MAPPING HYDROCARBON CHARGE HISTORIES: DETAILED CHARACTERISATION OF THE SOUTH PEPPER OIL FIELD, CARNARVON BASIN

1996 ◽  
Vol 36 (1) ◽  
pp. 445 ◽  
Author(s):  
M. Lisk ◽  
S. C. George ◽  
R. E. Summons ◽  
R. A. Quezada ◽  
G. W. O'Brien

The South Pepper Field is a small hydrocarbon accumulation located in the Barrow Sub-basin, North West Shelf. In this study, an integrated approach has been adopted which uses new analytical approaches, and combines fluid inclusion, micro and conventional GC-MS, stable isotope, mineralogical and petrological data, to allow the accurate reconstruction of the charge history of this field. The micro GC-MS work on oil-bearing fluid inclusions in the reservoir section allows, for the first time, a comparison to be made between the geochemical characteristics of the presently reservoired oil with samples of the palaeo-r eservoired oils, as preserved within the fluid inclusions.Oil inclusion abundances (OIA) recorded within the reservoir section in South Pepper-1 show two distinct abundance peaks, which are interpreted to correspond to zones of high oil saturation. The first occurs near the top of the reservoir, in sands that are presently gas saturated and represents a palaeo-oil column. The oil inclusions occur primarily within pre-existing ankerite cement that crystallised from highly saline fluids, probably derived from Palaeozoic evaporites. Carbon isotope compositions measured on the ankerite are isotopically depleted, consistent with the derivation of CO2 from the maturation of organic matter. Geochemical characterisation of the oil contained within these inclusions shows the presence of biomarkers such as 30-norhopanes and methylhopanes which are indicative of a calcareous source rock. This excludes the Jurassic Dingo Claystone as a source for this early oil charge and migration of oil from a pre-Jurassic source rock is inferred. Subsequent uplift and sub-aerial exposure of the basin margin during the Middle Miocene allowed fresh waters to dilute formation waters in the Barrow Group and biodegrade this early oil charge. However, the abundance of highly water-soluble compounds in the fluid inclusion oil suggests that biodegradation occurred subsequent to initial oil emplacement.The second oil inclusion abundance peak corresponds to the present-day oil zone and, although absolute oil inclusion abundances are similar to those recorded in the upper zone, the fluorescence colours are significantly different, suggesting a different source for the second oil charge. Geochemical characterisation of oil recovered by DST confirms this later oil charge was derived from a more clay-rich oxic source and has previously been typed to the Upper Dingo Claystone. The low abundance of this type of oil inclusion in samples from above the present GOC indicates that this later oil charge failed to accumulate at the top of the reservoir and so it cannot have been displaced by a later gas charge. Rather, the oil inclusion data suggest the emplacement of gas, probably derived from Triassic source rocks, occurred either prior to, or coincident with, the second oil charge.High OIA in the presently water bearing reservoir of South Pepper-3 suggests that high oil saturation originally extended beyond the present OWC. However, the absence of stratigraphically equivalent high OIA samples in wells from the east of the field suggests that late stage westerly tilting of the structure resulted in a reduction in closure and loss of oil across the eastern spill point. The presence of high gas readings and associated amplitude anomalies in the Windalia Radiolarite suggests that hydrocarbons are continuing to leak up the bounding fault. However, the absence of significant residual oil zones in other wells suggests that liquids were largely retained and that leakage involved the progressive bleeding of gas across a soft seal.

1992 ◽  
Vol 32 (1) ◽  
pp. 289 ◽  
Author(s):  
John Scott

The main potential source rock intervals are generally well defined on the North West Shelf by screening analysis such as Rock-Eval. The type of product from the source rocks is not well defined, owing to inadequacies in current screening analysis techniques. The implications of poor definition of source type in acreage assessment are obvious. The type of product is dependent on the level of organic maturity of the source rock, the ability of products to migrate out of the source rock and on the type of organic material present. The type of kerogen present is frequently determined by Rock-Eval pyrolysis. However, Rock-Eval has severe limitations in defining product type when there is a significant input of terrestrial organic material. This problem has been recognised in Australian terrestrial/continental sequences but also occurs where marine source rock facies contain terrestrially-derived higher plant material. Pyrolysis-gas chromatography as applied to source rock analysis provides, by molecular typing, a better method of estimating the type of products of the kerogen breakdown than bulk chemical analysis such as Rock-Eval pyrolysis.


