scholarly journals Asymmetric membranes for destabilization of oil droplets in produced water from alkaline-surfactant-polymer (ASP) flooding

2018 ◽  
Author(s):  
Azierah Ramlee ◽  
Chel-Ken Chiam ◽  
Rosalam Sarbatly
Keyword(s):  
Produced Water ◽  
Oil Droplets ◽  
Asymmetric Membranes ◽  
Asp Flooding ◽  
Alkaline Surfactant Polymer

Effects of alkaline/surfactant/polymer on stability of oil droplets in produced water from ASP flooding

2002 ◽  
Vol 211 (2-3) ◽  
pp. 275-284 ◽  
Author(s):  
Shubo Deng ◽  
Renbi Bai ◽  
J.Paul Chen ◽  
Gang Yu ◽  
Zhanpeng Jiang ◽  
...  
Keyword(s):  
Produced Water ◽  
Oil Droplets ◽  
Asp Flooding ◽  
Alkaline Surfactant Polymer

scholarly journals Study on Demulsification-Flocculation Mechanism of Oil-Water Emulsion in Produced Water from Alkali/Surfactant/Polymer Flooding

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 395 ◽  
Author(s):  
Bin Huang ◽  
Xiaohui Li ◽  
Wei Zhang ◽  
Cheng Fu ◽  
Ying Wang ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Produced Water ◽  
Negative Charge ◽  
Oil Droplets ◽  
Water Separation ◽  
Water Emulsion ◽  
Flocculation Mechanism ◽  
Asp Flooding ◽  
Oil Water Separation ◽  
Oil Water

The issue of pipeline scaling and oil-water separation caused by treating produced water in Alkali/Surfactant/Polymer (ASP) flooding greatly limits the wide use of ASP flooding technology. Therefore, this study of the demulsification-flocculation mechanism of oil-water emulsion in ASP flooding produced water is of great importance for ASP produced water treatment and its application. In this paper, the demulsification-flocculation mechanism of produced water is studied by simulating the changes in oil-water interfacial tension, Zeta potential and the size of oil droplets of produced water with an added demulsifier or flocculent by laboratory experiments. The results show that the demulsifier molecules can be adsorbed onto the oil droplets and replace the surfactant absorbed on the surface of oil droplets, reducing interfacial tension and weakening interfacial film strength, resulting in decreased stability of the oil droplets. The demulsifier can also neutralize the negative charge on the surface of oil droplets and reduce the electrostatic repulsion between them which will be beneficial for the accumulation of oil droplets. The flocculent after demulsification of oil droplets by charge neutralization, adsorption bridging, and sweeping all functions together. Thus, the oil droplets form aggregates and the synthetic action by the demulsifier and the flocculent causes the oil drop film to break up and oil droplet coalescence occurs to separate oil water.

scholarly journals Research on Basic Properties of Alkali-Surfactant-Polymer Flooding Produced Water and Influence of Oil-Displacing Agent on Settlement

2020 ◽  
Vol 4 (4) ◽  
pp. 1-7
Author(s):  
Zhang D
Keyword(s):  
Produced Water ◽  
Oil Droplets ◽  
Water Separation ◽  
Basic Properties ◽  
Asp Flooding ◽  
Oil Water Separation ◽  
Oil Water ◽  
The Stability ◽  
Relationship Of ◽  
Oil Droplet Size

The basic properties of alkali‒surfactant‒polymer (ASP) flooding produced water and effect of oil displacing agent on the stability of flooding produced water were obtained, through measuring and analysing water quality, oil content-settling time relationship and oil displacing agent-oil droplet size relationship of Zhong-106, Zhong-312, Zhong-417, Nan 4-8 and Bei 2-7 flooding produced water from Daqing Oilfield. The addition of ternary oil displacement agent to ASP flooding produced water greatly increases the difficulty of oil-water separation, and higher the concentration, worse the separation effect after standing. The effects of alkali, surfactant, and polymer on oil-water stability in simulated ASP flooding produced water were studied respectively. The ASP flooding produced water after 48 hours of settling formed a trace amount of nano-oil droplets, also accompanied by the accumulation and separation of a part of the oil droplets.

Destabilization of oil droplets in produced water from ASP flooding

2005 ◽  
Vol 252 (2-3) ◽  
pp. 113-119 ◽  
Author(s):  
Shubo Deng ◽  
Gang Yu ◽  
Zhanpeng Jiang ◽  
Ruiquan Zhang ◽  
Yen Peng Ting
Keyword(s):  
Produced Water ◽  
Oil Droplets ◽  
Asp Flooding

scholarly journals Study on the Stability of Produced Water from Alkali/Surfactant/Polymer Flooding under the Synergetic Effect of Quartz Sand Particles and Oil Displacement Agents

Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 315 ◽  
Author(s):  
Bin Huang ◽  
Chen Wang ◽  
Weisen Zhang ◽  
Cheng Fu ◽  
Haibo Liu ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Quartz Sand ◽  
Produced Water ◽  
Synergetic Effect ◽  
Oil Droplets ◽  
Oil Displacement ◽  
Asp Flooding ◽  
Oil Water ◽  
Sand Particles ◽  
The Stability

