A modular, easy-to-use microcapillary electrophoresis system with laser-induced fluorescence for quantitative compositional analysis of trace organic molecules

2020 ◽  
Vol 91 (10) ◽  
pp. 104101
Author(s):  
Zachary A. Duca ◽  
Nicholas C. Speller ◽  
Thomas Cantrell ◽  
Amanda M. Stockton
Keyword(s):  
Organic Molecules ◽  
Compositional Analysis ◽  
Laser Induced Fluorescence ◽  
Microcapillary Electrophoresis ◽  
Electrophoresis System ◽  
Trace Organic

scholarly journals Organic molecules in saturnian E-ring particles. Probing subsurface oceans of Enceladus?

2008 ◽  
Vol 4 (S251) ◽  
pp. 317-318 ◽  
Author(s):  
Frank Postberg ◽  
S. Kempf ◽  
R. Srama ◽  
E. Grün ◽  
J. K. Hillier ◽  
...  
Keyword(s):  
Mass Spectra ◽  
Organic Molecules ◽  
Compositional Analysis ◽  
Chemical Processes ◽  
Water Ice ◽  
Volcanic Plumes ◽  
Crucial Information ◽  
Impact Ionisation ◽  
First Time

AbstractThe population of Saturn's outermost tenuous E-ring is dominated by tiny water ice particles, some of which contain organic or mineral impurities. Active cryo-volcanism on the moon Enceladus, embedded in the E-ring, has been known to be a major source of particles replenishing the ring since late 2005. Therefore, particles in the vicinity of Enceladus provide crucial information about the dynamic and chemical processes occurring far below the moon's icy surface.We present a compositional analysis of thousands of impact ionisation mass spectra of Saturn's E-ring particles, with sizes predominantly below 1 μm, detected by the Cosmic Dust Analyser onboard the Cassini spacecraft. Our findings imply that organic compounds are a significant component of icy particles ejected by Enceladus plumes. Our in situ measurements are supported by detections of other Cassini instruments. They hint at a dynamic interaction of a hot rocky core with liquid water below the icy surface, where the organic molecules are generated. Further insights are expected from two close Enceladus flybys to be performed by Cassini in 2008. Then, for the first time, we will obtain spectra of freshly ejected particles at the traversals through the cryo-volcanic plumes.

Upconversion NaLuF4 fluorescent nanoprobes for jellyfish cell imaging and irritation assessment of organic dyes

2015 ◽  
Vol 3 (23) ◽  
pp. 6067-6076 ◽  
Author(s):  
Zenghui Chen ◽  
Xiaofeng Wu ◽  
Shigang Hu ◽  
Pan Hu ◽  
Huanyuan Yan ◽  
...  
Keyword(s):  
Cell Imaging ◽  
Organic Molecules ◽  
Organic Dyes ◽  
Good Biocompatibility ◽  
Trace Organic

Upconversion NaLuF4 nanoprobes with intense visible fluorescence and good biocompatibility have been successfully constructed for assessing the irritation of trace organic molecules in jellyfish cells based on the LRET process.

High Resolution Replication of Organoclay Surfaces

1982 ◽  
Vol 40 ◽  
pp. 576-577
Author(s):  
W. W. Barker ◽  
W. E. Rigsby ◽  
V. J. Hurst ◽  
W. J. Humphreys
Keyword(s):  
Clay Mineral ◽  
Organic Molecule ◽  
Organic Molecules ◽  
X Ray Diffraction ◽  
Xrd Pattern ◽  
X Ray ◽  
Naturally Occurring ◽  
Silicate Layers ◽  
Mineral Identification

Experimental clay mineral-organic molecule complexes long have been known and some of them have been extensively studied by X-ray diffraction methods. The organic molecules are adsorbed onto the surfaces of the clay minerals, or intercalated between the silicate layers. Natural organo-clays also are widely recognized but generally have not been well characterized. Widely used techniques for clay mineral identification involve treatment of the sample with H2 O2 or other oxidant to destroy any associated organics. This generally simplifies and intensifies the XRD pattern of the clay residue, but helps little with the characterization of the original organoclay. Adequate techniques for the direct observation of synthetic and naturally occurring organoclays are yet to be developed.

