical Separation ◽  
Carbon Dioxide Co2

Emissions of methane (CH4), carbon dioxide (CO2), nitrous oxide (N2O) and ammonia (NH3) during the storage of rough pig slurry and the fractions (solid and liquid) obtained by mechanical separation were investigated in a laboratory-scale study. Manures were stored for a period of 30 days in open vessels (1500 cm3 capacity) within a climate-controlled room which was kept at 25 ± 0.2°C. Gaseous emissions were determined with the dynamic chamber method by infrared photoacoustic detection. The main GHG emission from the liquid manures was CH4. CH4 losses from both liquid and solid fractions together were 3% higher than from the rough slurry. CO2 losses from both liquid and solid fractions together increased by 10% compared with rough pig slurry. Appreciable N2O fluxes were only measured from the solid fraction. Combining the losses during the storage of both liquid and solid fraction, they resulted in reduced NH3 emissions compared with the storage of the rough pig slurry. Evidence from the present study suggests that mechanical separation of pig slurry has the potential to increase up to 25% the emission of CO2-equivalents to the atmosphere during the storage of the separated fractions if compared with the rough slurry.

scholarly journals Methane, Nitrous Oxide and Ammonia Emissions from Livestock Farming in the Red River Delta, Vietnam: An Inventory and Projection for 2000-2030

2018 ◽  
Author(s):  
An Ha Truong ◽  
Minh Thuy Kim ◽  
Thi Thu Nguyen ◽  
Ngoc Tung Nguyen ◽  
Quang Trung Nguyen
Keyword(s):  
Nitrous Oxide ◽  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
River Delta ◽  
Red River ◽  
Ammonia Emission ◽  
Ammonia Emissions ◽  
Livestock Farming ◽  
Red River Delta ◽  
Livestock Sector

Livestock farming is a major source of greenhouse gas and ammonia emissions. In this study, we estimate methane, nitrous oxide and ammonia emission from livestock sector in the Red River Delta region from 2000 to 2015 and projection to 2030 using IPCC 2006 methodologies with the integration of local emission factors and provincial statistic livestock database. Methane, nitrous oxide and ammonia emissions in 2030 are estimated at 132&nbsp;kt, 8.3&nbsp;kt and 34.2&nbsp;kt, respectively. Total global warming potential is 9.7&nbsp;MtCO2eq in 2030, accounts for 33% greenhouse gas emissions from livestock in Vietnam. Pig farming is responsible for half of both greenhouse gases and ammonia emissions in the studied region. Other major livestock for greenhouse gas emission is cattle and for ammonia emission is poultry. Hanoi contributes for the largest emissions in the region in 2015 but will be caught up and surpassed by other provinces in 2030.

scholarly journals ANTHROPOGENIC COMPONENT OF GREENHOUSE GAS EMISSIONS FROM THE TERRITORY OF THE KALININGRAD REGION

2020 ◽  
pp. 94-110
Author(s):  
N.V. Dvoeglazova ◽  
B.V. Chubarenko ◽  
Y.A. Kozlova
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gases ◽  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
Main Role ◽  
Carbon Dioxide Absorption ◽  
Gas Emissions ◽  
Technology Improvement ◽  
Kaliningrad Region