2020 ◽  
Vol 38 (6) ◽  
pp. 2695-2710
Author(s):  
Yao-Ping Wang ◽  
Xin Zhan ◽  
Tao Luo ◽  
Yuan Gao ◽  
Jia Xia ◽  
...  

The oil–oil and oil–source rock correlations, also termed as geochemical correlations, play an essential role in the construction of petroleum systems, guidance of petroleum exploration, and definition of reservoir compartments. In this study, the problems arising from oil–oil and oil–source rock correlations were investigated using chemometric methods on oil and source rock samples from the WZ12 oil field in the Weixinan sag in the Beibuwan Basin. Crude oil from the WZ12 oil field can be classified into two genetic families: group A and B, using multidimensional scaling and principal component analysis. Similarly, source rocks of the Liushagang Formation, including its first, second, and third members, can be classified into group I and II, corresponding to group B and A crude oils, respectively. The principle geochemical parameters in the geochemical correlation for the characterisation and classification of crude oils and source rocks were 4MSI, C27Dia/C27S, and C24 Tet/C26 TT. This study provides insights into the selection of appropriate geochemical parameters for oil–oil and oil–source rock correlations, which can also be applied to other sedimentary basins.


2020 ◽  
Vol 20 (24) ◽  
pp. 15811-15833
Author(s):  
Danitza Klopper ◽  
Paola Formenti ◽  
Andreas Namwoonde ◽  
Mathieu Cazaunau ◽  
Servanne Chevaillier ◽  
...  

Abstract. The chemical composition of aerosols is of particular importance to assess their interactions with radiation, clouds and trace gases in the atmosphere and consequently their effects on air quality and the regional climate. In this study, we present the results of the first long-term dataset of the aerosol chemical composition at an observatory on the coast of Namibia, facing the south-eastern Atlantic Ocean. Aerosol samples in the mass fraction of particles smaller than 10 µm in aerodynamic diameter (PM10) were collected during 26 weeks between 2016 and 2017 at the ground-based Henties Bay Aerosol Observatory (HBAO; 22∘6′ S, 14∘30′ E; 30 m above mean sea level). The resulting 385 filter samples were analysed by X-ray fluorescence and ion chromatography for 24 inorganic elements and 15 water-soluble ions. Statistical analysis by positive matrix factorisation (PMF) identified five major components, sea salt (mass concentration: 74.7±1.9 %), mineral dust (15.7±1.4 %,), ammonium neutralised (6.1±0.7 %), fugitive dust (2.6±0.2 %) and industry (0.9±0.7 %). While the contribution of sea salt aerosol was persistent, as the dominant wind direction was south-westerly and westerly from the open ocean, the occurrence of mineral dust was episodic and coincided with high wind speeds from the south-south-east and the north-north-west, along the coastline. Concentrations of heavy metals measured at HBAO were higher than reported in the literature from measurements over the open ocean. V, Cd, Pb and Nd were attributed to fugitive dust emitted from bare surfaces or mining activities. As, Zn, Cu, Ni and Sr were attributed to the combustion of heavy oils in commercial ship traffic across the Cape of Good Hope sea route, power generation, smelting and other industrial activities in the greater region. Fluoride concentrations up to 25 µg m−3 were measured, as in heavily polluted areas in China. This is surprising and a worrisome result that has profound health implications and deserves further investigation. Although no clear signature for biomass burning could be determined, the PMF ammonium-neutralised component was described by a mixture of aerosols typically emitted by biomass burning, but also by other biogenic activities. Episodic contributions with moderate correlations between NO3-, nss-SO42- (higher than 2 µg m−3) and nss-K+ were observed, further indicative of the potential for an episodic source of biomass burning. Sea salt accounted for up to 57 % of the measured mass concentrations of SO42-, and the non-sea salt fraction was contributed mainly by the ammonium-neutralised component and small contributions from the mineral dust component. The marine biogenic contribution to the ammonium-neutralised component is attributed to efficient oxidation in the moist marine atmosphere of sulfur-containing gas phase emitted by marine phytoplankton in the fertile waters offshore in the Benguela Upwelling System. The data presented in this paper provide the first ever information on the temporal variability of aerosol concentrations in the Namibian marine boundary layer. This data also provide context for intensive observations in the area.


