scholarly journals Thermophysical Properties of Nanoparticle-Enhanced Ionic Liquids (NEILs) Heat-Transfer Fluids

2013 ◽  
Vol 27 (6) ◽  
pp. 3385-3393 ◽  
Author(s):  
Elise B. Fox ◽  
Ann E. Visser ◽  
Nicholas J. Bridges ◽  
Jake W. Amoroso
Keyword(s):  
Heat Transfer ◽  
Ionic Liquids ◽  
Thermophysical Properties ◽  
Heat Transfer Fluids

scholarly journals A Critical Review on the Development of Ionic Liquids-Based Nanofluids as Heat Transfer Fluids for Solar Thermal Energy

Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 858
Author(s):  
Titan Paul ◽  
Amitav Tikadar ◽  
Rajib Mahmud ◽  
Azzam Salman ◽  
A. K. M. Monjur Morshed ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Ionic Liquids ◽  
Vapor Pressure ◽  
Thermal Performance ◽  
Thermal Energy ◽  
Thermophysical Properties ◽  
Solar Thermal ◽  
Potential Candidate ◽  
Solar Thermal Energy ◽  
Heat Transfer Fluids

In recent years, solar thermal energy (STE) has attracted energy researchers because of its higher efficacy compared to the photovoltaic solar cell. STE is one of the forms of solar energy whereby heat is transferred via a secondary medium called heat transfer fluids (HTFs). Therefore, the overall performance of STE depends on the thermophysical properties and thermal performance of the HTFs. Traditional HTFs suffer from low decomposition temperature, high melting point, and higher vapor pressure. To overcome these limitations, researchers have recently begun working on new HTFs for STE. Ionic liquids (ILs) are considered as a potential candidate for the next generation of HTFs because of their enhanced thermophysical properties, such as thermal stability at high temperature, insignificant vapor pressure, and high ionic conductivity. In addition, thermophysical properties and thermal performance of ILs can be further enhanced by dispersing nanoparticles, which is one of the emerging research interests to improve the efficiency of the solar thermal system. This paper summarizes the recent study of ILs-based nanofluids as HTFs. These summaries are divided into two sections (i) thermophysical properties studies, such as density, viscosity, thermal conductivity, and heat capacity, and (ii) thermal performance studies such as natural convection and forced convection. Synthesis of ILs-based nanofluids and thermophysical properties measurement techniques are also discussed. Based on these state-of-the-art summaries, we offer recommendations for potential future research direction for ILs-based nanofluids.

scholarly journals Ionic liquid-based nanofluids (ionanofluids) for thermal applications: an experimental thermophysical characterization

2019 ◽  
Vol 91 (8) ◽  
pp. 1309-1340 ◽  
Author(s):  
Kamil Oster ◽  
Christopher Hardacre ◽  
Johan Jacquemin ◽  
Ana P. C. Ribeiro ◽  
Abdulaziz Elsinawi
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Heat Capacity ◽  
Ionic Liquids ◽  
Thermophysical Properties ◽  
New Technologies ◽  
Organic Liquids ◽  
Published Data ◽  
Thermal Exchange ◽  
Heat Transfer Fluids

Abstract Heat transfer fluids materials are manufactured for the purpose of transfer, distribution and storage of heat. Several of their important properties can be listed (for example flash point, thermal expansivity or technical safety). However, to assess the thermal exchange performance of these fluids, a prior knowledge of their heat capacity, density, viscosity and thermal conductivity is obligatory. The most popular heat transfer fluids are based on organic liquids, such as ethylene glycol. However, new technologies and development require more efficient materials. Ionanofluids, mixtures of ionic liquids and nanoparticles, were proposed as a viable replacement for those commonly used fluids due to the properties of ionic liquids (wide liquid range or low vapour pressure and flammability) combined with enhanced thermophysical properties of nanofluids caused by the dispersion of nanoparticles (mainly thermal conductivity and heat capacity). Very few authors reported the extensive analysis of those systems thermophysical properties and impact on the heat exchange efficiency. Moreover, the availability of published data is very limited. The aim of this work is to investigate ionanofluids based on the trihexyl(tetradecyl)phosphonium cation paired with the acetate, butanoate, hexanoate, octanoate or decanoate anion, mixed with carbon nanotubes, boron nitride, graphite or mesoporous carbon as nanoparticles with concentration up to 3 wt %. The density, heat capacity, thermal stability, thermal conductivity and viscosity of selected ionanofluids were determined experimentally as functions of the temperature (up to 363.15 K) and compared with theoretical tools to evaluate the predictive capability. Based on the experimental results, lubrication, heat storage potential and economic analysis were also discussed and compared to commercial heat transfer fluids.

