Conductivity relaxation and charge transport of trihexyl tetradecyl phosphonium dicyanamide ionic liquid by broadband dielectric spectroscopy

2018 ◽  
Author(s):  
Thasneema K. K. ◽  
M. Shahin Thayyil ◽  
Krishna Kumar N. S. ◽  
Govindaraj G. ◽  
V. C. Saheer
Keyword(s):  
Ionic Liquid ◽  
Charge Transport ◽  
Dielectric Spectroscopy ◽  
Conductivity Relaxation ◽  
Broadband Dielectric Spectroscopy

scholarly journals Hydrogen bonding and charge transport in a protic polymerized ionic liquid

Soft Matter ◽  
2020 ◽  
Vol 16 (26) ◽  
pp. 6091-6101 ◽  
Author(s):  
Arthur Markus Anton ◽  
Falk Frenzel ◽  
Jiayin Yuan ◽  
Martin Tress ◽  
Friedrich Kremer
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Fourier Transform ◽  
Charge Transport ◽  
Wide Temperature Range ◽  
Dielectric Spectroscopy ◽  
Fourier Transform Infrared ◽  
Polymerized Ionic Liquid ◽  
Temperature Range ◽  
Broadband Dielectric Spectroscopy

Hydrogen bonding and charge transport in the protic polymerized ionic liquid PAAPS are studied by combining Fourier transform infrared (FTIR) and broadband dielectric spectroscopy (BDS) in a wide temperature range from 170 to 300 K.

Broadband dielectric spectroscopy of micelles and microemulsions formed in a hydrophilic ionic liquid: the relaxation mechanism and interior parameters

2018 ◽  
Vol 42 (4) ◽  
pp. 2605-2615 ◽  
Author(s):  
Yiwei Lian ◽  
Kongshuang Zhao
Keyword(s):  
Ionic Liquid ◽  
Dielectric Spectroscopy ◽  
Volume Fraction ◽  
Relaxation Mechanism ◽  
Broadband Dielectric Spectroscopy ◽  
Dispersed Phases

Permittivity, conductivity and volume fraction of continuous and dispersed phases of micelles and non-aqueous microemulsions formed in ionic liquid.

Dynamics of Ion Locking in Doubly Polymerized Ionic Liquids

2020 ◽  
Author(s):  
Swati Arora ◽  
Julisa Rozon ◽  
Jennifer Laaser
Keyword(s):  
Dielectric Constant ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Ion Pairs ◽  
Polymer Chains ◽  
Ion Motion ◽  
Charged Species ◽  
Broadband Dielectric Spectroscopy ◽  
Covalently Linked ◽  
Insight Into

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>

scholarly journals Broadband dielectric spectroscopy for monitoring temperature-dependent chloride ion motion in BiOCl plates

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Adrian Radoń ◽  
Dariusz Łukowiec ◽  
Patryk Włodarczyk
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Spectroscopy ◽  
Low Frequency ◽  
Chloride Ion ◽  
Ion Source ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Broadband Dielectric Spectroscopy ◽  
Free Chloride ◽  
Structure Rebuilding

AbstractThe dielectric properties and electrical conduction mechanism of bismuth oxychloride (BiOCl) plates synthesized using chloramine-T as the chloride ion source were investigated. Thermally-activated structure rebuilding was monitored using broadband dielectric spectroscopy, which showed that the onset temperature of this process was 283 K. This rebuilding was related to the introduction of free chloride ions into [Bi2O2]2+ layers and their growth, which increased the intensity of the (101) diffraction peak. The electrical conductivity and dielectric permittivity were related to the movement of chloride ions between plates (in the low-frequency region), the interplanar motion of Cl− ions at higher frequencies, vibrations of these ions, and charge carrier hopping at frequencies above 10 kHz. The influence of the free chloride ion concentration on the electrical conductivity was also described. Structure rebuilding was associated with a lower concentration of free chloride ions, which significantly decreased the conductivity. According to the analysis, the BiOCl plate conductivity was related to the movement of Cl− ions, not electrons.

Sign in / Sign up

Export Citation Format

Share Document