ORGANIC PETROLOGY OF LIPTINITES IN THE DENISON TROUGH, QUEENSLAND

1987 ◽  
Vol 27 (1) ◽  
pp. 86
Author(s):  
J.W. Beeston
Keyword(s):  
Organic Matter ◽  
Energy Storage ◽  
Marine Algae ◽  
Reproductive Organs ◽  
Coal Seams ◽  
Organic Petrology ◽  
Wide Range ◽  
Coal Facies ◽  
Abandoned Channels ◽  
Lake Margin

Liptinite macerals in the Denison Trough are derived from a wide range of organisms including marine acritarchs, and non-marine algae, lycopods, articulates, ferns and gymnosperms. They are formed from the lipid and wax-rich components of these organisms, in particular from specialised tissues, leaves and reproductive organs developed for protection and/or energy storage. They occur chiefly in terrestrially deposited sediments and coals, yet their distribution is variable amongst the seven coal facies assemblages and six disseminated organic matter (DOM) suites distinguished in the trough. The most abundant liptinites are derived from miospores, leaf cuticles and algae. Miosporinite averages 2.6 per cent of total rock and is most abundant in coal seams, banded coals and carbonaceous mudstones that were deposited in ponds, abandoned channels and intraswamp lakes, where it ranges up to 14 per cent. Cutinite averages 0.7 per cent of total rock, and is most abundant in coal seams and banded coals that were deposited as leaf banks in shallow water marginal to peat swamps, where it ranges up to 10 per cent. Alginite averages 0.1 per cent of total rock, and is most abundant in mudstones that were deposited in lake margin ponds, where it ranges up to 22 per cent. Preservation of liptinites (as determined by fluorescence) is best where they were deposited in a quiet regime, at or near their sites of origin, in concentration. In some of these situations they occur in association or juxtaposition with the highly fluorescing, non-structured macerals sporogenite, phylloresinite and fluorinite. The latter are suggested as remnants of material that has otherwise yielded oil.

Designing the Electricity Market with Energy Storage Devices

2020 ◽  
Vol 12 (12) ◽  
pp. 31-43
Author(s):  
Tatiana A. VASKOVSKAYA ◽  
◽  
Boris A. KLUS ◽  
Keyword(s):  
Energy Storage ◽  
Electricity Market ◽  
Power Flow ◽  
Optimal Power Flow ◽  
Storage Systems ◽  
Energy System ◽  
Energy Storage Systems ◽  
Storage Model ◽  
Optimal Power ◽  
Wide Range

The development of energy storage systems allows us to consider their usage for load profile leveling during operational planning on electricity markets. The paper proposes and analyses an application of an energy storage model to the electricity market in Russia with the focus on the day ahead market. We consider bidding, energy storage constraints for an optimal power flow problem, and locational marginal pricing. We show that the largest effect for the market and for the energy storage system would be gained by integration of the energy storage model into the market’s optimization models. The proposed theory has been tested on the optimal power flow model of the day ahead market in Russia of 10000-node Unified Energy System. It is shown that energy storage systems are in demand with a wide range of efficiencies and cycle costs.

Coagulation/flocculation/ultrafiltration for natural organic matter removal in drinking water production

2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Natural Organic Matter ◽  
Membrane Fouling ◽  
Membrane Filtration ◽  
Membrane Surface ◽  
Water Production ◽  
Cellulose Acetate Membranes ◽  
Wide Range ◽  
Drinking Water Production

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.

New Thermal Energy Storage Materials From Industrial Wastes: Compatibility of Steel Slag With the Most Common Heat Transfer Fluids

2015 ◽  
Vol 137 (4) ◽  
Author(s):  
Iñigo Ortega-Fernández ◽  
Javier Rodríguez-Aseguinolaza ◽  
Antoni Gil ◽  
Abdessamad Faik ◽  
Bruno D’Aguanno
Keyword(s):  
Heat Transfer ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Steel Slag ◽  
Industrial Wastes ◽  
Energy Storage Materials ◽  
Iron And Steel ◽  
Heat Transfer Fluids ◽  
Wide Range

Slag is one of the main waste materials of the iron and steel manufacturing. Every year about 20 × 106 tons of slag are generated in the U.S. and 43.5 × 106 tons in Europe. The valorization of this by-product as heat storage material in thermal energy storage (TES) systems has numerous advantages which include the possibility to extend the working temperature range up to 1000 °C, the reduction of the system cost, and at the same time, the decrease of the quantity of waste in the iron and steel industry. In this paper, two different electric arc furnace (EAF) slags from two companies located in the Basque Country (Spain) are studied. Their thermal stability and compatibility in direct contact with the most common heat transfer fluids (HTFs) used in the concentrated solar power (CSP) plants are analyzed. The experiments have been designed in order to cover a wide range of temperature up to the maximum operation temperature of 1000 °C corresponding to the future generation of CSP plants. In particular, three different fluids have been studied: synthetic oil (Syltherm 800®) at 400 °C, molten salt (Solar Salt) at 500 °C, and air at 1000 °C. In addition, a complete characterization of the studied slags and fluids used in the experiments is presented showing the behavior of these materials after 500 hr laboratory-tests.