Use of metallic nanoparticles to improve the thermophysical properties of organic heat transfer fluids used in concentrated solar power

Solar Energy ◽  
2014 ◽  
Vol 105 ◽  
pp. 468-478 ◽  
Author(s):  
Dileep Singh ◽  
Elena V. Timofeeva ◽  
Michael R. Moravek ◽  
Sreeram Cingarapu ◽  
Wenhua Yu ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermophysical Properties ◽  
Metallic Nanoparticles ◽  
Solar Power ◽  
Concentrated Solar Power ◽  
Heat Transfer Fluids

Novel Ionic Liquid Thermal Storage for Solar Thermal Electric Power Systems

2001 ◽  
Author(s):  
Banqiu Wu ◽  
Ramana G. Reddy ◽  
Robin D. Rogers
Keyword(s):  
Heat Transfer ◽  
Ionic Liquids ◽  
Thermal Power ◽  
Thermal Storage ◽  
Solar Thermal ◽  
Liquid Temperature ◽  
Storage Density ◽  
Heat Transfer Fluids ◽  
Solar Thermal Power ◽  
Storage Media

Abstract Feasibility of ionic liquids as liquid thermal storage media and heat transfer fluids in a solar thermal power plant was investigated. Many ionic liquids such as [C4min][PF6], [C8mim][PF6], [C4min][bistrifluromethane sulflonimide], [C4min][BF4], [C8mim][BF4], and [C4min][bistrifluromethane sulflonimide] were synthesized and characterized using thermogravimetric analysis (TGA), differential scanning calorimeter (DSC), nuclear magnetic resonance (NMR), viscometry, and some other methods. Properties such as decomposition temperature, melting point, viscosity, density, heat capacity, and thermal expansion coefficient were measured. The calculated storage density for [C8mim][PF6] is 378 MJ/m3 when the inlet and outlet field temperatures are 210°C and 390°C. For a single ionic liquid, [C4mim][BF4], the liquid temperature range is from −75°C to 459°C. It is found that ionic liquids have advantages of high density, wide liquid temperature range, low viscosity, high chemical stability, non-volatility, high heat capacity, and high storage density. Based on our experimental results, it is concluded that ionic liquids could be excellent liquid thermal storage media and heat transfer fluids in solar thermal power plant.

Natural Convection in Rectangular Cavity With Nanoparticle Enhanced Ionic Liquids (NEILs)

2012 ◽  
Author(s):  
Titan C. Paul ◽  
A. K. M. M. Morshed ◽  
Elise B. Fox ◽  
Ann E. Visser ◽  
Nicholas J. Bridges ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Heat Capacity ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Natural Convection ◽  
Thermophysical Properties ◽  
Convection Heat Transfer ◽  
Natural Convection Heat Transfer ◽  
Convection Heat

A systematic natural convection heat transfer experiment has been carried out of nanoparticle enhanced ionic liquids (NEILs) in rectangular enclosures (lengthxwidthxheight, 50×50×50mm and 50×50×75mm) heated from below condition. In the present experiment NEIL was made of N-butyl-N-methylpyrrolidinium bis{(trifluoromethyl)sulfonyl} imide, ([C4mpyrr][NTf2]) ionic liquid with 0.5% (weight%) Al2O3 nanoparticles. In addition to characterize the natural convection behavior of NEIL, thermophysical properties such as thermal conductivity, heat capacity, and viscosity were also measured. The result shows that the thermal conductivity of NEIL enhanced ∼3% from the base ionic liquid (IL), heat capacity enhanced ∼12% over the measured temperature range. The natural convection experimental result shows consistent for two different enclosures based on the degrading natural convection heat transfer rate over the measured Rayleigh number range. Possible reasons of the degradation of natural convection heat transfer may be the relative change of the thermophysical properties of NEIL compare to the base ionic liquid.

Ionic liquids as heat transfer fluids: comparison with known systems, possible applications, advantages and disadvantages

2015 ◽  
Vol 84 (8) ◽  
pp. 875-890 ◽  
Author(s):  
E A Chernikova ◽  
L M Glukhov ◽  
V G Krasovskiy ◽  
L M Kustov ◽  
M G Vorobyeva ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Ionic Liquids ◽  
Heat Transfer Fluids ◽  
Advantages And Disadvantages
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