The increase in greenhouse gases in the atmosphere is influenced to a greater extent by a degree of development of industry, a growth of electrification, deforestation, and the burning of fuel for the production of heating and electricity. The contribution of emissions of each of these factors and the ratio of greenhouse gases in them should be taken into account when developing the measures to prevent climate change. According to calculations of emissions from the territory of the Kaliningrad region the burning of fuel and energy resources are supposed to be playing the main role in the greenhouse gas emission from the territory of the Kaliningrad region. In statistical reference books this activity is described as the “activities for the production and distribution of electricity, gas and water.” The usage of this fuel in the energy sector is increasing: from 1742.4 thousand tons of standard fuel in 1991 up to 2193.9 in 2016. Such little increase in total emissions is due to the general technology improvement in the country. Carbon dioxide makes up the bulk of greenhouse gas emissions from the territory of the Kaliningrad region. The percentage of the gases in the total volume is as follows: CO2 - 96.7%, CH4 - 1%, N2 O - 2.3%. Its emissions for the period from 2013 to 2016 varied from 3,757.4 in 2014 to 4,091.7 in 2015 thousand tons of standard fuel, reaching its maximum value in 2015. The estimate presented in this paper is a lower estimate, since it does not take into account emissions from industrial processes, leaks, land use, waste, etc., as well as from some categories of emission sources due to the lack of data on the use of fuel in the Kaliningrad region. Among other things, the calculations of emissions of carbon dioxide, methane and nitrous oxide from the use of fuel by vehicles in 2016, which have shown to be 1.86 times less than from burning of fossil fuels for the same year (2032.87 Gg CO2 eq. and 3914.79 Gg CO2 eq., respectively) and to account for 34.5% of the total emissions, have been made. Moreover, according to the methodology for calculating emissions the factor of carbon dioxide absorption by the region’s forests has been taken into account. The amount of carbon dioxide absorbed by forests has shown to be only 11.9% of the emissions of this gas during the combustion of boiler and furnace fuel.

scholarly journals Simultaneous shipborne measurements of CO<sub>2</sub>, CH<sub>4</sub> and CO and their application to improving greenhouse-gas flux estimates in Australia

2019 ◽  
Vol 19 (10) ◽  
pp. 7055-7072 ◽  
Author(s):  
Beata Bukosa ◽  
Nicholas M. Deutscher ◽  
Jenny A. Fisher ◽  
Dagmar Kubistin ◽  
Clare Paton-Walsh ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Biomass Burning ◽  
Greenhouse Gas Emission ◽  
Anthropogenic Sources ◽  
Climate Feedback ◽  
Eastern Coast ◽  
Sources And Sinks ◽  
Australian Continent ◽  
Carbon Gases

Abstract. Quantitative understanding of the sources and sinks of greenhouse gases is essential for predicting greenhouse-gas–climate feedback processes and their impacts on climate variability and change. Australia plays a significant role in driving variability in global carbon cycling, but the budgets of carbon gases in Australia remain highly uncertain. Here, shipborne Fourier transform infrared spectrometer measurements collected around Australia are used together with a global chemical transport model (GEOS-Chem) to analyse the variability of three direct and indirect carbon greenhouse gases: carbon dioxide (CO2), methane (CH4) and carbon monoxide (CO). Using these measurements, we provide an updated distribution of these gases. From the model, we quantify their sources and sinks, and we exploit the benefits of multi-species analysis to explore co-variations to constrain relevant processes. We find that for all three gases, the eastern Australian coast is largely influenced by local anthropogenic sources, while the southern, western and northern coasts are characterised by a mixture of anthropogenic and natural sources. Comparing coincident and co-located enhancements in the three carbon gases highlighted several common sources from the Australian continent. We found evidence for 17 events with similar enhancement patterns indicative of co-emission and calculated enhancement ratios and modelled source contributions for each event. We found that anthropogenic co-enhancement events are common along the eastern coast, while co-enhancement events in the tropics primarily derive from biomass burning sources. While the GEOS-Chem model generally reproduced the timing of co-enhancement events, it was less able to reproduce the magnitude of enhancements. We used these differences to identify underestimated, overestimated and missing processes in the model. We found model overestimates of CH4 from coal burning and underestimates of all three gases from biomass burning. We identified missing sources from fossil fuel, biofuel, oil, gas, coal, livestock, biomass burning and the biosphere in the model, pointing to the need to further develop and evaluate greenhouse-gas emission inventories for the Australian continent.

scholarly journals Energy Valuation Methods for Biofuels in South Florida: Introduction to Life Cycle Assessment and Emergy Approaches

EDIS ◽  
2013 ◽  
Vol 2013 (3) ◽  
Author(s):  
J. Van Treese, II ◽  
Edward A. Hanlon ◽  
N. Y. Amponsah ◽  
J. L. Izursa ◽  
J. C. Capece
Keyword(s):  
Life Cycle Assessment ◽  
Life Cycle ◽  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
South Florida ◽  
Gas Emission ◽  
Assessment Approach ◽  
Environmental Component ◽  
Soil And Water

