HYDROCARBON GENERATION AND EXPULSION FROM EARLY CRETACEOUS SOURCE ROCKS IN THE BROWSE BASIN, NORTH WEST SHELF, AUSTRALIA: A SMALL ANGLE NEUTRON SCATTERING STUDY

2004 ◽  
Vol 44 (1) ◽  
pp. 151 ◽  
Author(s):  
A.P. Radlinski ◽  
J.M. Kennard ◽  
D.S. Edwards ◽  
A.L. Hinde ◽  
R. Davenport
Keyword(s):  
Neutron Scattering ◽  
Pore Size ◽  
Source Rock ◽  
Early Cretaceous ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Source Rocks ◽  
Geochemical Data ◽  
Hydrocarbon Generation ◽  
North West

Small Angle Neutron Scattering (SANS) analyses were carried out on 165 potential source rocks of Late Jurassic–Early Cretaceous age from nine wells in the Browse Basin (Adele–1, Argus–1, Brecknock South–1, Brewster–1A, Carbine–1, Crux–1, Dinichthys–1, Gorgonichthys–1 and Titanichthys–1). Samples from Brewster–1A and Dinichthys–1 were also analysed using the Ultra Small Angle Neutron Scattering (USANS) technique.The SANS/USANS data detect the presence of generated bitumen and mobile hydrocarbons in pores and are pore-size specific. As the pore-size range in mudstones extends from about 0.001–30 μm, the presence of bitumen in the small pores detected by SANS indicates the depth of onset of hydrocarbon generation, whereas the presence of bitumen and mobile hydrocarbons in the largest pores detected by USANS indicates a significant saturation and the onset of expulsion.Although geochemical data imply the existence of a potential gas and oil source rock in the Lower Cretaceous section (Echuca Shoals and Jamieson Formations), the SANS/USANS data indicate significant generation but little or no expulsion. This source limitation may explain poor exploration success for liquid hydrocarbons in the area. The SANS/USANS data provide evidence of intra- and inter-formational hydrocarbon migration or kerogen kinetics barriers. There is no evidence of an oil charge to the Berriasian Brewster Sandstone from the Echuca Shoals Formation, although some gas charge in Brewster–1A is possible. This novel microstructural technique can be used to independently calibrate and refine source rock generation/expulsion scenarios derived from geochemistry modelling.

Small angle neutron scattering signature of oil generation in artificially and naturally matured hydrocarbon source rocks

2000 ◽  
Vol 31 (1) ◽  
pp. 1-14 ◽  
Author(s):  
A.P. Radliński ◽  
C.J. Boreham ◽  
P. Lindner ◽  
O. Randl ◽  
G.D. Wignall ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Source Rocks ◽  
Hydrocarbon Source Rocks ◽  
Oil Generation

Experimental Evidence of Super Densification of Adsorbed Hydrogen by in-situ Small Angle Neutron Scattering (SANS)

2011 ◽  
Vol 1334 ◽  
Author(s):  
Dipendu Saha ◽  
Lilin He ◽  
Cristian I. Contescu ◽  
Nidia C. Gallego ◽  
Yuri B. Melnichenko
Keyword(s):  
Neutron Scattering ◽  
Pore Size ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Hydrogen Gas ◽  
Necessary Condition ◽  
Adsorbed Hydrogen ◽  
Oak Ridge ◽  
Hydrogen Molecules

ABSTRACTEntrapping hydrogen molecules within the nanopores of solid adsorbents serves as a unique alternative for on-board storing of hydrogen for transportation purposes. The key advantage of the physisorption process for hydrogen storage is the higher density values achieved with the adsorbed gas, compared to that of the compressed phase, translating into higher storage capacities at lower pressures. The necessary condition for effective adsorption is the presence of narrow micropores of < 2 nm in width which provide the most suitable environment of hydrogen adsorption. Despite numerous theoretical calculations or indirect experimental estimations, there has not been a direct experimental measurement of the density of adsorbed hydrogen as a function of pressure and/or pore size. In the present study, we report on the use of in-situ small angle neutron scattering (SANS) to study the phase behavior of hydrogen confined in narrow micropores. We provide for the first time direct experimental measurements of the effect of pore size and pressure on hydrogen adsorbed on a polyfurfuryl alcohol-derived activated carbon (PFAC), at room temperature and pressures up to 207 bar. SANS studies were carried out at the General-Purpose Small-Angle Neutron Scattering spectrometer of the High Flux Isotope Reactor at Oak Ridge National Laboratory. The measurements covered the Q-range from 0.01 to 0.8 Å-1, covering the pores in the range of 9 to 34 Å of the PFAC material. Initial results suggest that the density of adsorbed hydrogen is higher than the density of bulk hydrogen gas and increases with decreasing pore size.

scholarly journals An integrated pore size distribution measurement method of small angle neutron scattering and mercury intrusion capillary pressure