Direct phase determination in electron crystallography: small organic molecules

1992 ◽  
Vol 50 (2) ◽  
pp. 1166-1167
Author(s):  
Douglas L. Dorset
Keyword(s):  
Organic Molecules ◽  
Data Sets ◽  
Temperature Structure ◽  
3D Analysis ◽  
Intensity Data ◽  
Electron Crystallography ◽  
Phase Determination ◽  
Measured Intensity ◽  
3D Data

The quantitative use of electron diffraction intensity data for the determination of crystal structures represents the pioneering achievement in the electron crystallography of organic molecules, an effort largely begun by B. K. Vainshtein and his co-workers. However, despite numerous representative structure analyses yielding results consistent with X-ray determination, this entire effort was viewed with considerable mistrust by many crystallographers. This was no doubt due to the rather high crystallographic R-factors reported for some structures and, more importantly, the failure to convince many skeptics that the measured intensity data were adequate for ab initio structure determinations.We have recently demonstrated the utility of these data sets for structure analyses by direct phase determination based on the probabilistic estimate of three- and four-phase structure invariant sums. Examples include the structure of diketopiperazine using Vainshtein's 3D data, a similar 3D analysis of the room temperature structure of thiourea, and a zonal determination of the urea structure, the latter also based on data collected by the Moscow group.

Compositional Analysis of III-V Interface Lattice Images

1980 ◽  
Vol 38 ◽  
pp. 318-319
Author(s):  
A. Olsen ◽  
J.C.H. Spence ◽  
P. Petroff
Keyword(s):  
Crystal Structure ◽  
Image Matching ◽  
Compositional Analysis ◽  
Depth Of Field ◽  
Limit Set ◽  
High Contrast ◽  
Resolution Limit ◽  
Fourier Image ◽  
Lattice Images ◽  
True Structure

Since the point resolution of the JEOL 200CX electron microscope is up = 2.6Å it is not possible to obtain a true structure image of any of the III-V or elemental semiconductors with this machine. Since the information resolution limit set by electronic instability (1) u0 = (2/πλΔ)½ = 1.4Å for Δ = 50Å, it is however possible to obtain, by choice of focus and thickness, clear lattice images both resembling (see figure 2(b)), and not resembling, the true crystal structure (see (2) for an example of a Fourier image which is structurally incorrect). The crucial difficulty in using the information between Up and u0 is the fractional accuracy with which Af and Cs must be determined, and these accuracies Δff/4Δf = (2λu2Δf)-1 and ΔCS/CS = (λ3u4Cs)-1 (for a π/4 phase change, Δff the Fourier image period) are strongly dependent on spatial frequency u. Note that ΔCs(up)/Cs ≈ 10%, independent of CS and λ. Note also that the number n of identical high contrast spurious Fourier images within the depth of field Δz = (αu)-1 (α beam divergence) decreases with increasing high voltage, since n = 2Δz/Δff = θ/α = λu/α (θ the scattering angle). Thus image matching becomes easier in semiconductors at higher voltage because there are fewer high contrast identical images in any focal series.

High Spatial Resolution Compositional Analysis at Interfaces

1980 ◽  
Vol 38 ◽  
pp. 356-359
Author(s):  
John B. Vander Sande ◽  
Thomas F. Kelly ◽  
Douglas Imeson
Keyword(s):  
Electron Microscope ◽  
High Spatial Resolution ◽  
Compositional Analysis ◽  
Scanning Transmission Electron Microscope ◽  
Thin Specimen ◽  
X Ray ◽  
Volume Of Interest ◽  
Transmission Electron ◽  
Scanning Transmission ◽  
Electron Energy Loss

In the scanning transmission electron microscope (STEM) a fine probe of electrons is scanned across the thin specimen, or the probe is stationarily placed on a volume of interest, and various products of the electron-specimen interaction are then collected and used for image formation or microanalysis. The microanalysis modes usually employed in STEM include, but are not restricted to, energy dispersive X-ray analysis, electron energy loss spectroscopy, and microdiffraction.

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