Effect of different aqueous electrolytes on electrochemical performance of activated carbon anchored by multiwalled carbon nanotubes for supercapacitor applications

Author(s):  
Manoranjan Mandal ◽  
Subhasri Subudhi ◽  
Injamul Alam ◽  
B. V. R. S. Subramanyam ◽  
Sonali Das ◽  
...  
2013 ◽  
Vol 94 ◽  
pp. 182-191 ◽  
Author(s):  
P. Sivaraman ◽  
Arup R. Bhattacharrya ◽  
Sarada P. Mishra ◽  
Avinash P. Thakur ◽  
K. Shashidhara ◽  
...  

2007 ◽  
Vol 119 ◽  
pp. 55-58 ◽  
Author(s):  
Soo Jin Park ◽  
Se Hyuk Im ◽  
John M. Rhee ◽  
Young Seak Lee

Electrochemical double layer capacitors (EDLCs) are promising high power energy sources for many different applications where high power density, high cycle efficiency and long cycle life are needed. However, because the energy density of EDLCs is small compared to that of rechargeable batteries one needs to increase the capacitance of EDLCs. The nanofiber diameters range from 50 nm to 400 nm, depending on the concentration of polymer solution types, tip-to-collector distance, applied voltage, and viscosity of the solution. The main advantage of the electrospinning process is that it is a simple means to prepare continuous fibers with unusually large surface to volume ratios and pore structure surfaces. So, feature of nanofiber webs are the high specific surface area developed by creating pores on the nanofiber surface. In this work, the multiwalled carbon nanotubes embedded polyacrylonitrile solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of 350 nm ultrafine nanofibers, which were used to produce a series of activated carbon nanofibers with developed mesoporosity and high electrical conductivity through stabilization, carbonization-activation processes.


NANO ◽  
2017 ◽  
Vol 12 (04) ◽  
pp. 1750051 ◽  
Author(s):  
Manyuan Cai ◽  
Xiaogang Sun ◽  
Yanyan Nie ◽  
Wei Chen ◽  
Zhiwen Qiu ◽  
...  

Pre-lithiated multiwalled carbon nanotube anode was prepared by internal short circuit approach(ISC) for 5[Formula: see text]min, 30[Formula: see text]min, 60[Formula: see text]min and 120[Formula: see text]min respectively. Lithium ion capacitors (LICs) were assembled by using pre-lithiated multiwalled carbon nanotubes as anodes and activated carbon (AC) as cathodes. The structure of multiwalled carbon nanotubes and electrodes were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical performance of pre-lithiated multiwalled carbon nanotube electrodes and pristine carbon nanotube electrodes were tested by galvanostatic charge/discharge and electrochemical impedance. The results indicated that pre-lithiation carbon nanotubes greatly improved the charge/discharge performance of LICs. The energy density was four times than conventional electric double-layer capacitors (EDLCs) at the current density of 100[Formula: see text]mA/g. The LICs achieved a specific capacitance of 59.3[Formula: see text]F/g at the current density of 100[Formula: see text]mA/g with 60[Formula: see text]min pre-lithiatiation process. The maximum energy density and power density was 96[Formula: see text]Wh/kg and 4035[Formula: see text]W/kg, respectively. The energy density still remained about 89.0% after 1000 cycles. The LIC showed excellent supercapacitor performance.


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