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rui Shen ◽  
Xiaoyi Zhang ◽  
Yubin Ke ◽  
Wei Xiong ◽  
Hekun Guo ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Capillary Pressure ◽  
Size Distribution ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Measurement Method ◽  
Full Scale ◽  
Mercury Intrusion

AbstractSmall-angle neutron scattering and high-pressure mercury intrusion capillary pressure testing are integrated to analyze the pore size distribution of the broad sense shale oil reservoir samples of the Permian Lucaogou Formation in the Jimsar Sag, Junggar Basin, China. The results show that, compared with the measurement method integrating gas adsorption and mercury intrusion, combination of small-angle neutron scattering and mercury intrusion can more accurately characterize full-scale pore size distribution. The full-scale pore size distribution curve of the rock samples in the study area includes two types: the declining type and submicron pore-dominated type. The declining type is mainly found with silty mudstone and dolomitic mudstone, and most of its pores are smaller than 80 nm. Silt-fine sandstones and dolarenite are mostly of the submicron pores-dominated type, with most pores smaller than 500 nm. They also present large specific pore volumes and average pore diameters of macropores and are the favorable lithogenous facies for development of high-quality reservoirs.

THE PETROLEUM GEOCHEMISTRY OF OILS AND SOURCE ROCKS FROM THE NORTHERN BONAPARTE BASIN, OFFSHORE NORTHERN AUSTRALIA

2000 ◽  
Vol 40 (1) ◽  
pp. 257 ◽  
Author(s):  
J.C. Preston ◽  
D.S. Edwards
Keyword(s):  
Source Rock ◽  
Early Cretaceous ◽  
Late Jurassic ◽  
Structural Complexity ◽  
Source Rocks ◽  
Geochemical Data ◽  
Northwestern Part ◽  
Migration Patterns ◽  
Catchment Areas ◽  
Migration Pathways

Geochemical data from oils and source rock extracts have been used to delineate the active petroleum systems of the Northern Bonaparte Basin. The study area comprises the northeastern portion of the Territory of Ashmore and Cartier Islands, and the western part of the Zone of Co-operation Area A, and is specifically concerned with the wells located on and between the Laminaria and Flamingo highs. The oils and condensates from this region can be divided into two distinct chemical groups which correspond with the reservoir types, namely, a smaller group recovered from fracture porosity within the Early Cretaceous Darwin Formation, and a larger group reservoired in sandstones of the Middle-to-Late Jurassic Plover and Elang formations. The oils recovered from the Darwin Formation have a marine source affinity and correlate with sediment extracts from the underlying Early Cretaceous Echuca Shoals Formation. The Elang/ Plover-reservoired oils, which include all the commercial accumulations, were divided into two end-member families; the first includes the relatively land-plant- influenced oils from the northwestern part of the area (e.g. Laminaria, Corallina, Buffalo and Jahal fields), the second includes the relatively marine-influenced oils to the southeast (e.g. Bayu-Undan fields). Another oil family comprises the geographically and geochemically intermediate oils of the Elang and Kakatua fields and adjacent areas. While none of the oils can be uniquely correlated with a single source unit, they show geochemical similarities with Middle-to-Late Jurassic source rock extracts. Organic-rich rocks within the Plover and Elang formations are the major source of hydrocarbons for this area. The range in geochemistry of the Elang/Plover-reservoired oils may arise from facies variation within these sediments, but is more probably due to the localised additional input of hydrocarbons generated from thermally mature organic-rich claystone seals that overlie the Elang reservoir in catchment areas and traps; i.e. from the Frigate Formation for the northwestern oil family and from the Flamingo Group for the southeastern oil family. The short-range migration patterns dictated by the structural complexity of the basin are reflected in the closeness with which variations in the geochemical character of the accumulated liquids track variations in the character of source-seal lithologies. The length of migration pathways can, therefore, be inferred from the similarity or otherwise of source-seal characters with those of the hydrocarbon accumulations themselves. The resulting observations may challenge existing ideas concerning migration patterns, hydrocarbon prospectivity and prospect risking within the Northern Bonaparte Basin.

Pore Size Effect on Methane Adsorption in Mesoporous Silica Materials Studied by Small-Angle Neutron Scattering

Langmuir ◽  
2016 ◽  
Vol 32 (35) ◽  
pp. 8849-8857 ◽  
Author(s):  
Wei-Shan Chiang ◽  
Emiliano Fratini ◽  
Piero Baglioni ◽  
Jin-Hong Chen ◽  
Yun Liu
Keyword(s):  
Mesoporous Silica ◽  
Size Effect ◽  
Neutron Scattering ◽  
Pore Size ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Methane Adsorption ◽  
Silica Materials ◽  
Mesoporous Silica Materials

scholarly journals Accessibility of Pores to Methane in New Albany Shale Samples of Varying Maturity Determined Using SANS and USANS

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8438
Author(s):  
Tomasz Blach ◽  
Andrzej P. Radlinski ◽  
Phung Vu ◽  
Yeping Ji ◽  
Liliana de Campo ◽  
...  
Keyword(s):  
Organic Matter ◽  
Neutron Scattering ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Marcellus Shale ◽  
Hydrocarbon Generation ◽  
Pressure Cycling ◽  
New Albany Shale ◽  
Shale Formation ◽  
Accessible Porosity