A generally applicable pedotransfer function that estimates field capacity and permanent wilting point from soil texture and bulk density

2008 ◽  
Vol 88 (5) ◽  
pp. 761-774 ◽  
Author(s):  
J. A. P. Pollacco
Keyword(s):  
Organic Matter ◽  
Soil Moisture ◽  
Bulk Density ◽  
Soil Texture ◽  
The United States ◽  
Pedotransfer Functions ◽  
Pedotransfer Function ◽  
Data Set ◽  
Wide Range ◽  
Fitting Parameters

Hydrological models require the determination of fitting parameters that are tedious and time consuming to acquire. A rapid alternative method of estimating the fitting parameters is to use pedotransfer functions. This paper proposes a reliable method to estimate soil moisture at -33 and -1500 kPa from soil texture and bulk density. This method reduces the saturated moisture content by multiplying it with two non-linear functions depending on sand and clay contents. The novel pedotransfer function has no restrictions on the range of the texture predictors and gives reasonable predictions for soils with bulk density that varies from 0.25 to 2.16 g cm-3. These pedotransfer functions require only five parameters for each pressure head. It is generally accepted that the introduction of organic matter as a predictor improves the outcomes; however it was found by using a porosity based pedotransfer model, using organic matter as a predictor only modestly improves the accuracy. The model was developed employing 18 559 samples from the IGBP-DIS soil data set for pedotransfer function development (Data and Information System of the International Geosphere Biosphere Programme) database that embodies all major soils across the United States of America. The function is reliable and performs well for a wide range of soils occurring in very dry to very wet climates. Climatical grouping of the IGBP-DIS soils was proposed (aquic, tropical, cryic, aridic), but the results show that only tropical soils require specific grouping. Among many other different non-climatical soil groups tested, only humic and vitric soils were found to require specific grouping. The reliability of the pedotransfer function was further demonstrated with an independent database from Northern Italy having heterogeneous soils, and was found to be comparable or better than the accuracy of other pedotransfer functions found in the literature. Key words: Pedotransfer functions, soil moisture, soil texture, bulk density, organic matter, grouping

scholarly journals Excitation-Dependent Fluorescence Quantum Yield for Freshwater Chromophoric Dissolved Organic Matter from Northern Russian Lakes

2018 ◽  
Vol 2018 ◽  
pp. 1-7 ◽  
Author(s):  
Svetlana Patsaeva ◽  
Daria Khundzhua ◽  
Oleg A. Trubetskoj ◽  
Olga E. Trubetskaya
Keyword(s):  
Organic Matter ◽  
Quantum Yield ◽  
Dissolved Organic Matter ◽  
Fluorescence Quantum Yield ◽  
Molecular Size ◽  
Reversed Phase ◽  
Chromophoric Dissolved Organic Matter ◽  
Excitation Wavelength ◽  
Fluorescence Detector ◽  
Wide Range

Advanced fluorescence analysis within the wide range of excitation wavelengths from 230 to 510 nm accompanied with chromatography was used to study natural chromophoric dissolved organic matter (CDOM) from three freshwater Karelian lakes. The influence of excitation wavelength (λex) on fluorescence quantum yield and emission maximum position was determined. The CDOM fluorescence quantum yield has reached a minimum at λex∼270–280 nm and a maximum at λex∼340–360 nm. It was monotonously decreasing after 370 nm towards longer excitation wavelengths. Analytical reversed-phase high-performance liquid chromatography with multiwavelength fluorescence detector characterized distribution of fluorophores between hydrophilic/hydrophobic CDOM parts. This technique revealed “hidden” protein-like fluorophores for some CDOM fractions, in spite of the absence of protein-like fluorescence in the initial CDOM samples. The humic-like fluorescence was documented for all hydrophilic and hydrophobic CDOM chromatographic peaks, and its intensity was decreasing along with peaks’ hydrophobicity. On contrary, the protein-like fluorescence was found only in the hydrophobic peaks, and its intensity was increasing along with peaks’ hydrophobicity. This work provides new data on the CDOM optical properties consistent with the formation of supramolecular assemblies controlled by association of low-molecular size components. In addition, these data are very useful for understanding the CDOM function in the environment.

