Preferential Solvation of a Highly Medium Responsive Pentacyanoferrate(II) Complex in Binary Solvent Mixtures: Understanding the Role of Dielectric Enrichment and the Specificity of Solute–Solvent Interactions

2016 ◽  
Vol 120 (35) ◽  
pp. 9422-9433 ◽  
Author(s):  
Raffaello Papadakis
Keyword(s):  
Preferential Solvation ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Solvent Interactions ◽  
Binary Solvent Mixtures

Preferential solvation of p-nitroaniline in a binary mixture of chloroform and hydrogen bond acceptor solvents: the role of specific solute–solvent hydrogen bonding

2020 ◽  
Vol 22 (6) ◽  
pp. 3545-3562 ◽  
Author(s):  
Prakash Kumar Malik ◽  
Madhusmita Tripathy ◽  
Aravind Babu Kajjam ◽  
Sabita Patel
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Binary Mixture ◽  
Preferential Solvation ◽  
Binary Solvent ◽  
Local Concentration ◽  
Solvent Mixtures ◽  
Hydrogen Bond Acceptor ◽  
Binary Solvent Mixtures

Solute–solvent H-bonding in binary solvent mixtures may increase the local concentration at specific sites resulting in location specific preferential solvation.

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