2002 ◽  
Vol 42 (1) ◽  
pp. 387 ◽  
Author(s):  
S.C. George ◽  
H. Volk ◽  
T.E. Ruble ◽  
M.P. Brincat

Geochemical evidence is presented for a previously unrecognised oil generative source rock in the Nancar Trough area. This source rock supplements the middle to late Jurassic source rocks, which have previously been shown to have generated most of the oils in the northern Bonaparte Basin and the Vulcan Sub-basin. Fluids with a strong contribution from this new source rock, defined here as the Nancar oil family, have an unusually high abundance of mid-chain substituted monomethylalkanes. In comparison, oils from the Vulcan Sub-basin contain mostly terminally substituted monomethylalkanes and the overall abundance is much lower. Oils from the Laminaria High and some from the northern Vulcan Sub-Basin show intermediate characteristics and may be co-sourced. Evidence from the analysis of fluid inclusion oils was important in establishing the presence of the new oil family because interference from drilling mud contaminants could be excluded. The detailed geochemistry of Ludmilla–1 fluid inclusion oil suggests the source rock for the Nancar oil family was deposited in a marine environment under sub-oxic conditions with limited sulphur content, a low contribution of terrestrial organic matter and a high contribution of organic matter from bacterial activity. Since monomethylalkanes are typical biomarkers of cyanobacteria, the source rock that gave rise to the new oil family may be rich in cyanobacterial organic matter. Further studies on sediment extracts are needed to establish an explicit oil-source rock correlation and to identify the stratigraphic location/palaeo-environment of the source rock. Such information will be valuable in determining the prospectivity of the large and relatively unexplored province draining the Nancar Trough kitchen.


2004 ◽  
Vol 44 (1) ◽  
pp. 151 ◽  
Author(s):  
A.P. Radlinski ◽  
J.M. Kennard ◽  
D.S. Edwards ◽  
A.L. Hinde ◽  
R. Davenport

Small Angle Neutron Scattering (SANS) analyses were carried out on 165 potential source rocks of Late Jurassic–Early Cretaceous age from nine wells in the Browse Basin (Adele–1, Argus–1, Brecknock South–1, Brewster–1A, Carbine–1, Crux–1, Dinichthys–1, Gorgonichthys–1 and Titanichthys–1). Samples from Brewster–1A and Dinichthys–1 were also analysed using the Ultra Small Angle Neutron Scattering (USANS) technique.The SANS/USANS data detect the presence of generated bitumen and mobile hydrocarbons in pores and are pore-size specific. As the pore-size range in mudstones extends from about 0.001–30 μm, the presence of bitumen in the small pores detected by SANS indicates the depth of onset of hydrocarbon generation, whereas the presence of bitumen and mobile hydrocarbons in the largest pores detected by USANS indicates a significant saturation and the onset of expulsion.Although geochemical data imply the existence of a potential gas and oil source rock in the Lower Cretaceous section (Echuca Shoals and Jamieson Formations), the SANS/USANS data indicate significant generation but little or no expulsion. This source limitation may explain poor exploration success for liquid hydrocarbons in the area. The SANS/USANS data provide evidence of intra- and inter-formational hydrocarbon migration or kerogen kinetics barriers. There is no evidence of an oil charge to the Berriasian Brewster Sandstone from the Echuca Shoals Formation, although some gas charge in Brewster–1A is possible. This novel microstructural technique can be used to independently calibrate and refine source rock generation/expulsion scenarios derived from geochemistry modelling.