scholarly journals Simultaneous Monitoring of Crystalline Active Materials and Resistance Evolution in Lithium-Sulfur Batteries

2019 ◽  
Author(s):  
Yu-Chuan Chien ◽  
Ashok Menon ◽  
William Brant ◽  
Daniel Brandell ◽  
Matthew Lacey
Keyword(s):  
Energy Storage ◽  
Structural Changes ◽  
Dissolution Kinetics ◽  
Carbon Composite ◽  
Diffusion Resistance ◽  
Active Materials ◽  
Host Matrix ◽  
Current Interruption ◽  
Wide Range ◽  
Lithium Sulfur

Operando X-ray diffraction (XRD) is a valuable tool for studying secondary battery materials as it allows for the direct correlation of electrochemical behavior with structural changes of crystalline active materials. This is especially true for the lithium-sulfur chemistry, in which energy storage capability depends on the complex growth and dissolution kinetics of lithium sulfide (Li2S) and sulfur (S8) during discharge and charge, respectively. In this work, we present a novel development of this method through combining operando XRD with simultaneous and continuous resistance measurement using an Intermittent Current Interruption (ICI) method. We show that a coefficient of diffusion resistance, which reflects the transport properties in the sulfur/carbon composite electrode, can be determined from analysis of each current interruption. Its relationship to the established Warburg impedance model is validated theoretically and experimentally. We also demonstrate for an optimized electrode formulation and cell construction that the diffusion resistance increases sharply at the discharge end point, which is consistent with the blocking of pores in the carbon host matrix. The combination of XRD with ICI allows for a direct correlation of structural changes with not only electrochemical properties but also energy loss processes at a non-equilibrium state, and therefore is a valuable technique for the study of a wide range of energy storage chemistries.<br>

scholarly journals Type of organic fertilizer rather than organic amendment per se increases abundance of soil biota

PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e11204
Author(s):  
Maria Viketoft ◽  
Laura G.A. Riggi ◽  
Riccardo Bommarco ◽  
Sara Hallin ◽  
Astrid R. Taylor
Keyword(s):  
Organic Matter ◽  
Organic Amendments ◽  
Trophic Levels ◽  
Soil Biota ◽  
Organic Fertilizers ◽  
Nitrogen Fertilizers ◽  
Mineral Fertilizers ◽  
Soil Organisms ◽  
Wide Range

Addition of organic amendments is a commonly used practice to offset potential loss of soil organic matter from agricultural soils. The aim of the present study was to examine how long-term addition of organic matter affects the abundance of different soil biota across trophic levels and the role that the quality of the organic amendments plays. Here we used a 17-year-old fertilization experiment to investigate soil biota responses to four different organic fertilizers, compared with two mineral nitrogen fertilizers and no fertilization, where the organic fertilizers had similar carbon content but varied in their carbon to nitrogen ratios. We collected soil samples and measured a wide range of organisms belonging to different functional groups and trophic levels of the soil food web. Long-term addition of organic and mineral fertilizers had beneficial effects on the abundances of most soil organisms compared with unfertilized soil, but the responses differed between soil biota. The organic fertilizers generally enhanced bacteria and earthworms. Fungi and nematodes responded positively to certain mineral and organic fertilizers, indicating that multiple factors influenced by the fertilization may affect these heterogeneous groups. Springtails and mites were less affected by fertilization than the other groups, as they were present at relatively high abundances even in the unfertilized treatment. However, soil pH had a great influence on springtail abundance. In summary, the specific fertilizer was more important in determining the numerical and compositional responses of soil biota than whether it was mineral or organic. Overall, biennial organic amendments emerge as insufficient, by themselves, to promote soil organisms in the long run, and would need to be added annually or combined with other practices affecting soil quality, such as no or reduced tillage and other crop rotations, to have a beneficial effect.

scholarly journals Thermal fractionation of soil organic matter produces fine-scale distributions of SOM age

2021 ◽  
Author(s):  
Shane Stoner ◽  
Carlos Sierra ◽  
Marion Schrumpf ◽  
Sebastian Dötterl ◽  
Susan Trumbore
Keyword(s):  
Thermal Stability ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Chemical Oxidation ◽  
Fine Scale ◽  
Mineral Association ◽  
Density Fractions ◽  
Chemical Complexity ◽  
Wide Range ◽  
Carbon Release