With the wide application of ASP (alkali/surfactant/polymer) flooding oil recovery technology, the produced water from ASP flooding has increased greatly. The clay particles carried by crude oil in the process of flow have a synergetic effect with oil displacement agents in the produced water, which increases the treatment difficulty of produced water. The stability of produced water is decided by the stability of oil droplets in the ASP-flooding-produced water system. The oil content, Zeta potential, interfacial tension and oil droplet size are important parameters to characterize the stability of produced water. In this paper, the changes of the oil content, Zeta potential, interfacial tension and oil droplet size of ASP flooding oily wastewater under the synergetic effect of different concentrations of quartz sand particles and oil displacement agents were studied by laboratory experiments. The experimental results show that the negatively charged quartz sand particles can absorb active substances in crude oil and surfactant molecules in the water phase and migrate to the oil–water interface, which increases the repulsion between quartz sand particles, decreasing the oil–water interfacial tension. Thus, the stability of oil droplets is enhanced, and the aggregation difficulty between oil droplets and quartz sand particles is increased. With the continually increasing quartz sand concentration, quartz sand particles combine with surfactant molecules adsorbed on the oil–water interface to form an aggregate. Meanwhile, the polymer molecules crimp from the stretching state, and the number of them surrounding the surface of the flocculation structure is close to saturation, which makes the oil droplets and quartz sand particles prone to aggregation, and the carried active substances desorb from the interface, resulting in the instability of the produced water system. The research on the synergetic effect between quartz sand particles and oil displacement agents is of great significance for deepening the treatment of ASP-produced water.

scholarly journals Nonionic Surfactant to Enhance the Performances of Alkaline–Surfactant–Polymer Flooding with a Low Salinity Constraint

2020 ◽  
Vol 10 (11) ◽  
pp. 3752 ◽  
Author(s):  
Shabrina Sri Riswati ◽  
Wisup Bae ◽  
Changhyup Park ◽  
Asep K. Permadi ◽  
Adi Novriansyah
Keyword(s):  
Nonionic Surfactant ◽  
Oil Recovery ◽  
Anionic Surfactant ◽  
Pore Volume ◽  
Salinity Gradient ◽  
Reference Case ◽  
Low Salinity ◽  
Asp Flooding ◽  
Optimum Salinity ◽  
Alkaline Surfactant Polymer

This paper presents a nonionic surfactant in the anionic surfactant pair (ternary mixture) that influences the hydrophobicity of the alkaline–surfactant–polymer (ASP) slug within low-salinity formation water, an environment that constrains optimal designs of the salinity gradient and phase types. The hydrophobicity effectively reduced the optimum salinity, but achieving as much by mixing various surfactants has been challenging. We conducted a phase behavior test and a coreflooding test, and the results prove the effectiveness of the nonionic surfactant in enlarging the chemical applicability by making ASP flooding more hydrophobic. The proposed ASP mixture consisted of 0.2 wt% sodium carbonate, 0.25 wt% anionic surfactant pair, and 0.2 wt% nonionic surfactant, and 0.15 wt% hydrolyzed polyacrylamide. The nonionic surfactant decreased the optimum salinity to 1.1 wt% NaCl compared to the 1.7 wt% NaCl of the reference case with heavy alcohol present instead of the nonionic surfactant. The coreflooding test confirmed the field applicability of the nonionic surfactant by recovering more oil, with the proposed scheme producing up to 74% of residual oil after extensive waterflooding compared to 51% of cumulative oil recovery with the reference case. The nonionic surfactant led to a Winsor type III microemulsion with a 0.85 pore volume while the reference case had a 0.50 pore volume. The nonionic surfactant made ASP flooding more hydrophobic, maintained a separate phase of the surfactant between the oil and aqueous phases to achieve ultra-low interfacial tension, and recovered the oil effectively.

A network model for capture of emulsion droplets in porous media

2008 ◽  
Vol 48 (1) ◽  
pp. 21
Author(s):  
Changhong Gao
Keyword(s):  
Porous Media ◽  
Enhanced Oil Recovery ◽  
Network Model ◽  
Oil Recovery ◽  
Produced Water ◽  
Permeability Reduction ◽  
Oil Droplets ◽  
New Approach ◽  
Reservoir Rocks ◽  
Emulsion Droplets

Capture of emulsion droplets in porous media can be costly or beneficial. When produced water is injected into reservoir for pressure maintenance, the oil droplets in produced water can plug reservoir rocks and cause the well to lose injectivity. Enhanced oil recovery (EOR) technology takes advantage of this feature and plugs high-injectivity zones with emulsions. Previous studies reveal that interception and straining are the mechanisms of permeability decline. Established models rely on filtration data to determine key parameters. In this work, a network model is proposed to simulate capture of oil droplets in reservoir rocks and resultant permeability reduction. The model is validated with test data and reasonably good results are obtained. The simulation also reveals that the wettability of the tested porous media was altered by injection of emulsions. The new approach considers the characteristics of the porous media and incorporates the damage mechanisms, thus providing more scientific insights into the flow and capture of droplets in porous media.

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