This 5-page fact sheet gives an overview of two methods for evaluating energy transformations in biofuels production. The Life Cycle Assessment approach involves measurements affecting greenhouse gases, which can be linked to the energy considerations used in the Emergy Assessment. Although these two methods have their basis in energy or greenhouse gas emission evaluations, their approaches can lead to a reliable judgment regarding a biofuel process. We can use them to evaluate the economic environmental component of a biofuel process, and decide which biofuel processes favor sustainability. The intended audiences of this publication are growers, researchers, students, and any other readers interested in agriculture and ecology. Written by J. Van Treese II, E. A. Hanlon, N. Y. Amponsah, J. L. Izursa, and J. C. Capece, and published by the UF Department of Soil and Water Science, March 2013. http://edis.ifas.ufl.edu/ss579

scholarly journals Seasonality of greenhouse gas emission factors from biomass burning in the Brazilian Cerrado

2020 ◽  
Author(s):  
Roland Vernooij ◽  
Marcos Vinicius Giongo Alves ◽  
Marco Assis Borges ◽  
Máximo Menezes Costa ◽  
Ana Carolina Sena Barradas ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Biomass Burning ◽  
Large Scale ◽  
Greenhouse Gas Emission ◽  
Emission Factors ◽  
Dry Season ◽  
Total Carbon ◽  
Vegetation Types ◽  
Gas Emission

Abstract. Landscape fires, often referred to as biomass burning (BB), emit substantial amounts of (greenhouse) gases and aerosols into the atmosphere each year. Frequently burning savannas, mostly in Africa, Australia, and South America are responsible for over 60 % of total BB carbon emissions. Compared to many other sources of emissions, fires have a strong seasonality. Previous research has identified the mitigation potential of prescribed fires in savanna ecosystems; by burning early in the dry season when the vegetation has not fully cured, fires are in general patchier and burn less intense. While it is widely accepted that burned area and the total carbon consumed is lower when fires are ignited early in the dry season, little is known about the seasonality of emission factors (EF) of greenhouse gases. This is important because potentially, higher EFs in the early dry season (EDS) could offset some of the carbon benefits of EDS burning. Also, a better understanding of EF seasonality may improve large-scale BB assessments, which to date rely on temporally-static EFs. We used a sampling system mounted on an unmanned aerial vehicle (UAV) and cavity ring-down spectroscopy to estimate CO2, CO, CH4, and N2O EFs in the Estação Ecológica Serra Geral do Tocantins in the Brazilian states of Tocantins and Bahia. The protected area contains all major Cerrado vegetation types found in Brazil, and EDS burning was implemented on a large scale since 2014. We collected and analyzed over 800 smoke samples during the EDS and late dry season (LDS). Averaged over all measurements, the modified combustion efficiency (MCE) was slightly higher in the LDS (0.976 vs. 0.972) and the CH4 and CO EFs were 13 % and 15 % lower in the LDS compared to the EDS. This seasonal effect was larger in more wood-dominated vegetation types. N2O EFs showed a more complex seasonal dependency, with opposite seasonal trends for savannas that were dominated by grasses versus those with abundant shrubs. We found that the N2O EF for the open cerrado was less than half of those reported so far in the BB literature for savannas. This may indicate a substantial overestimation of the contribution of fires in the N2O budget. Overall, our data implies that in this region, seasonal variability in greenhouse gas emission factors may offset only a small fraction of the carbon mitigation gains in fire abatement programs.

scholarly journals THE ADAPTATION OF UKRAINIAN LEGISLATION ON CLIMATE CHANGES TO THE ACQUIS COMMUNAUTAIRE OF THE EUROPEAN UNION

2020 ◽  
pp. 12-18
Author(s):  
T. Kovalenko
Keyword(s):  
Greenhouse Gases ◽  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Greenhouse Gas Emission ◽  
Ozone Layer ◽  
Gas Emissions ◽  
Association Agreement ◽  
National Legislation ◽  
The Law ◽  
Ozone Depleting Substances