&lt;p&gt;Soil organic matter (SOM) is a complex collection of organic molecules of varying origin, structure, chemical activity, and mineral association. A wide array of laboratory methods exists to separate SOM based on qualitative, biological, chemical, and physical characteristics. However, all present conceptual and logistical limitations, including the requirement of a substantial amount soil material.&lt;/p&gt;&lt;p&gt;An newly applied alternative method of fractionation relies on a conceptual analogue between biochemical stability in soil and thermal stability, e.g. more persistent SOM will require higher temperatures (greater energy inputs) to decompose than less persistent SOM. This accounts for both chemical complexity and mineral association as main factors in determining SOM persistence.&lt;/p&gt;&lt;p&gt;In this method, carbon is released by heating SOM to 900&amp;#176;C at a constant rate. The peaks of carbon release are grouped into activation energy pools, CO&lt;sub&gt;2 &lt;/sub&gt;is collected, and analyzed for &lt;sup&gt;13&lt;/sup&gt;C and &lt;sup&gt;14&lt;/sup&gt;C. We seek to describe in finer detail the distribution of soil radiocarbon by adding another fractionation step following a different paradigm of SOM stability, and explore mineralogical effects on SOM quality and stability using thermal analysis, radiocarbon, and gas chromatography.&lt;/p&gt;&lt;p&gt;Here, we analyzed bulk soil and soil fractions derived from density separation and chemical oxidation, as well as mineral horizons dominated by diverse mineralogies. Density fractions contained a wide range of radiocarbon activities and that young SOM is stabilized across multiple fractions, likely due to organomineral complexation. Initial results showed that soil minerals with limited stabilization potential released C at lower temperatures than those with diverse stabilization mechanisms. High-temperature sub-fractions contained the oldest carbon across fractions and minerals, thus supporting the assumption that thermal stability can be used as a limited analogue for stability in soil. We present a fine-scale distribution of radiocarbon in SOM and discuss the potential of this method for comparison with other fractionation techniques.&lt;/p&gt;

HUMUS FRACTION RATIOS AS A MEANS OF DISCRIMINATING BETWEEN HORIZON TYPES

1980 ◽  
Vol 60 (2) ◽  
pp. 219-229 ◽  
Author(s):  
L. E. LOWE
Keyword(s):  
Organic Matter ◽  
Humic Acid ◽  
Carbon Content ◽  
Fulvic Acid ◽  
Soil Classification ◽  
Acid Fraction ◽  
Humus Fraction ◽  
Wide Range ◽  
Fraction Distribution

Humus fraction distribution in a wide range of horizon samples was examined by measuring carbon content in humic acid (Ch), in fulvic acid (Cf) and in the strongly colored polyphenolic component of the fulvic acid fraction (Ca). Fraction distribution was described by the ratios Ch/Cf and Ca/Cf. It was concluded that humus fraction ratios were related to horizon types as used in the Canadian System of Soil Classification, and were effective in discriminating between certain horizon types, particularly between Luvisolic Bt and Podzolic Bf. The results also suggested that humus fraction ratios may be effective in separating distinct sub-populations within Ah horizons and Bf horizons in general, based on qualitative differences in organic matter present. Aspects of the role of humus fractions in soil genesis are discussed.

scholarly journals The living soil ? an agricultural perspective

2007 ◽  
Vol 28 (3) ◽  
pp. 104 ◽  
Author(s):  
Margaret M Roper ◽  
Vadakattu V S R Gupta
Keyword(s):  
Biological Control ◽  
Porous Medium ◽  
Organic Matter ◽  
Plant Growth ◽  
Ecosystem Function ◽  
Soil Structure ◽  
Biological Function ◽  
Decomposition Of Organic Matter ◽  
Wide Range ◽  
Biodiversity And Ecosystem Function

Soils are much more than a porous medium for supporting plant growth. Soils are living, because they contain a wide range of microorganisms including bacteria, fungi, algae, protozoa, nematodes and other fauna including microarthropods, macroarthropods, termites and earthworms. All play a crucial role in the biological function of soils including decomposition of organic matter, nutrient transformations, biological control, development of soil structure to mention a few. Until recently the complexity of life in the soil has been difficult to unravel, but new DNA and biochemical tools are providing insights into its phenotypic and functional diversity and capability, and should drive the development of managements that nurture biodiversity and ecosystem function.

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