2007 ◽  
Vol 13 ◽  
pp. 13-16 ◽  
Author(s):  
Henrik I. Petersen ◽  
Hans P. Nytoft

The Central Graben in the North Sea is a mature petroleum province with Upper Jurassic – lowermost Cretaceous marine shale of the Kimmeridge Clay Formation and equivalents as the principal source rock, and Upper Cretaceous chalk as the main reservoirs. However, increasing oil prices and developments in drilling technologies have made deeper plays depending on older source rocks increasingly attractive. In recent years exploration activities have therefore also been directed towards deeper clastic plays where Palaeozoic deposits may act as petroleum source rocks. Carboniferous coaly sections are the most obvious source rock candidates. The gas fields of the major gas province in the southern North Sea and North-West Europe are sourced from the thick Upper Carboniferous Coal Measures, which contain hundreds of coal seams (Drozdzewski 1993; Lokhorst 1998; Gautier 2003). North of the gas province Upper Carboni-ferous coal-bearing strata occur onshore in northern England and in Scotland, but offshore in the North Sea area they have been removed by erosion. However, Lower Carboniferous strata are present offshore and have been drilled in the Witch Ground Graben and in the north-eastern part of the Forth Approaches Basin (Fig. 1A), where most of the Lower Carbon iferous sediments are assigned to the sandstone/shale-dominated Tayport For mation and to the coal-bearing Firth Coal Formation (Bruce & Stemmerik 2003). Highly oil-prone Lower Carboniferous lacustrine oil shales occur onshore in the Midland Valley, Scotland, but they have only been drilled by a single well off shore and seem not to be regionally distributed (Parnell 1988). In the southern part of the Norwegian and UK Central Graben and in the Danish Central Graben a total of only nine wells have encountered Lower Carboniferous strata, and while they may have a widespread occurrence (Fig. 1B; Bruce & Stemmerik 2003) their distribution is poorly constrained in this area. The nearly 6000 m deep Svane-1/1A well (Fig. 1B) in the Tail End Graben encountered gas and condensate at depths of 5400–5900 m, which based on carbon isotope values may have a Carboniferous source (Ohm et al. 2006). In the light of this the source rock potential of the Lower Carboniferous coals in the Gert-2 well (Fig. 1C) has recently been assessed (Petersen & Nytoft 2007).


2001 ◽  
Vol 41 (1) ◽  
pp. 549
Author(s):  
B.G.K. van Aarssen ◽  
R. Alexander ◽  
R.I. Kagi

The ratio of two trimethylnaphthalenes in sediment extracts can be used to indicate the establishment of a liquid reaction environment in the source rock. The abundance of 1,3,6-TMN relative to 1,3,7-TMN (denoted here as 136/137) is near constant in crude oils. In sediments however, there is a much larger variation. This difference is attributed to the presence of two different reaction environments in the source rock: a liquid organic phase which is the direct precursor of crude oils, and the kerogen / rock matrix onto which compounds are adsorbed. In the liquid reaction environment, methylated naphthalenes undergo many reactions, leading to a near constant value for 136/137. On the other hand, when they are adsorbed onto kerogen or minerals, different reactions prevail and an excess of 1,3,6-TMN is formed. When measured in sediment extracts, the closer 136/137 is to the value typical for oils, the better the liquid reaction environments established in the source rock. This concept was used to study the behaviour of 136/ 137 with depth in 10 sedimentary sequences from the North West Shelf. The results showed that sediments from several wells were capable of establishing a liquid reaction environment, a necessary step in the formation of oil. Results from other wells indicated that little or no liquid reaction environment could be established, suggesting that these sediments were unlikely to be capable of oil formation. The 136/137 parameter is a convenient indicator for determining the extent to which the liquid reaction environment has been established in the source rock and may be useful in determining oil generation potential.