The accessibility of pores to methane has been investigated in Devonian New Albany Shale Formation early-mature (Ro = 0.50%) to post-mature (Ro = 1.40%) samples. A Marcellus Shale Formation sample was included to expand the maturation range to Ro 2.50%. These are organic matter-rich rocks with total organic carbon (TOC) values of 3.4 to 14.4% and porosity values of 2.19 to 6.88%. Contrast matching small-angle neutron scattering (SANS) and ultra-small angle neutron scattering (USANS) techniques were used to generate porosity-related data before and after pressure cycling under hydrostatic (in a vacuum and at 500 bar of deuterated methane) and uniaxial stress (0 to ca. 350 bar) conditions. Our results showed that the accessible porosity was small for the samples studied, ranging from zero to 2.9%. No correlation between the accessible porosity and TOC or mineralogical composition was revealed, and the most likely explanation for porosity variation was related to the thermal transformation of organic matter and hydrocarbon generation. Pressure caused improvements in accessible porosity for most samples, except the oil window sample (Ro = 0.84%). Our data show that densification of methane occurs in nanopores, generally starting at diameters smaller than 20 nm, and that the distribution of methane density is affected by pressure cycling.

Monitoring phase behavior of hydrogen confined in carbon nanopores by in-situ Small Angle Neutron Scattering technique

2012 ◽  
Vol 1440 ◽  
Author(s):  
Hongxin Zhang ◽  
Lilin He ◽  
Yuri B. Melnichenko ◽  
Cristian I. Contescu ◽  
Nidia C. Gallego
Keyword(s):  
Neutron Scattering ◽  
Phase Behavior ◽  
Pore Size ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Hydrogen Gas ◽  
Carbon Adsorbents ◽  
Ambient Temperatures ◽  
Polyfurfuryl Alcohol

ABSTRACTWe report on the use of in-situ small angle neutron scattering (SANS) technique to study the phase behavior of hydrogen confined in narrow pores of ultramicroporous carbon (UMC) with a very large surface area (2630 m2/g) and pore volume (1.3 cm3/g). The effect of pore size and pressure on hydrogen adsorbed on UMC at room temperature and pressures up to ∼200 bar were investigated. In a previous experiment, we have measured the density of adsorbed H2 gas in the nanopores and mesopores of polyfurfuryl alcohol-derived activated carbon (PFAC) by SANS technique. Here, a comparative SANS study between the UMC and PFAC was conducted in order to further investigate the densification of H2 as a function of pore size and pressure. Initial results suggest that the density of confined H2 in both UMC and PFAC is considerably higher than that of the bulk hydrogen gas. The density is systematically higher in the narrow pores and decreases with increasing pore size. These results clearly demonstrate the advantage of adsorptive storage over compressed gas storage and emphasize the greater efficiency of micropores over mesopores in the adsorption process, which can be used to guide the development of new carbon adsorbents tailored for maximum H2 storage capacities at near-ambient temperatures.

KITCHENS, KETTLES AND CUPS OF HYDROCARBONS, VICTORIAN OTWAY BASIN

1997 ◽  
Vol 37 (1) ◽  
pp. 285
Author(s):  
K. Mehin ◽  
A.G. Link
Keyword(s):  
Source Rock ◽  
Early Cretaceous ◽  
Bulk Composition ◽  
Source Rocks ◽  
Eastern Region ◽  
Hydrocarbon Generation ◽  
Good Source ◽  
Oil Generation ◽  
Close Proximity ◽  
Rock Eval

Evaluation of Early Cretaceous source rocks within the onshore Victoria Otway Basin has revealed that thick, mature shales containing predominantly gas-prone and in local concentrations, oil-prone macerals exist northwest of Portland, in the Tyrendarra Embayment, and around the Port Campbell region.Current results of Rock-Eval, bulk composition, gas chromatography, and biomarker analyses, coupled with geohistory and hydrocarbon generation interpretations, indicate that at least three phases of oil generation and expulsion occurred within the basin. The earliest phase, which coincided with the maximum heatflow in the crust around 100 Ma, resulted in the charging of the existing stratigraphic/shoestring traps of the basin. The second and third phases occurred in the eastern end of the basin at around 85 and 60 Ma. There is also evidence to suggest that structural traps of the eastern areas were formed later, during Oligocene time, and that these traps are probably still receiving late-stage charges of hydrocarbons.Although the sparse well density in the basin has resulted in limited, non-uniforin sampling opportunities, several regions with good Early Cretaceous source rocks can be recognised. Some of these good source rock areas are in close proximity to the several known hydrocarbon shows and producing fields. These current studies, which also include a source rock risk analysis indicating source rock adequacy, show that locations for future exploration could include the Casterton-Portland-Mt Gambier western region, the Peterborough-Port Campbell eastern region, and the prospective close peripheries and offshore extensions of these regions.

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