Ionic liquids as heat transfer fluids: comparison with known systems, possible applications, advantages and disadvantages

2015 ◽  
Vol 84 (8) ◽  
pp. 875-890 ◽  
Author(s):  
E A Chernikova ◽  
L M Glukhov ◽  
V G Krasovskiy ◽  
L M Kustov ◽  
M G Vorobyeva ◽  
...  
Author(s):  
Banqiu Wu ◽  
Ramana G. Reddy ◽  
Robin D. Rogers

Abstract Feasibility of ionic liquids as liquid thermal storage media and heat transfer fluids in a solar thermal power plant was investigated. Many ionic liquids such as [C4min][PF6], [C8mim][PF6], [C4min][bistrifluromethane sulflonimide], [C4min][BF4], [C8mim][BF4], and [C4min][bistrifluromethane sulflonimide] were synthesized and characterized using thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), nuclear magnetic resonance (NMR), viscometry, and some other methods. Properties such as decomposition temperature, melting point, viscosity, density, heat capacity, and thermal expansion coefficient were measured. The calculated storage density for [C8mim][PF6] is 378 MJ/m3 when the inlet and outlet field temperatures are 210°C and 390°C. For a single ionic liquid, [C4mim][BF4], the liquid temperature range is from −75°C to 459°C. It is found that ionic liquids have advantages of high density, wide liquid temperature range, low viscosity, high chemical stability, non-volatility, high heat capacity, and high storage density. Based on our experimental results, it is concluded that ionic liquids could be excellent liquid thermal storage media and heat transfer fluids in solar thermal power plant.


Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 858
Author(s):  
Titan Paul ◽  
Amitav Tikadar ◽  
Rajib Mahmud ◽  
Azzam Salman ◽  
A. K. M. Monjur Morshed ◽  
...  

In recent years, solar thermal energy (STE) has attracted energy researchers because of its higher efficacy compared to the photovoltaic solar cell. STE is one of the forms of solar energy whereby heat is transferred via a secondary medium called heat transfer fluids (HTFs). Therefore, the overall performance of STE depends on the thermophysical properties and thermal performance of the HTFs. Traditional HTFs suffer from low decomposition temperature, high melting point, and higher vapor pressure. To overcome these limitations, researchers have recently begun working on new HTFs for STE. Ionic liquids (ILs) are considered as a potential candidate for the next generation of HTFs because of their enhanced thermophysical properties, such as thermal stability at high temperature, insignificant vapor pressure, and high ionic conductivity. In addition, thermophysical properties and thermal performance of ILs can be further enhanced by dispersing nanoparticles, which is one of the emerging research interests to improve the efficiency of the solar thermal system. This paper summarizes the recent study of ILs-based nanofluids as HTFs. These summaries are divided into two sections (i) thermophysical properties studies, such as density, viscosity, thermal conductivity, and heat capacity, and (ii) thermal performance studies such as natural convection and forced convection. Synthesis of ILs-based nanofluids and thermophysical properties measurement techniques are also discussed. Based on these state-of-the-art summaries, we offer recommendations for potential future research direction for ILs-based nanofluids.


Author(s):  
Ann E. Visser ◽  
Nicholas J. Bridges ◽  
Brenda L. Garcia-Diaz ◽  
Joshua R. Gray ◽  
Elise B. Fox

2018 ◽  
Vol 57 (18) ◽  
pp. 6516-6529 ◽  
Author(s):  
João M. P. França ◽  
Maria José V. Lourenço ◽  
S. M. Sohel Murshed ◽  
Agílio A. H. Pádua ◽  
Carlos A. Nieto de Castro

2013 ◽  
Vol 27 (6) ◽  
pp. 3385-3393 ◽  
Author(s):  
Elise B. Fox ◽  
Ann E. Visser ◽  
Nicholas J. Bridges ◽  
Jake W. Amoroso

2019 ◽  
Vol 91 (8) ◽  
pp. 1309-1340 ◽  
Author(s):  
Kamil Oster ◽  
Christopher Hardacre ◽  
Johan Jacquemin ◽  
Ana P. C. Ribeiro ◽  
Abdulaziz Elsinawi

Abstract Heat transfer fluids materials are manufactured for the purpose of transfer, distribution and storage of heat. Several of their important properties can be listed (for example flash point, thermal expansivity or technical safety). However, to assess the thermal exchange performance of these fluids, a prior knowledge of their heat capacity, density, viscosity and thermal conductivity is obligatory. The most popular heat transfer fluids are based on organic liquids, such as ethylene glycol. However, new technologies and development require more efficient materials. Ionanofluids, mixtures of ionic liquids and nanoparticles, were proposed as a viable replacement for those commonly used fluids due to the properties of ionic liquids (wide liquid range or low vapour pressure and flammability) combined with enhanced thermophysical properties of nanofluids caused by the dispersion of nanoparticles (mainly thermal conductivity and heat capacity). Very few authors reported the extensive analysis of those systems thermophysical properties and impact on the heat exchange efficiency. Moreover, the availability of published data is very limited. The aim of this work is to investigate ionanofluids based on the trihexyl(tetradecyl)phosphonium cation paired with the acetate, butanoate, hexanoate, octanoate or decanoate anion, mixed with carbon nanotubes, boron nitride, graphite or mesoporous carbon as nanoparticles with concentration up to 3 wt %. The density, heat capacity, thermal stability, thermal conductivity and viscosity of selected ionanofluids were determined experimentally as functions of the temperature (up to 363.15 K) and compared with theoretical tools to evaluate the predictive capability. Based on the experimental results, lubrication, heat storage potential and economic analysis were also discussed and compared to commercial heat transfer fluids.


2011 ◽  
Vol 25 (10) ◽  
pp. 4862-4864 ◽  
Author(s):  
Nicholas J. Bridges ◽  
Ann E. Visser ◽  
Elise B. Fox

2014 ◽  
Vol 1070-1072 ◽  
pp. 1722-1726
Author(s):  
Guang Xiao Kou ◽  
Rong Rong Lu ◽  
Jing Hua Yang ◽  
Ling Ling Cai ◽  
Pei Na Shang

Introduces the technological process of the open heating system with a liquid-phase organic heat transfer fluids heater by analyzing the advantages and disadvantages of preventing heat transfer fluids from oxidation based on expansion pipe with cooling water casing. And it presents two methods to prevent heat transfer fluids from oxidation by arranging directly cooling coils or pulsating heat pipes in the expansion tank; it also provides the schematic diagram of those methods as well as comparatively analyzes their advantages and disadvantages.


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