Vibrational properties of substitutional hexagonal boron nitride sheets

2020 ◽  
Author(s):  
Himadri R. Soni ◽  
Amit K. Bhojani ◽  
Prafulla K. Jha
2014 ◽  
Vol 94 ◽  
pp. 225-233 ◽  
Author(s):  
Md. Sherajul Islam ◽  
Kenji Ushida ◽  
Satoru Tanaka ◽  
Takayuki Makino ◽  
Akihiro Hashimoto

2019 ◽  
Vol 30 (19) ◽  
pp. 195201 ◽  
Author(s):  
Magdalena Birowska ◽  
Joanna Urban ◽  
Michał Baranowski ◽  
Duncan K Maude ◽  
Paulina Plochocka ◽  
...  

2019 ◽  
Author(s):  
Matěj Velický ◽  
Sheng Hu ◽  
Colin R. Woods ◽  
Peter S. Toth ◽  
Viktor Zólyomi ◽  
...  

Marcus-Hush theory of electron transfer is one of the pillars of modern electrochemistry with a large body of supporting experimental evidence presented to date. However, some predictions, such as the electrochemical behavior at microdisk electrodes, remain unverified. Herein, we present a study of electron tunneling across a hexagonal boron nitride barrier between a graphite electrode and redox levels in a liquid solution. This was achieved by the fabrication of microdisk electrodes with a typical diameter of 5 µm. Analysis of voltammetric measurements, using two common redox mediators, yielded several electrochemical parameters, including the electron transfer rate constant, limiting current, and transfer coefficient. They show a significant departure from the Butler-Volmer behavior in a clear manifestation of the Marcus-Hush theory of electron transfer. In addition, our system provides a novel experimental platform, which could be applied to address a number of scientific problems such as identification of reaction mechanisms, surface modification, or long-range electron transfer.


Polymers ◽  
2018 ◽  
Vol 10 (2) ◽  
pp. 206 ◽  
Author(s):  
Elisseos Verveniotis ◽  
Yuji Okawa ◽  
Kenji Watanabe ◽  
Takashi Taniguchi ◽  
Takaaki Taniguchi ◽  
...  

2021 ◽  
Vol 125 (6) ◽  
pp. 1325-1335 ◽  
Author(s):  
Cesar Jara ◽  
Tomáš Rauch ◽  
Silvana Botti ◽  
Miguel A. L. Marques ◽  
Ariel Norambuena ◽  
...  

ACS Photonics ◽  
2021 ◽  
Author(s):  
Prince Khatri ◽  
Ralph Nicholas Edward Malein ◽  
Andrew J. Ramsay ◽  
Isaac J. Luxmoore

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