The article examines the current state of the Association Agreement implementation in terms of national legislation on climate change and the protection of the ozone layer compliance with the requirements of the EU legal acts listed in Annex XXX to Chapter 6 "Environment" of that Agreement. Under the Association Agreement, such harmonization entails the need to bring national legislation into line with Directive № 2003/87/EC establishing a Community greenhouse gas emissions trading scheme by September 1, 2019 and amending Directive № 96/61/EC ~ 18 ~ ВІСНИК Київського національного університету імені Тараса Шевченка ISSN 1728-3817 as amended by Directive № 2004/101/EC; Regulation (EC) № 842/2006 on certain fluorinated greenhouse gases; Regulation (EU) № 2037/2000 on substances that deplete the ozone layer, as amended and the amendments made by the Regulation (EU) №№ 2038/2000, (EU) 2039/2000, (EU) 1804/2003, (EU) 2077/2004, (EU) 29/2006, (EU) 1366/2006, (EU) 1784/2006, (EC) 1791/2006 and (EC) 2007/899, and Decisions №№ 2003/160 /EC, 2004/232/EC and 2007/54 /EC. The analysis of the national legislation shows that Ukraine as a whole fulfilled its obligations to adapt national legislation to the EU legislation in terms of setting up a monitoring system, reporting and verification of greenhouse gas emissions. The Law of Ukraine "On the Basics of Monitoring, Reporting and Verification of Greenhouse Gas Emissions" was adopted on 12 December 2019. The law comes into force on 1 January 2021. At the same time, it is necessary to adopt by-laws to ensure the effectiveness of the provisions of the aforementioned Law, since as of 1 April 2020 no legislative act has been adopted in its development. Ukraine has also fully fulfilled its obligations to implement the provisions of Regulation (EC) № 2037/2000 on substances that deplete the ozone layer and the provisions of Regulation (EC) № 842/2006 of the European Parliament and of the Council on certain fluorinated greenhouse gases. The Law of Ukraine "On Regulation of Economic Activity with Ozone-Depleting Substances and Fluorinated Greenhouse Gases" was adopted on 12 December 1 2019. The law comes into force on 27 June 2020. The article proves that the legal acts, necessary to introduce internal greenhouse gas emission allowance trading scheme and other market and non-market greenhouse gas emission reduction instruments of these gases in accordance with Ukraine's obligations under the Association Agreement have not yet been adopted. Also there is the necessity to make amendments to the Regulation on the Interagency Commission on Implementation of the United Nations Framework Convention on Climate Change, approved by the Cabinet of Ministers of Ukraine Decree № 583 of April 14, 1999, to extend its tasks in accordance with the provisions of the Paris Agreement. Keywords: the Association Agreement; climate and ozone protection; fluorinated greenhouse gases; monitoring of greenhouse gas emissions; ozone-depleting substances; reporting of greenhouse gas emissions; verification of greenhouse gas emissions.

Greenhouse Gas Emission, Rainfall and Crop Production Over North-Western India

2018 ◽  
Vol 11 (1) ◽  
pp. 47-61
Author(s):  
Vinay Kumar ◽  
Sudip Jana ◽  
Amit Bhardwaj ◽  
R. Deepa ◽  
Saroj Kumar Sahu ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Greenhouse Gas ◽  
Crop Production ◽  
Greenhouse Gas Emission ◽  
Coupled Model ◽  
Western India ◽  
Gas Emission ◽  
Northwestern India ◽  
Increasing Trend ◽  
One Year

Background: This study is based on datasets acquired from multi sources e.g. rain-gauges, satellite, reanalysis and coupled model for the region of Northwestern India. The influence of rainfall on crop production is obvious and direct. With the climate change and global warming, greenhouse gases are also showing an adverse impact on crop production. Greenhouse gases (e.g. CO2, NO2 and CH4) have shown an increasing trend over Northwestern Indian region. In recent years, rainfall has also shown an increasing trend over Northwestern India, while the production of rice and maize are reducing over the region. From eight selected sites, over Northwestern India, where rice and maize productions have reduced by 40%, with an increase in CO2, NO2 and CH4 gas emission by 5% from 1998 to 2011. Results: The correlation from one year to another between rainfall, gas emission and crop production was not very robust throughout the study period, but seemed to be stronger for some years than others. Conclusion: Such trends and crop yield are attributed to rainfall, greenhouse gas emissions and to the climate variability.

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