Role of solvent polarity on fluorescence quenching of 3MOCE in binary solvent mixtures

2020 ◽  
Author(s):  
S. Vaijayanthimala ◽  
Kalpana Sharma ◽  
Raveendra Melavanki ◽  
P. Bhavya ◽  
U. Meghana ◽  
...  
Keyword(s):  
Fluorescence Quenching ◽  
Solvent Polarity ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Binary Solvent Mixtures ◽  
Role Of Solvent

Effect of Solvent Polarity on the Fluorescence Quenching of Biologically Active 5BAMC by Aniline in Binary Solvent Mixtures

2010 ◽  
Vol 20 (6) ◽  
pp. 1175-1180 ◽  
Author(s):  
Raveendra M. Melavanki ◽  
Raviraj A. Kusanur ◽  
Jagadish S. Kadadevaramath ◽  
Manohar V. Kulkarni
Keyword(s):  
Fluorescence Quenching ◽  
Solvent Polarity ◽  
Biologically Active ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Binary Solvent Mixtures ◽  
Effect Of Solvent

Effect of viscosity and dielectric constant variation on fractional fluorescence quenching analysis of coumarin dye in binary solvent mixtures

Luminescence ◽  
2018 ◽  
Vol 33 (5) ◽  
pp. 933-940 ◽  
Author(s):  
P. Bhavya ◽  
Raveendra Melavanki ◽  
Raviraj Kusanur ◽  
Kalpana Sharma ◽  
V. T. Muttannavar ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Fluorescence Quenching ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Binary Solvent Mixtures ◽  
Quenching Analysis ◽  
Coumarin Dye

scholarly journals Probing Solvation Effects in Binary Solvent Mixtures with the Use of Solvatochromic Dyes

2021 ◽  
Author(s):  
Ioanna Deligkiozi ◽  
Raffaello Papadakis
Keyword(s):  
Preferential Solvation ◽  
Solvent Polarity ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Two Phase ◽  
Binary Solvent Mixtures ◽  
The Third ◽  
Beta Cyclodextrin ◽  
High Responsiveness ◽  
Linear Solvation

In this work three molecules exhibiting dual sensing solvatochromic behaviors are examined in the context of solvation in binary solvent mixtures (BSMs). The compounds studied involve two functional groups with high responsiveness to solvent polarity namely pentacyanoferrate(II) (PC) and azo groups. Two of these compounds are [2]rotaxanes involving alpha- or beta- cyclodextrin (CyD) and the third is their CyD-free precursor. The dual solvatochromic behavior of these compounds is investigated in water/ethlylene glycol (EG) mixtures and their dual solvatochromic responses are assessed in terms of the intensity of solvatochromism and the extent of preferential solvation. To achieve this the linear solvation model by Kamlet, Abboud and Taft [J. Organomet. Chem. 1983, 48, 2877–2887] and the two-phase model of solvation by Bagchi and coworkers [J. Phys. Chem. 1991, 95, 3311–3314] are employed. The influence of the presence or lack of CyD (alpha- or beta-) on these dual solvatochromic sensors is analyzed.

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