2004 ◽  
Vol 44 (1) ◽  
pp. 223 ◽  
Author(s):  
H. Volk ◽  
S.C. George ◽  
C.J. Boreham ◽  
R.H. Kempton

The molecular composition of fluid inclusion (FI) oils from Leander Reef–1, Houtman–1 and Gage Roads–2 provide evidence of the origin of palaeo-oil accumulations in the offshore Perth Basin. These data are complemented by compound specific isotope (CSI) profiles of n-alkanes for the Leander Reef–1 and Houtman–1 samples, which were acquired on purified n-alkane fractions gained by micro-fractionation of lean FI oil samples, showing the technical feasibility of this technique. The Leander Reef–1 FI oil from the top Carynginia Formation shares many biomarker similarities with oils from the Dongara and Yardarino oilfields, which have been correlated with the Early Triassic Kockatea Shale. The heavier isotopic values for the C15-C25 n-alkanes in the Leander Reef–1 FI oil indicate, however, that it is a mixture, and suggest that the main part of this oil (~90%) was sourced from the more terrestrial and isotopically heavier Early Permian Carynginia Formation or Irwin River Coal Measures. This insight would have been precluded when looking at molecular evidence alone. The Houtman–1 FI oil from the top Cattamarra Coal Measures (Middle Jurassic) was sourced from a clay-rich, low sulphur source rock with a significant input of terrestrial organic matter, deposited under oxic to sub-oxic conditions. Biomarkers suggest sourcing from a more prokaryotic-dominated facies than for the other FI oils, possibly a saline lagoon. The Houtman–1 FI oil δ13C CSI n-alkane data are similar to those acquired on the Walyering–2 oil. Possible lacustrine sources may exist in the Early Jurassic Eneabba Formation and are present in the Late Jurassic Yarragadee Formation. The low maturity Gage Roads–2 FI oil from the Carnac Formation (Early Cretaceous) was derived from a strongly terrestrial, non-marine source rock containing a high proportion of Araucariacean-type conifer organic matter. It has some geochemical differences to the presently reservoired oil in Gage Roads–1, and was probably sourced from the Early Cretaceous Parmelia Formation.


2021 ◽  
Author(s):  
A. R. Livsey

The South Sumatra Basin has been a focus for hydrocarbon exploration since the earliest oil discoveries in the late 1890s. Despite production of over 2500MMbbls of oil and 9.5TCF of gas our regional understanding of the basin’s petroleum systems is still evolving. Most discoveries occur along a series of Late Neogene NNW-SSE elongated anticlines. The most prolific reservoirs are fluvial – shallow marine sandstones of the Upper Oligocene – Lower Miocene Talang Akar Formation but hydrocarbons have also been discovered in numerous sandstone and carbonate reservoirs ranging in age from Middle – Late Miocene to Eocene. Pre-Tertiary fractured Basement reservoirs are also important gas producers. A geochemical database for produced, tested and seep oils and gases has been compiled from the analytical reports, produced by different service companies over a 40-year period, to understand the spatial distribution of hydrocarbon types and relate this to source type, source maturity and migration patterns. Integration with published palaeoenvironmental reconstructions for the time intervals associated with source rock deposition has enabled a better understanding of migration directions and migration limits. The database of over 100 oils and 40 gases has revealed a wider variation in geochemical character than previously thought, indicating the presence of numerous fluvio-deltaic and lacustrine types suggesting subtle variations in the character of the effective source rocks within the basin, related to both organic matter type and depositional environment. Seven major oil families, often with several sub-groups, have been identified, while the presence of both biogenic and thermogenic gases of varying maturities are also noted. Spatial analysis of these hydrocarbons, integrated with source rock indications, palaeoenvironmental reconstructions and structural maps have allowed definition of kitchen areas and drainage areas for these hydrocarbon accumulations and a better understanding of the charge risk and likely hydrocarbon type in undrilled areas.


Sign in / Sign up

Export Citation Format

Share Document